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Chalcogenide perovskites (CPs) have emerged as promising materials for optoelectronic applications due to their stability, non-toxicity, small bandgaps, high absorption coefficients, and defect tolerance. Although transition metal-based…

Materials Science · Physics 2025-03-04 Surajit Adhikari , Sankhasuvra Das , Priya Johari

Metal halide perovskites have emerged as promising gain materials for on-chip lasers in photonic integrated circuits (PICs). However, stable continuous wave (CW) lasing behavior under optical pumping at room temperature - a prerequisite for…

Lead-free halide double perovskites provide a promising solution for the long-standing issues of lead-containing halide perovskites, i.e., the toxicity of Pb and the low stability under ambient conditions and high-intensity illumination.…

Materials Science · Physics 2024-06-14 Guang Wang , Jiongzhi Zheng , Jie Xue , Yixin Xu , Qiye Zheng , Geoffroy Hautier , Haipeng Lu , Yanguang Zhou

The long-term chemical instability and the presence of toxic Pb in otherwise stellar solar absorber APbX$_{3}$ have hindered their large-scale commercialization. Previously explored ways to achieve Pb-free halide perovskites involved…

Materials Science · Physics 2017-05-29 Xin-Gang Zhao , Dongwen Yang , Yuanhui Sun , Tianshu Li , Lijun Zhang , Liping Yu , Alex Zunger

Lead-free chalcogenide perovskites are emerging as game-changers in the race for sustainable, high-performance photovoltaics. These materials offer a perfect trifecta: non-toxic elemental composition, exceptional phase stability, and…

Materials Science · Physics 2025-09-19 Surajit Adhikari , Priya Johari

Double perovskite-based magnets wherein frustration and competition between emergent degrees of freedom are at play can lead to novel electronic and magnetic phenomena. Herein, we report the electronic structure and magnetic properties of…

Surface states are ubiquitous to semiconductors and significantly impact the physical properties and consequently the performance of optoelectronic devices. Moreover, surface effects are strongly amplified in lower dimensional systems such…

Chalcogenide perovskites have emerged as promising lead free materials for photovoltaic and thermoelectric applications. Among them, BaZrS3 has attracted particular attention due to its thermal and chemical stability, favorable…

Halide perovskites are a promising class of materials for optoelectronic applications, due to their excellent optoelectronic performance. However, they suffer several dynamical degradation problems, the characterization of which is…

Materials Science · Physics 2021-11-01 Sander Raaijmakers , Mike Pols , José Manuel Vicent-Luna , Shuxia Tao

Perovskite solar cells with record power conversion efficiency are fabricated by alloying both hybrid and fully inorganic compounds. While the basic electronic properties of the hybrid perovskites are now well understood, key electronic…

The great tunability of the properties of halide perovskites presents new opportunities for optoelectronic applications as well as significant challenges associated with exploring combinatorial chemical spaces. In this work, we develop a…

Materials Science · Physics 2021-09-23 Arun Mannodi-Kanakkithodi , Maria K. Y. Chan

Tin-based halide perovskites have emerged as promising lead-free alternatives for optoelectronic applications, yet their structural stability and phase behavior at finite temperatures remain challenging to predict. Here, we assess the…

Materials Science · Physics 2026-05-18 Thiago Puccinelli , Lucas Martin Farigliano , Gustavo Martini Dalpian

The discovery of stable, lead-free halide perovskites for optoelectronic applications is constrained by vast compositional space and limited interpretability of conventional screening approaches. We present a genome-guided, physics-informed…

Divalent cations mixed lead halide perovskites with enhanced performances, high stabilities, and reduced toxicity are requisite to make persistent progress in perovskite solar cells. However, the mixing strategy is not reported extensively…

Materials Science · Physics 2022-11-09 Anupriya Nyayban , Subhasis Panda , Avijit Chowdhury

In strongly correlated electronic systems, several novel physical properties are induced by the orbital degree of freedom. In particular, orbital degeneracy near the Fermi level leads to spontaneous symmetry breaking, such as the nematic…

Strongly Correlated Electrons · Physics 2021-02-02 Ling-Fang Lin , Nitin Kaushal , Yang Zhang , Adriana Moreo , Elbio Dagotto

We investigate the lead-free halide double perovskites (HDPs) Cs$ _2BB'X_6$ ($B$=Ag, Na; $B'$=In, Bi; $X$=Cl, Br) via first-principles calculations. We find that both the geometric and electric structures of the HDPs obtained by the…

Materials Science · Physics 2022-08-08 Yuyang Ji , Peize Lin , Xinguo Ren , Lixin He

The magnetic spin degrees of freedom in magnetic materials serve as additional capability to tune materials properties, thereby invoking magneto-optical response. Herein, we report the magneto-optoelectronic properties of a family of…

Materials Science · Physics 2023-10-25 Muskan Nabi , Sanika S. Padelkar , Jacek J. Jasieniak , Alexandr N. Simonov , Aftab Alam

Researchers have addressed the non-traditional power generation schemes as alternatives to the traditional fossil-fuel methods enormously since the scientific community has serious concerns about shortages of energy on our planet for future…

Materials Science · Physics 2022-11-02 Syed Zuhair Abbas Shah , Shanawer Niaz , Tabassum Nasir , James Sifuna

Organic or inorganic (A) metal (M) halide (X) perovskites (AMX3) are semiconductor materials setting the basis for the development of highly efficient, low-cost and multijunction solar energy conversion devices. The best efficiencies…

Materials Science · Physics 2018-10-17 Frederike Lehmann , Silvia Binet , Alexandra Franz , Andreas Taubert , Susan Schorr

We predict the structural, electronic and optic properties of the inorganic Ge-based halide perovskites AGeX3 (A = Cs, Rb; X = I, Br, Cl) by using first-principles method. In particular, absolute electronic energy band levels are calculated…

Materials Science · Physics 2018-10-08 Un-Gi Jonga , Chol-Jun Yu , Yun-Hyok Kye , Yong-Guk Choe , Hao Wei , Shuzhou Li
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