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Lead halide perovskite solar cells have recently emerged as a very promising photovoltaic technology due to their excellent power conversion efficiencies; however, the toxicity of lead and the poor stability of perovskite materials remain…

Materials Science · Physics 2017-03-10 Xiaolei Li , Xiangli Zhong , Yue Hu , Bochao Li , Yusong Sheng , Yang Zhang , Chao Weng , Ming Feng , Hongwei Han , Jinbin Wang

Lead-free vacancy-ordered perovskites (VOHPs) such as Cs2SnCl6 have emerged as promising materials for optoelectronic applications but typically suffer from wide band gaps and low photoluminescence quantum yields (PLQY). In this work, the…

Materials Science · Physics 2025-12-19 Shruti Prasad , Pabitra Kumar Nayak , Dibyajyoti Ghosh

Organic-inorganic hybrid halide perovskites have ignited tremendous interests for photovoltaic applications. However, their nonlinear optical response has not been studied although many of these structures lack the centrosymmetry and…

Materials Science · Physics 2020-02-14 Wenshen Song , Guang-Yu Guo , Su Huang , Lan Yang , Li Yang

Antiperovskite derivatives have recently emerged as promising lead-free alternatives to halide perovskites for optoelectronic applications. Here, using a comprehensive first-principles calculations including density functional perturbation…

Materials Science · Physics 2026-04-03 Surajit Adhikari , Aftab Alam , Priya Johari

Interfaces between the perovskite active layer and the charge-transport layers (CTLs) play a critical role in both efficiency and stability of halide-perovskite photovoltaics. One of the major concerns is that surface defects of perovskite…

Lead halide perovskite-based photoactive layers are nowadays employed for a large number of optoelectronic applications, from solar cells to photodetectors and light-emitting diodes, because of their excellent absorption, emission and…

Halide perovskites have emerged as a promising class of materials for photovoltaic applications. A challenge in these applications is how to prevent the crystal structure from degradation to photovoltaically inactive phases, which requires…

Materials Science · Physics 2024-03-22 Erik Fransson , J. Magnus Rahm , Julia Wiktor , Paul Erhart

The quest for environmentally benign and stable optoelectronic materials has intensified, and chalcogenide perovskites (CPs) have emerged as promising candidates owing to their non-toxic composition, stability, small bandgaps, large…

Materials Science · Physics 2025-02-21 Ayan Chakravorty , Surajit Adhikari , Priya Johari

Lead halide perovskites have attracted considerable attention as potential gas sensing elements due to their unique ability to detect and respond to an external stimulus with measurable electrical or optical signals. The distinctive…

Metal halides perovskites (MHPs) are attracting considerable interest for optoelectronic applications, with Cs$_2$AgBiBr$_6$ one of the main contenders among lead-free systems. Cs$_2$AgBiBr$_6$ crystallizes in a nominally double-perovskite…

Despite their puzzling vibrational characteristics that include strong signatures of anharmonicity and thermal disorder already around room temperature, halide perovskites exhibit favorable optoelectronic properties for applications in…

Materials Science · Physics 2022-02-08 Christian Gehrmann , Sebastián Caicedo-Dávila , Xiangzhou Zhu , David A. Egger

Hybrid organic-inorganic halide perovskites have emerged as a disruptive new class of materials, exhibiting optimum properties for a broad range of optoelectronic applications, most notably for photovoltaics. The first report of highly…

Materials Science · Physics 2018-08-21 Marina R. Filip , George Volonakis , Feliciano Giustino

Metal halide perovskites (MHPs) combine extraordinary optoelectronic properties with chemical and mechanical properties not found in their semiconductor counterparts. For instance, they exhibit optoelectronic properties on par with…

Applied Physics · Physics 2023-04-20 Bryan A. Rosales , Kelly Schutt , Joseph J. Berry , Lance M. Wheeler

Modelling the inorganic exciton contribution to 2D hybrid organic-inorganic perovskites is essential to understand their properties and screen for new materials. Here, we combine hybrid density functional theory calculations including spin…

Materials Science · Physics 2024-07-03 Svenja Janke

The halide double perovskite Cs$_2$AgBiBr$_6$ has been proposed as a potential replacement for organic halide perovskites for photovoltaic applications. Further investigation of its dielectric response, optical properties and structural…

In the past few years, the meteoric development of hybrid organic--inorganic perovskite solar cells (PSC) astonished the community. The efficiency has already reached the level needed for commercialization; however, the instability hinders…

Materials Science · Physics 2016-04-26 Fedwa El-Mellouhi , El Tayeb Bentria , Sergey N Rashkeev , Sabre Kais , Fahhad H Alharbi

The structural, vibrational, and optical properties of Rb$_2$TeBr$_6$ have been investigated under high pressure using synchrotron X-ray diffraction, Raman spectroscopy, photoluminescence (PL), and optical absorption measurements. At…

Materials Science · Physics 2026-04-20 Suvashree Mukherjee , Asish Kumar Mishra , K. A. Irshad , Boby Joseph , Goutam Dev Mukherjee

Lead halide perovskites (LHPs) are promising materials for opto-electronics and photovoltaics, thanks to favorable characteristics and low manufacturing costs enabled by solution processing. In light of this, it is crucial to assess the…

Materials Science · Physics 2021-10-01 Giovanni Procida , Richard Schier , Ana M. Valencia , Caterina Cocchi

Vacancy-ordered halide double perovskites Cs$_2BX_6$ have recently attracted significant attention due to their intrinsically ultralow lattice thermal conductivity ($\kappa_{\mathrm{L}}$), which is highly desirable for thermal insulation…

Materials Science · Physics 2026-02-09 Lingzhi Cao , Yateng Wang , Zhonghao Xia , Jiangang He

Organic-inorganic halide perovskites have been intensively re-investigated due to their applications, yet the opto-electronic function of the organic cation remains unclear. Through organic-selective resonant Auger electron spectroscopy…