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The behavior of confined cylindrical micelle-forming surfactants under the influence of shear has been investigated using Monte Carlo simulations. The surfactants are modeled as coarse-grained lattice polymers, while the Monte Carlo shear…

Soft Condensed Matter · Physics 2009-11-10 Gaurav Arya , Athanassios Z. Panagiotopoulos

Water drops spontaneously accumulate charges when they move on hydrophobic dielectric surfaces by slide electrification. On the one hand, slide electrification generates electricity with possible applications on tiny devices. On the other…

Soft Condensed Matter · Physics 2025-04-03 Xiaomei Li , Zhongyuan Ni , Xiaoteng Zhou , Lisa S. Bauer , Diego Diaz , Gabriele Schäfer , Hans-Jürgen Butt

In this work, we use large-scale molecular dynamics simulations coupled to free energy calculations to identify for the first time a limit of stability (spinodal) and a change in the nucleation mechanism in aqueous NaCl solutions. This is a…

Chemical Physics · Physics 2019-05-01 Hao Jiang , Pablo G. Debenedetti , Athanassios Z. Panagiotopoulos

Catalytically active colloids maintain non-equilibrium conditions in which they produce and deplete chemicals and hence effectively act as sources and sinks of molecules. While individual colloids that are symmetrically coated do not…

Soft Condensed Matter · Physics 2015-06-11 Rodrigo Soto , Ramin Golestanian

In this article, we study the transport properties of superconcentrated electrolytes using Molecular Dynamics simulations, which have been shown experimentally to retard elemental dissolution in vanadium containing cathode materials. Five…

Materials Science · Physics 2021-11-30 Arijit Mitra , Saptarshi Das , Debasish Das , Subhasish B. Majumder , Siddhartha Das

The diffusivity of water in aqueous cesium iodide solutions is larger than that in neat liquid water, and vice versa for sodium chloride solutions. Such peculiar ion-specific behavior, called anomalous diffusion, is not reproduced in…

Chemical Physics · Physics 2023-10-26 Nikhil V. S. Avula , Michael L. Klein , Sundaram Balasubramanian

We propose a simple active hydrodynamic model for the self-propulsion of a liquid droplet suspended in micellar solutions. The self-propulsion of the droplet occurs by spontaneous breaking of isotropic symmetry and is studied using both…

Fluid Dynamics · Physics 2023-07-12 Swarnak Ray , Arun Roy

The effect of salt concentration Cs on the critical shear rate required for the onset of shear thickening and apparent relaxation time of the shear-thickened phase, has been investigated systematically for dilute CTAB/NaSal solutions.…

Fluid Dynamics · Physics 2009-11-13 Mukund Vasudevan , Amy Shen , Bamin Khomami , Radhakrishna Sureshkumar

In the framework of the model inter-comparison study - Asia Phase II (MICS2), where eight models are compared over East Asia, this paper studies the influence of different parameterizations used in the aerosol module on the aerosol…

Atmospheric and Oceanic Physics · Physics 2007-05-23 Karine Sartelet , Hiroshi Hayami , Bruno Sportisse

Surfactant self-assembly at solid-liquid interfaces governs interfacial stability, transport, and reactivity across many technologies, yet resolving interfacial surfactant phases and their transition kinetics in situ remains challenging.…

Magnetic fields are ubiquitously observed in the interstellar medium (ISM) of present-day star-forming galaxies with dynamically relevant energy densities. Using three-dimensional magneto-hydrodynamic (MHD) simulations of the supernova (SN)…

We have used molecular dynamics simulations to study the effect of water on the wetting behavior and the interfacial structure of ionic liquid (IL) 1-ethyl-3-methylimidazolium boron tetrafluoride[EMIM][BF4] droplets on graphite surfaces…

Chemical Physics · Physics 2020-12-09 Sanchari Bhattacharjee , Sandip Khan

In this paper we study the main surface characteristics which control the foamability of solutions of various surfactants. Experiments with anionic, cationic and nonionic surfactants with different head groups and chain lengths are…

Soft Condensed Matter · Physics 2019-12-18 B. Petkova , S. Tcholakova , M. Chenkova , K. Golemanov , N. Denkov , D. Thorley , S. Stoyanov

Concentrated fabric conditioners are water-based formulations containing 10 wt. % of cationic surfactants that are deposited on textile fibers during the rinse cycle in a washing machine to make them smoother and softer to touch. In topical…

The development of novel task-specific ionic liquids (ILs) represents an essential challenge in modern organic and physical chemistries. Recently we reported surface-active ILs contained the two well-known organic cations…

Soft Condensed Matter · Physics 2022-01-04 Vitaly V. Chaban

Surfactants are amphiphilic molecules that spontaneously self-assemble in aqueous solution into various ordered and disordered phases. Under certain conditions, one-dimensional structures in the form of long, flexible wormlike micelles can…

Soft Condensed Matter · Physics 2018-12-19 Christopher N. Lam , William D. Hong , Changwoo Do , Wei-Ren Chen

The solvation structures and ion dynamics of CaCl$_2$ aqueous electrolytes have been investigated using ab initio molecular dynamics simulations and molecular dynamics simulations with deep learning potentials. We found multiple solvation…

Chemical Physics · Physics 2023-07-20 Zhou Yu , Lei Cheng

Hypothesis: Ionic liquids have various applications in catalytic reaction environments. In those systems, their interaction with interfaces is key to their performance as a liquid phase. We hypothesize that the way a monolayer ionic liquid…

Soft Condensed Matter · Physics 2024-03-14 Kevin Höllring , Nataša Vučemilović-Alagić , David M. Smith , Ana-Sunčana Smith

Understanding interfacial phenomena in confined systems is important for optimizing CO2 capture technologies. Here, we present a comprehensive investigation of CO2 adsorption in hydrated amorphous silica nanopores through an integrated…

Materials Science · Physics 2025-02-12 Jihong Shi , Tao Zhang , Shuyu Sun , Liang Gong

Liquid-phase exfoliation of two-dimensional materials is very attractive for large-scale applications. Although used extensively, isolating MoS2 layers (<10) with high efficiency is reported to be extremely difficult. Further, the…

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