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The properties of a classical simple liquid can be strongly affected by application of an external potential that supports inhomogeneity. To understand the nature of these property changes the equilibrium particle distribution functions of…

Soft Condensed Matter · Physics 2018-06-29 Yan He , Stuart A. Rice , Xinliang Xu

The molecular density functional theory of fluids provides an exact theory for computing solvation free energies in implicit solvents. One of the reasons it has not received nearly as much attention as quantum density functional theory for…

Statistical Mechanics · Physics 2019-02-04 David M. Rogers

We use supervised machine learning together with the concepts of classical density functional theory to investigate the effects of interparticle attraction on the pair structure, thermodynamics, bulk liquid-gas coexistence, and associated…

Soft Condensed Matter · Physics 2025-01-29 Florian Sammüller , Matthias Schmidt , Robert Evans

In important early work, Stell showed that one can determine the pair correlation function h(r) of the hard sphere fluid for all distances r by specifying only the "tail" of the direct correlation function c(r) at separations greater than…

Statistical Mechanics · Physics 2007-05-23 Kirill Katsov , John D. Weeks

Model of hard sphere system is important part of modern theories of liquids. Radial distribution function of hard sphere fluid represented in form of explicit analytical expression allows to obtain thermodynamic potentials in analytical…

Statistical Mechanics · Physics 2016-10-11 Timur Aslyamov

The Ornstein-Zernike equation is a powerful tool in liquid state theory for predicting structural and thermodynamic properties of fluids. Combined with a suitable closure, it has been shown to reproduce e.g. the static structure factor,…

Soft Condensed Matter · Physics 2024-07-29 Ilian Pihlajamaa , Liesbeth M. C. Janssen

Some formulae are presented for finding two-integral distribution functions (DFs) which depends only on the two classical integrals of the energy and the magnitude of the angular momentum with respect to the axis of symmetry for stellar…

Mathematical Physics · Physics 2007-08-28 Zhenglu Jiang , Leonid Ossipkov

A first-principle multiscale modeling approach is presented, which is derived from the solution of the Ornstein-Zernike equation for the coarse-grained representation of polymer liquids. The approach is analytical, and for this reason is…

Soft Condensed Matter · Physics 2009-09-09 J. McCarty , I. Y. Lyubimov , M. G. Guenza

Line optical tweezer and colloidal-probe atomic force microscopy can measure force curves between two large colloidal particles of chemically the same surfaces in a suspension of small colloidal particles. Recently, the authors proposed a…

Soft Condensed Matter · Physics 2016-12-22 Ken-ichi Amano , Kota Hashimoto , Ryosuke Sawazumi

Two-molecule theory refers to a class of microscopic, self-consistent field theories for the radial distribution function in classical molecular liquids. The version examined here can be considered as one of the very few formally derived…

Soft Condensed Matter · Physics 2024-11-20 Huimin Li , James P. Donley , David T. Wu , John G. Curro , Caleb A. Tormey

By using the Rosenfeld density functional we determine the number density profiles of both components of binary hard-sphere fluids close to a planar hard wall as well as the corresponding excess coverage and surface tension. The comparison…

Soft Condensed Matter · Physics 2009-10-31 R. Roth , S. Dietrich

A thermodynamically self-consistent Ornstein-Zernike approximation (SCOZA) is applied to a fluid of spherical particles with a pair potential given by a hard-core repulsion and a Yukawa attractive tail $w(r)=-\exp [-z(r-1)]/r$. This…

Statistical Mechanics · Physics 2009-10-31 D. Pini , G. Stell , N. B. Wilding

The rich and diverse dynamics of particle-based systems ultimately originates from the coupling of their degrees of freedom via internal interactions. To arrive at a tractable approximation of such many-body problems, coarse-graining is…

Soft Condensed Matter · Physics 2022-03-31 Matthias Schmidt

Using liquid integral equation theory, we calculate the pair correlations of particles that interact via a smooth repulsive pair potential in d = 4 spatial dimensions. We discuss the performance of different closures for the…

Soft Condensed Matter · Physics 2015-10-09 M. Heinen , J. Horbach , H. Löwen

We have studied the structure and thermodynamic properties of isotropic three-dimensional core-softened fluid by using the second-order Ornstein-Zernike integral equations completed by the hypernetted chain and Percus-Yevick closures. The…

Soft Condensed Matter · Physics 2011-06-17 O. Pizio , Z. Sokolowska , S. Sokolowski

We prove convergence of the multi-body correlation function as a power series in the density. We work in the context of the cluster expansion in the canonical ensemble and we obtain bounds uniform in the volume and the number of particles.…

Mathematical Physics · Physics 2017-03-22 Tobias Kuna , Dimitrios Tsagkarogiannis

The radial polynomials of the 2D (circular) and 3D (spherical) Zernike functions are tabulated as powers of the radial distance. The reciprocal tabulation of powers of the radial distance in series of radial polynomials is also given, based…

Mathematical Physics · Physics 2010-01-07 Richard J. Mathar

Based on fundamental measure theory, a Helmholtz free energy density functional for three-component mixtures of hard spheres with general, non-additive interaction distances is constructed. The functional constitutes a generalization of the…

Soft Condensed Matter · Physics 2011-09-28 Matthias Schmidt

We measure the two-point density correlations and Voronoi cell distributions of cyclically sheared granular spheres obtained with a fluorescence technique and compare them with random packing of frictionless spheres. We find that the radial…

Materials Science · Physics 2015-05-14 Andreea Panaitescu , Arshad Kudrolli

The structural properties of single component fluids of hard hyperspheres in odd space dimensionalities $d$ are studied with an analytical approximation method that generalizes the Rational Function Approximation earlier introduced in the…

Statistical Mechanics · Physics 2011-11-10 Rene D. Rohrmann , Andres Santos
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