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Many ionic surfactants with wide applications in personal-care and house-hold detergency show limited water solubility at lower temperatures (Krafft point). This drawback can be overcome by using mixed solutions, where the ionic surfactant…

The forces between colloidal particles at a decane-water interface, in the presence of low concentrations of a monovalent salt (NaCl) and of the surfactant sodium dodecylsulfate (SDS) in the aqueous subphase, have been studied using laser…

Soft Condensed Matter · Physics 2008-07-11 B. J. Park , J. P. Pantina , E. Furst , M. Oettel , S. Reynaert , J. Vermant

We investigate the concentration dependence of surfactant diffusion in wormlike micellar solutions using dissipative particle dynamics simulations. The simulations show that the self-diffusion coefficient of surfactants exhibits a…

Soft Condensed Matter · Physics 2025-02-19 Yusuke Koide , Takato Ishida , Takashi Uneyama , Yuichi Masubuchi

The impact of mesoscale organization on dynamics and ion transport in binary ionic liquid mixtures is investigated by broadband dielectric spectroscopy, dynamic-mechanical spectroscopy, x-ray scattering, and molecular dynamics simulations.…

Soft Condensed Matter · Physics 2019-05-09 Tyler Cosby , Utkarsh Kapoor , Jindal K. Shah , Joshua Sangoro

The role of ionic interactions between sodium dodecyl sulfate, SDS, and sapphire surfaces have been studied using specular neutron reflection to determine the structure and composition of adsorbed surfactant layers. Increasing the pH of the…

Soft Condensed Matter · Physics 2012-05-02 Ningning Li , Robert K. Thomas , Adrian R. Rennie

We study the evolution of the mass of evaporating single microdroplets of sodium do-decyl sulphate (SDS) / diethylene glycol (DEG) mixture. First, we recognise and deconvolute the influence of residual water evaporation [Kolwas et al. Soft…

Chemical Physics · Physics 2021-05-21 Maciej Kolwas , Daniel Jakubczyk , Justice Archer , Tho Do Duc

We present a coarse-grained model for ionic surfactants in explicit aqueous solutions, and study by computer simulation both the impact of water content on the morphology of the system, and the consequent effect of the formed interfaces on…

Soft Condensed Matter · Physics 2015-03-16 Samuel Hanot , Sandrine Lyonnard , Stefano Mossa

Spherical micelle modified by cononsolvency effect is investigated by using self-consistent field theory (SCFT) and random phase approximation, which is formed by diblock copolymers consisted of one permanent hydrophobic block and one…

Soft Condensed Matter · Physics 2025-04-08 Xiangyu Zhang , Jing Zong , Dong Meng

The experimental survey of the water drops to different concentrations from non ionic surfactant (C11E5) and set down anionic (SDS) on glass horizontal surfaces has been made. The 1st step consisted in measuring the tension of surface, the…

Fluid Dynamics · Physics 2009-06-29 H. Alla , S. Freifer , C. Medjellel

We investigate the self-assembly process of a surfactant with inverted polarity in water and cyclohexane using both all-atom and coarse grained hybrid particle-field molecular dynamics simulations. Unlike conventional surfactants, the…

Soft Condensed Matter · Physics 2020-07-03 M. Carrer , T. Skrbic , S. L. Bore , G. Milano , M. Cascella , A. Giacometti

Photon correlation spectroscopy and rheological measurements are performed to investigate the microscopic dynamics and mechanical responses of aqueous solutions of triblock copolymers and aqueous mixtures of triblock copolymers and anionic…

Soft Condensed Matter · Physics 2011-09-28 Rajib Basak , Nabaneeta Mukhopadhyay , Ranjini Bandyopadhyay

Isothermal-isobaric molecular dynamics simulations are used to examine the microscopic structure and other properties of a model solution consisting of NaCl salt dissolved in water-methanol mixture. The SPC/E water model and the united atom…

Soft Condensed Matter · Physics 2018-06-27 M. Cruz Sanchez , J. Gujt , S. Sokolowski , O. Pizio

Discotic ionic liquid crystals (DILCs) consist of self-assembled superdiscs of cations and anions that spontaneously stack in linear columns with high one-dimensional ionic and electronic charge mobility, making them prominent model systems…

Ionic liquids are promising candidates for electrolytes in energy-storage systems. We demonstrate that mixing two ionic liquids allows to precisely tune their physical properties, like the dc conductivity. Moreover, these mixtures enable…

Soft Condensed Matter · Physics 2018-02-27 E. Thoms , P. Sippel , D. Reuter , M. Weiß , A. Loidl , S. Krohns

The effect of different ionic cosolutes (NaCl, Na$_2$SO$_4$, Li$_2$SO$_4$, NaSCN, Na$_2$[Fe(CN)5NO], and Na$_3$[Co(NO)$_6$]) on the interaction between sodium dodecyl sulfate (SDS) and poly(ethylene oxide) (PEO) was examined by small-angle…

The rate of micelle solubilization (SR) can be appraised following the decrease of the radius of a macroscopic drop of oil in contact with a surfactant solution [Todorov, 2002]. Alternatively, the time required for the dissolution of a…

Soft Condensed Matter · Physics 2020-10-30 Jose Daniel Rodriguez , Maurice Espinoza , Kareem Rahn-Chique , German Urbina-Villalba

We investigate the aggregation of amphiphilic molecules by adapting the two-state Muller-Lee-Graziano model for water, in which a solvent-induced hydrophobic interaction is included implicitly. We study the formation of various types of…

Statistical Mechanics · Physics 2009-11-10 S. Moelbert , B. Normand , P. De Los Rios

The kinetics of non-ionic surfactant adsorption at a fluid-fluid interface from a micellar solution is considered theoretically. Our model takes into account the effect of micelle relaxation on the diffusion of the free surfactant…

Soft Condensed Matter · Physics 2007-05-23 Herve Mohrbach

We use coarse-grained molecular-dynamics (MD) simulations to investigate the structural and dynamical properties of micelles under non-equilibrium Poiseuille flow in a nano-confined geometry. The effects of flow, confinement, and the…

Soft Condensed Matter · Physics 2015-06-23 Mona Habibi , Colin Denniston , Mikko Karttunen

Bubble bursting at the surface of the sea water produce drops and is the main source of sea spay aerosol. The mechanisms underlying the drops production from a single bubble bursting event have been intensively studied and the influence of…

Fluid Dynamics · Physics 2022-10-05 Juliette Pierre , Mathis Poujol , Thomas Séon