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A new approach to modelling the behaviour of simple fluids is presented. Starting from the usual expression of the partition function of N molecules, a Fourier transformation is performed. It is argued that the N(N-1)/2 dynamical variables…

Fluid Dynamics · Physics 2020-03-03 Richard Bonneville

We derive a dynamic Ornstein-Zernike equation for classical fluids undergoing overdamped Brownian motion and driven out of equilibrium. Inhomogeneous two-time correlation functions are obtained from functional differentiation of the…

Soft Condensed Matter · Physics 2013-10-31 Joseph M. Brader , Matthias Schmidt

In the density functional (DF) theory of Kohn and Sham, the kinetic energy of the ground state of a system of noninteracting electrons in a general external field is calculated using a set of orbitals. Orbital free methods attempt to…

Strongly Correlated Electrons · Physics 2009-11-13 Jeng-Da Chai , John D Weeks

Analytical expressions for radial distribution function (RDF) are of critical importance for various applications, such as development of the perturbation theories for equilibrium properties. Theoretically, RDF expressions for…

Statistical Mechanics · Physics 2023-10-20 Hongqin Liu

We investigate the spatial structure of dense square-shoulder fluids. To this end we derive analytical perturbative solutions of the Ornstein-Zernike equation in the low- and high-temperature limits as expansions around the known hard…

Statistical Mechanics · Physics 2020-06-08 O. Coquand , M. Sperl

We explore the self-propulsion of an active Ornstein-Uhlenbeck particle with a non-linear velocity dependent friction. Using analytical approach and numerical simulation, we have exactly investigated the dynamical behaviour of the particle…

Soft Condensed Matter · Physics 2024-05-15 N Arsha , M Sahoo

There are various routes for deriving partial radial distribution functions of disordered systems from experimental diffraction (and/or EXAFS) data. Due to limitations and errors of experimental data, as well as to imperfections of the…

Disordered Systems and Neural Networks · Physics 2012-07-16 Z. Steinczinger , L. Pusztai

We use the density functional method to examine the properties of the nonuniform (two-phase) fluid of two-level atoms, a part of which is excited. Basing on the analysis of the equation of state of a gas of two-level atoms, a part of which…

Soft Condensed Matter · Physics 2007-05-23 Oleg Derzhko , Vasyl Myhal

We present a scheme for investigating arbitrary thermal observables in spatially inhomogeneous equilibrium many-body systems. Extending the grand canonical ensemble yields any given observable as an explicit hyper-density functional.…

Soft Condensed Matter · Physics 2024-09-10 Florian Sammüller , Silas Robitschko , Sophie Hermann , Matthias Schmidt

Diffusion within porous media, such as biological tissues, exhibits departures from conventional Fick's laws, which could result in space-fractional diffusion. The paper considers a reaction-diffusion system with two spatial compartments --…

General Mathematics · Mathematics 2025-11-12 Dimiter Prodanov

Mixtures of hard hyperspheres in odd space dimensionalities are studied with an analytical approximation method. This technique is based on the so-called Rational Function Approximation and provides a procedure for evaluating equations of…

Soft Condensed Matter · Physics 2015-03-17 René D. Rohrmann , Andrés Santos

For quantum systems with two dimensional configuration space we construct a physical radial momentum observable. Rescaling the radius we find the dilatonic degrees of freedom form a Weyl algebra. With this we construct the radial Wigner…

Quantum Physics · Physics 2008-11-26 J. Twamley

We develop a novel method to simultaneously determine the vertical potential, force and stellar $z-v_z$ phase space distribution function (DF) in our local patch of the Galaxy. We assume that the Solar Neighborhood can be treated as a…

Astrophysics of Galaxies · Physics 2021-03-17 Haochuan Li , Lawrence M. Widrow

The current article completes our investigation of the hard-particle interaction by determining their distribution functionals. Beginning with a short review of the perturbation expansion of the free-energy functional, we derive two…

Soft Condensed Matter · Physics 2015-02-17 Stephan Korden

This thesis explores the evolution of liquid-state theories based on the Ornstein-Zernike (OZ) equation, summarizing the foundational methods developed by Baxter, Lebowitz, Wertheim, and others. A unifying feature of these approaches is…

Mathematical Physics · Physics 2026-04-07 Jianzhong Wu

We present a density functional scheme for calculating the pair density (PD) by means of the correlated wave function. This scheme is free from both of problems related to PD functional theory, i.e., (a) the need to constrain the…

Strongly Correlated Electrons · Physics 2015-06-25 Masahiko Higuchi , Katsuhiko Higuchi

A method for calculating pair correlation functions in a crystal is developed. The method is based on separating the one- and two- particle correlation functions into the symmetry conserving and the symmetry broken parts. The conserving…

Soft Condensed Matter · Physics 2015-06-19 Anubha Jaiswal , Atul S. Bharadwaj , Yashwant Singh

In this paper, we develop a Bernstein dual-Petrov-Galerkin method for the numerical simulation of a two-dimensional fractional diffusion equation. A spectral discretization is applied by introducing suitable combinations of dual Bernstein…

Numerical Analysis · Mathematics 2017-05-16 Mostafa Jani , Shahnam Javadi , Esmail Babolian , Dambaru Bhatta

In this paper we propose and explore a method of analysis of the scattering experimental data for uniform liquid-like systems. In our pragmatic approach we are not trying to introduce by hands an artificial small parameter to work out a…

Soft Condensed Matter · Physics 2018-01-24 E. I. Kats , A. R. Muratov

The rational function approximation method, density functional theory, and NVT Monte Carlo simulation are used to obtain the density profiles of multicomponent hard-sphere mixtures near a planar hard wall. Binary mixtures with a size ratio…

Statistical Mechanics · Physics 2007-06-06 Alexandr Malijevsky , Santos B. Yuste , Andres Santos , Mariano Lopez de Haro