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The physical impossibility of heat transfer under isothermal conditions implies that the classical expression for the entropy of the ideal gas may not be compatible with the internal energy of the gas itself. A corrected expression of the…

Statistical Mechanics · Physics 2023-09-01 A. Paglietti

We consider relaxation of an isolated system to the equilibrium using detailed balance condition and Onsager's fluctuation approximation. There is a small deviation from the equilibrium in two parameters. For this system, explicit…

Statistical Mechanics · Physics 2012-07-20 V. D. Seleznev , L. M. Martyushev

We propose a new form of the Second Law inequality that defines a tight bound for extractable work from the non-equilibrium quantum state. In classical thermodynamics, the optimal work is given by the difference of free energy, what…

Quantum Physics · Physics 2023-02-14 Marcin Łobejko

It is known that the equilibrium properties of open classical systems that are strongly coupled to a heat bath are described by a set of thermodynamic potentials related to the system's Hamiltonian of mean force. By adapting this framework…

Statistical Mechanics · Physics 2017-06-28 Harry J. D. Miller , Janet Anders

We consider a chain of particles connected by an-harmonic springs, with a boundary force (tension) acting on the last particle, while the first particle is kept pinned at a point. The particles are in contact with stochastic heat baths,…

Mathematical Physics · Physics 2020-01-23 Stefano Marchesani , Stefano Olla

In our recent letter [1] we discussed that thermodynamics is violated in quantum Brownian motion beyond the weak coupling limit. In his comment, Tasaki [2] derives an inequality for the relative entropy and claims, without making any…

Statistical Mechanics · Physics 2007-05-23 A. E. Allahverdyan , Th. M. Nieuwenhuizen

We study the evolution of Tsallis entropy along the heat flow and establish its concavity in arbitrary dimensions. Extending prior results that were restricted to the one-dimensional setting, we prove that the Tsallis entropy is concave in…

Information Theory · Computer Science 2026-04-24 Lukang Sun

This paper generalizes isomorph theory to systems that are not in thermal equilibrium. The systems are assumed to be R-simple, i.e., have a potential energy that as a function of all particle coordinates $\textbf{R}$ obeys the…

Soft Condensed Matter · Physics 2020-10-06 Jeppe C. Dyre

The second law of thermodynamics in nonextensive statistical mechanics is discussed in the quantum regime. Making use of the convexity property of the generalized relative entropy associated with the Tsallis entropy indexed by q, Clausius'…

Statistical Mechanics · Physics 2009-11-10 Sumiyoshi Abe , A. K. Rajagopal

We formulate, under general conditions, the problem of maximisation of the total entropy of the system, assumed to be in a composable form, for fixed total value of the constrained quantity. We derive the general form of the composability…

Statistical Mechanics · Physics 2009-11-10 Ramandeep S. Johal

The entropic form $S_q$ is, for any $q \neq 1$, {\it nonadditive}. Indeed, for two probabilistically independent subsystems, it satisfies $S_q(A+B)/k=[S_q(A)/k]+[S_q(B)/k]+(1-q)[S_q(A)/k][S_q(B)/k] \ne S_q(A)/k+S_q(B)/k$. This form will…

Data Analysis, Statistics and Probability · Physics 2014-11-18 Constantino Tsallis

We investigate the phenomenology leading to the non-conservation of energy of the continuous spontaneous localization (CSL) model from the viewpoint of non-equilibrium thermodynamics, and use such framework to assess the equilibration…

Statistical Mechanics · Physics 2023-12-29 Simone Artini , Mauro Paternostro

Thermal energy storage (TES) systems coupled with heat pumps offer significant potential for improving building energy efficiency by shifting electricity demand to off-peak hours. However, conventional operating strategies maintain…

Systems and Control · Electrical Eng. & Systems 2026-01-19 Ju-Hong Oh , Seon-In Kim , Eui-Jong Kim

Entanglement entropy is one of the most prominent measures in quantum physics. We show that it has an interesting ergotropic interpretation in terms of unitarily extracted work. It determines how much energy one can extract from a source of…

Quantum Physics · Physics 2023-06-16 Dominik Šafránek

The paper analyzes the entropy of a system composed by non-interacting and indistinguishable particles whose quantum state numbers are modelled as independent and identically distributed classical random variables. The crucial observation…

Statistical Mechanics · Physics 2023-05-18 Arnaldo Spalvieri

Thermodynamics have been applied to astronomy, biology, psychology, some social systems and so on. But, various evolutions from astronomy to biology and social systems cannot be only increase of entropy. When fluctuations are magnified due…

General Physics · Physics 2009-10-06 Yi-Fang Chang

In the present work we study the well-known Two Capacitor Problem from a new perspective. Although this problem has been thoroughly investigated, as far as we know there are no studies of the thermodynamic aspects of the discharge process.…

Classical Physics · Physics 2012-06-12 Vitor Lara , Alexandre P. Lima , Antônio T. Costa

We study thermodynamic limits when controllers operate with only partial observability of internal correlations in multipartite systems. Understanding the costs imposed by lack of information is crucial in settings where agents must act…

Statistical Mechanics · Physics 2025-09-25 Akihito Sudo

This paper addresses fundamental aspects of statistical mechanics such as the motivation of a classical state space with spontaneous transitions, the meaning of non-equilibrium in the context of thermalization, and the justification of…

Statistical Mechanics · Physics 2011-05-31 Haye Hinrichsen , Christian Gogolin , Peter Janotta

Through the consideration of spherically symmetric gravitating systems consisting of perfect fluids with linear equation of state constrained to be in a finite volume, an account is given of the properties of entropy at conditions in which…

General Relativity and Quantum Cosmology · Physics 2008-11-26 Alessandro Pesci