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We investigate the relation between various statistical ensembles of finite systems. If ensembles differ at the level of fluctuations of the order parameter, we show that the equations of states can present major differences. A sufficient…

Statistical Mechanics · Physics 2009-11-07 F. Gulminelli , Ph. Chomaz

Entropy in nonequilibrium statistical mechanics is investigated theoretically so as to extend the well-established equilibrium framework to open nonequilibrium systems. We first derive a microscopic expression of nonequilibrium entropy for…

Statistical Mechanics · Physics 2007-06-13 Takafumi Kita

The original canonical ensemble formalism for the nonextensive entropy thermostatistics is reconsidered. It is shown that the unambiguous connection of the statistical mechanics with the equilibrium thermodynamics is provided if the…

Statistical Mechanics · Physics 2009-11-11 A. S. Parvan

There is a dichotomy in the nonequilibrium dynamics of quantum many body systems. In the presence of integrability, expectation values of local operators equilibrate to values described by a generalized Gibbs ensemble, which retains…

Strongly Correlated Electrons · Physics 2019-05-15 Neil J. Robinson , Andrew J. A. James , Robert M. Konik

We consider an isolated, macroscopic quantum system. Let H be a micro-canonical "energy shell," i.e., a subspace of the system's Hilbert space spanned by the (finitely) many energy eigenstates with energies between E and E + delta E. The…

After the justification of the maximum entropy approach for equilibrium thermodynamic system, and of a maximum path entropy algorithm for nonequilibrium thermodynamic systems by virtue of the principle of virtual work, we present in this…

Statistical Mechanics · Physics 2007-12-18 Qiuping A. Wang

This paper investigates generalized thermodynamic relationships in physical systems where relevant macroscopic variables are determined by the exponential Kolmogorov-Nagumo average. We show that while the thermodynamic entropy of such…

Statistical Mechanics · Physics 2025-01-23 Pablo A. Morales , Jan Korbel , Fernando E. Rosas

A unified formulation of the density functional theory is constructed on the foundations of entropic inference in both the classical and the quantum regimes. The theory is introduced as an application of entropic inference for inhomogeneous…

Statistical Mechanics · Physics 2021-12-20 Ahmad Yousefi

Equilibrium statistical mechanics is intended to link the microscopic dynamics of particles to the thermodynamic laws for macroscopic quantities. However, the modern statistical theory is faced with significant difficulties, as applied to…

Statistical Mechanics · Physics 2016-03-15 A. G. Godizov , A. A. Godizov

We study the nature of and approach to thermal equilibrium in isolated quantum systems. An individual isolated macroscopic quantum system in a pure or mixed state is regarded as being in thermal equilibrium if all macroscopic observables…

Quantum Physics · Physics 2017-08-15 Sheldon Goldstein , David A. Huse , Joel L. Lebowitz , Roderich Tumulka

The most complicated phenomena of equilibrium statistics, phase separations and transitions of various order and critical phenomena, can clearly and sharply be seen even for small systems in the topology of the curvature of the…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

The maximum entropy principle from statistical mechanics states that a closed system attains an equilibrium distribution that maximizes its entropy. We first show that for graphs with fixed number of edges one can define a stochastic edge…

Disordered Systems and Neural Networks · Physics 2007-05-23 Jesse S. A. Bridgewater , P. Oscar Boykin , Vwani P. Roychowdhury

We show how the macroscopic state variables pressure, entropy and temperature of equilibrium thermodynamics can be consistently derived from the (quantum) chaotic spectral structure of one or two particles in two-dimensional domains. This…

Electro-energy-reaction-diffusion systems are thermodynamically consistent continuum models for reaction-diffusion processes that account for temperature and electrostatic effects in a way that total charge and energy are conserved. The…

Analysis of PDEs · Mathematics 2026-04-09 Katharina Hopf , Michael Kniely , Alexander Mielke

We consider the thermal equilibrium distribution at inverse temperature $\beta$, or canonical ensemble, of the wave function $\Psi$ of a quantum system. Since $L^2$ spaces contain more nondifferentiable than differentiable functions, and…

Mathematical Physics · Physics 2007-05-23 Roderich Tumulka , Nino Zanghi

In quantum statistical mechanics, equilibrium states have been shown to be the typical states for a system that is entangled with its environment, suggesting a possible identification between thermodynamic and von Neumann entropies. In this…

Quantum Physics · Physics 2017-06-28 Thibaut Josset

This study shows that the generalized Boltzmann distribution is the only distribution mathematically consistent with thermodynamics when the system is described by an ensemble of a certain mathematical form. This mathematical form is very…

Statistical Mechanics · Physics 2022-02-10 Xiang Gao

A classical particle system coupled with a thermostat driven by an external constant force reaches its steady state when the ensemble-averaged drift velocity does not vary with time. The statistical mechanics of such a system is derived…

Statistical Mechanics · Physics 2020-12-02 Jie Yao , Yanting Wang

The recent remarkable developments in quantum optics, mesoscopic and cold atom physics have given reality to wave functions. It is then interesting to explore the consequences of assuming ensembles over the wave functions simply related to…

Quantum Physics · Physics 2010-12-13 Giovanni Jona-Lasinio , Carlo Presilla

Understanding the rich spatial and temporal structures in nonequilibrium thermal environments is a major subject of statistical mechanics. Because universal laws, based on an ensemble of systems, are mute on an individual system, exploring…

Statistical Mechanics · Physics 2019-04-19 Liyi Zhao , Ping Fang , Chushun Tian