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We present an analysis of the thermoelectric properties of of $n$-type GeTe and SnTe in relation to the lead chalcogenides PbTe and PbSe. We find that the singly degenerate conduction bands of semiconducting GeTe and SnTe are highly…

Materials Science · Physics 2013-10-22 Xin Chen , David Parker , David J. Singh

Thermoelectric performance of SnTe has been found to enhance with isovalent doping of alkaline and transition metal elements where most of these elements have solubility of less than 13%. We propose a strategy of doping rare earth element…

Materials Science · Physics 2022-12-26 Somnath Acharya , Dibyendu Dey , Tulika Maitra , Ajay Soni , A. Taraphder

Achieving high valley degeneracy (i.e. "band convergence") in a material usually results in considerably enhanced thermoelectric properties. However, it is still unclear why this strategy of designing efficient thermoelectric materials is…

Materials Science · Physics 2022-05-30 Ransell D'Souza , José D. Querales-Flores , Jiang Cao , Stephen Fahy , Ivana Savić

As a result of suppressed phonon conduction, large improvements of the thermoelectric figure of merit, ZT, have been recently reported for nanostructures compared to the raw materials' ZT values. It has also been suggested that low…

Mesoscale and Nanoscale Physics · Physics 2011-04-11 Neophytos Neophytou , Hans Kosina

We present results of electronic band structure, Fermi surface and electron transport properties calculations in orthorhombic $n$- and $p$-type SnSe, applying Korringa-Kohn-Rostoker method and Boltzmann transport approach. The analysis…

Materials Science · Physics 2015-05-11 K. Kutorasinski , B. Wiendlocha , S. Kaprzyk , J. Tobola

Thermoelectric semiconducting materials are often evaluated by their figure-of-merit, zT. However, by using zT as the metric for showing improvements, it is not immediately clear whether the improvement is from an enhancement of the…

Materials Science · Physics 2018-01-03 Stephen Dongmin Kang , G. Jeffrey Snyder

Thermoelectric (TE) conversion in conducting materials is of eminent importance for providing renewable energy and solid-state cooling. Although traditionally, the Seebeck effect plays a key role for the TE figure of merit zST, it…

Materials Science · Physics 2020-01-16 Junsen Xiang , Sile Hu , Meng Lyu , Wenliang Zhu , Chaoyang Ma , Ziyu Chen , Frank Steglich , Genfu Chen , Peijie Sun

Substitution of Cu for Ni in the Kondo lattice system CeNi$_2$Al$_3$ results in a simultaneous optimization of the three interdependent thermoelectric parameters: thermoelectric power, electrical and thermal conductivities, where the…

Strongly Correlated Electrons · Physics 2015-05-14 Peijie Sun , Tusyoshi Ikeno , Toshio Mizushima , Yosikazu Isikawa

SnSe monolayers experience a temperature induced two-dimensional Pnm2$_1 \to$ P4/nmm structural transformation precipitated by the softening of vibrational modes. The standard theoretical treatment of thermoelectricity---which relies on a…

Materials Science · Physics 2021-01-22 John W. Villanova , Salvador Barraza-Lopez

Materials with ring-shaped electronic bands are promising thermoelectric candidates, since their unusual dispersion shape is predicted to give large power factors. While previous calculations of these materials have relied on the assumption…

Mesoscale and Nanoscale Physics · Physics 2021-04-14 Cameron Rudderham , Jesse Maassen

Low dimensional structures have demonstrated improved thermoelectric (TE) performance because of a drastic reduction in their thermal conductivity, {\kappa}l. This has been observed for a variety of materials, even for traditionally poor…

Materials Science · Physics 2012-01-31 Neophytos Neophytou , Hans Kosina

Thermoelectric devices convert temperature gradients into electrical power and vice versa, thus enabling energy scavenging from waste heat, sensing and cooling. Yet, many of these attractive applications are hindered by the limited…

Materials Science · Physics 2019-02-14 Davide Donadio

Designing thermoelectric materials with high figure of merit $ZT=S^2 G T/\kappa$ requires fulfilling three often irreconcilable conditions, i.e., the high electrical conductance $G$, small thermal conductance $\kappa$ and high Seebeck…

Mesoscale and Nanoscale Physics · Physics 2014-07-11 Po-Hao Chang , Mohammad Saeed Bahramy , Naoto Nagaosa , Branislav K. Nikolic

Nanocomposites are promising candidates for the next generation of thermoelectric materials since they exhibit extremely low thermal conductivities as a result of phonon scattering on the boundaries of the various material phases. The…

Mesoscale and Nanoscale Physics · Physics 2017-12-06 Samuel Foster , Mischa Thesberg , Neophytos Neophytou

Understanding how to optimize electronic band structures for thermoelectrics is a topic of long-standing interest in the community. Prior models have been limited to simplified bands and/or scattering models. In this study, we apply more…

Materials Science · Physics 2021-02-12 Junsoo Park , Yi Xia , Vidvuds Ozoliņš , Anubhav Jain

A composite material is considered which consists of conducting nanoparticles separated by tunneling dielectric barriers. The influence of the phonon thermal conductivity of dielectric matrix on the thermoelectric figure of merit of this…

Mesoscale and Nanoscale Physics · Physics 2012-09-21 L. P. Bulat , D. Kossakovski , D. A. Pshenay-Severin

Thermoelectric materials intrigue much interest due to their wide range of application such as power generators and refrigerators. The efficiency of thermoelectric materials is quantified by the figure of merit, and a figure greater than…

Mesoscale and Nanoscale Physics · Physics 2022-02-16 Masashi Hosoi , Ikuma Tateishi , Hiroyasu Matsuura , Masao Ogata

The efficiency of energy conversion in thermoelectric generators (TEGs) is directly proportional to electrical conductivity and Seebeck coefficient while inversely to thermal conductivity. The challenge is to optimize these interdependent…

IV-VI semiconductor SnSe has been known as the material with record high thermoelectric performance.The multiple close-to-degenerate valence bands in the electronic band structure has been one of the key factors contributing to the high…

We report about detailed dimensionless figure of merit ($ZT$) calculated by using Fermi integral method (compared with Bi$_2$Te$_3$, CoSb$_3$, and SrTiO$_3$) for thermoelectric (TE) materials' design and its module application.…

Materials Science · Physics 2020-03-05 Hirofumi Kakemoto