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We prove the second law of thermodynamics and the nonequilibirum fluctuation theorem for pure quantum states.The entire system obeys reversible unitary dynamics, where the initial state of the heat bath is not the canonical distribution but…

Statistical Mechanics · Physics 2017-09-13 Eiki Iyoda , Kazuya Kaneko , Takahiro Sagawa

We set up a framework for quantum stochastic thermodynamics based solely on experimentally controllable, but otherwise arbitrary interventions at discrete times. Using standard assumptions about the system-bath dynamics and insights from…

Quantum Physics · Physics 2019-08-22 Philipp Strasberg

Quantum entanglement is commonly assumed to be fragile at ambient temperature and over macroscopic distances, where thermal noise and dissipation are expected to rapidly suppress nonclassical correlations. Here we show that this intuition…

Quantum Physics · Physics 2025-12-30 Shalender Singh , Santosh Kumar

We study a particle immersed in a heat bath, in the presence of an external force which decays at least as rapidly as $1/x$, for example a particle interacting with a surface through a Lennard-Jones or a logarithmic potential. As time…

Statistical Mechanics · Physics 2019-01-09 Erez Aghion , David A. Kessler , Eli Barkai

The present paper studies a large class of temperature dependent probability distributions and shows that entropy and energy can be defined in such a way that these probability distributions are the equilibrium states of a generalized…

Statistical Mechanics · Physics 2015-06-24 Jan Naudts

In this work we present a formalism to describe non equilibrium conditions in systems with a discretized energy spectrum, such as quantum systems. We develop a formalism based on a combination of Gibbs-Shannon entropy and information…

Statistical Mechanics · Physics 2013-07-23 Alessio Gagliardi , Alessandro Pecchia , Aldo Di Carlo

Preparing thermal equilibrium states is an essential task for finite-temperature quantum simulations. In statistical mechanics, microstates in thermal equilibrium can be obtained from statistical ensembles. To date, numerous ensembles have…

Quantum Physics · Physics 2025-05-23 Yasushi Yoneta

If we prepare an isolated, interacting quantum system in an eigenstate and perturb a local observable at an initial time, its expectation value will relax towards a thermal expectation value, even though the time evolution of the system is…

Quantum Physics · Physics 2024-06-04 Tobias Helbig , Tobias Hofmann , Ronny Thomale , Martin Greiter

The physical significance of the stochastic processes associated to the generalized Gibbs ensembles is scrutinized here with special attention to the thermodynamic fluctuations of small systems. The contact with the environment produces an…

Statistical Mechanics · Physics 2024-09-04 Amilcare Porporato , Salvatore Calabrese , Lamberto Rondoni

Small systems consisting of a few particles are increasingly technologically relevant. In such systems, an intense debate in microcanonical statistical mechanics has been about the correctness of Boltzmann's surface entropy versus Gibbs'…

Statistical Mechanics · Physics 2024-09-20 Ananth Govind Rajan

We deal with a generalized statistical description of nonequilibrium complex systems based on least biased distributions given some prior information. A maximum entropy principle is introduced that allows for the determination of the…

Statistical Mechanics · Physics 2009-11-13 Erik Van der Straeten , Christian Beck

All ensembles of statistical mechanics are equivalent in the sense that they give the equivalent thermodynamic functions in the thermodynamic limit. However, when investigating microscopic structures in the first-order phase transition…

Statistical Mechanics · Physics 2019-05-13 Yasushi Yoneta , Akira Shimizu

We derive a systematic approach to the thermodynamics of quantum systems based on the underlying symmetry groups. We show that the entropy of a system can be described in terms of group-theoretical quantities that are largely independent of…

A positive rate of entropy production at steady state is a distinctive feature of truly non-equilibrium processes. Exact results, while being often limited to simple models, offer a unique opportunity to explore the thermodynamic features…

Statistical Mechanics · Physics 2022-06-29 Henry Alston , Luca Cocconi , Thibault Bertrand

Predicting the stationary behavior of observables in isolated many-body quantum systems is a central challenge in quantum statistical mechanics. While one can often use the Gibbs ensemble, which is simple to compute, there are many…

Quantum Physics · Physics 2025-07-30 Lodovico Scarpa , Abdulla Alhajri , Vlatko Vedral , Fabio Anza

At the core of equilibrium statistical mechanics lies the notion of statistical ensembles: a collection of microstates, each occurring with a given a priori probability that depends only on a few macroscopic parameters such as temperature,…

Statistical Mechanics · Physics 2015-06-19 Dapeng Bi , Silke Henkes , Karen E. Daniels , Bulbul Chakraborty

We consider ensembles of pure Gaussian states parametrized by single-mode marginals and (optionally) specific mode-mode correlations. Such ensembles provide a model for the final states when isolated quantum systems thermalize, as they can…

Quantum Physics · Physics 2026-03-24 Erik Aurell , Lucas Hackl , Mario Kieburg

A new method is proposed for a treatment of ideal quantum gases in the microcanonical ensemble near the thermodynamic limit. The method allows rigorous asymptotic calculations of the average number of particles and particle number…

Nuclear Theory · Physics 2011-07-19 V. V. Begun , M. I. Gorenstein , A. P. Kostyuk , O. S. Zozulya

The random matrix ensembles (RME) of quantum statistical Hamiltonians, e.g. Gaussian random matrix ensembles (GRME) and Ginibre random matrix ensembles (Ginibre RME), are applied in literature to following quantum statistical systems:…

Statistical Mechanics · Physics 2007-05-23 Maciej M. Duras

A generalization of the Gibbs entropy postulate is proposed based on the BBGKY hierarchy as the nonequilibrium entropy for a system of N interacting particles. This entropy satisfies the basic principles of thermodynamics in the sense that…

Statistical Mechanics · Physics 2007-05-23 A. Perez-Madrid