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In perovskite solar cells, photovoltaic action is created by charge transport layers (CTLs) either side of the light-absorbing metal halide perovskite semiconductor. Hence, the rates for desirable charge extraction and unwanted interfacial…

Thin-film solar cells suffer from various types of recombination, of which leakage current usually dominates at lower voltages. Herein, we demonstrate first a three-order reduction of the shunt loss mechanism in planar methylammonium lead…

Halide perovskite solar cells have demonstrated a rapid increase in power conversion efficiencies. Understanding and mitigating remaining carrier losses in halide perovskites is now crucial to enable further increases to approach their…

The ability to spatially resolve the carrier mobility profile along the cross section of micrometer-thin solar cells is vital both for fundamental studies in photovoltaics and as a quality control for reproducibly obtaining high conversion…

Applied Physics · Physics 2024-01-15 Noah B. Stocek , Miguel J. Young , Reg Bauld , Tianhao Ouyang , Giovanni Fanchini

The unprecedented rise in power conversion efficiency of solar cells based on metal halide perovskites (MHPs) has led to enormous research effort to understand their photo-physical properties. In this paper, we review the progress in…

Applied Physics · Physics 2020-07-10 Tom J. Savenije , Dengyang Guo , Valentina M. Caselli , Eline M. Hutter

Charge transport layers (CTLs) are key components of diffusion controlled perovskite solar cells, however, they can induce additional non-radiative recombination pathways which limit the open circuit voltage (V_OC) of the cell. In order to…

Carrier recombination is a process that significantly influences the performance of semiconductor devices such as solar cells, photodiodes, and light-emitting diodes (LEDs). Therefore, a model that can accurately describe and quantify the…

Applied Physics · Physics 2022-04-11 M. L. Inche Ibrahim , Anvar A. Zakhidov

The effective conductivity determines the reciprocal of the transport resistance, the dominant loss of fill factor in organic solar cells. We experimentally determine the dependence of effective conductivity on its electron and hole…

Materials Science · Physics 2025-08-18 Chen Wang , Toni Seiler , Doyoung Sun , Safa Shoaee , Maria Saladina , Carsten Deibel

Stability is one of the most important challenges facing organic solar cells (OSC) on their path to commercialization. In the high-performance material system PM6:Y6 studied here, investigate degradation mechanisms of inverted photovoltaic…

The power conversion efficiency (PCE) of organic solar cells (OSCs) has been largely improved by the introduction of novel non-fullerene acceptors (NFAs). Further improvements in PCE require a more comprehensive understanding of the free…

Materials Science · Physics 2024-11-14 Phillip Teschner , Atul Shukla , Dieter Neher

Recombination losses contribute to reduce $J_{SC}$, $V_{OC}$ and the fill factor of organic solar cells. Recent advances in non-fullerene organic photovoltaics have shown, nonetheless, that efficient charge generation can occur under small…

Materials Science · Physics 2022-11-24 Artur M. Andermann , Luis G. C. Rego

Charge carrier recombination is studied in operational organic solar cells made from the polymer:fullerene system PCDTBT:PC71BM (poly[N-9"-heptadecanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)] :…

Organic solar cells are a promising avenue for renewable energy, and our study introduces a comprehensive model to investigate exciton dissociation processes at the donor-acceptor interface. Examining quantum efficiency and emitted phonons…

Materials Science · Physics 2025-02-05 Jouda Jemaa Khabthani , Khouloud Chika , Alexandre Perrin , Didier Mayou

The steady-state distribution of carrier concentrations in a solar cell under operating conditions is a key source of carrier recombination and directly influences the output current density. In this study, we investigated the effects of…

Materials Science · Physics 2024-11-01 Isshin Sumiyoshi , Yoshitaro Nose

Transient photovoltage (TPV) and voltage dependent charge extraction (CE) measurements were applied to poly(3-hexylthiophene)(P3HT):[6,6]-phenyl-C61 butyric acid methyl ester (PCBM) bulk heterojunction solar cells to analyze the limitations…

Materials Science · Physics 2012-08-23 Markus Gluecker , Alexander Foertig , Vladimir Dyakonov , Carsten Deibel

Recently, much effort has been devoted to improve the efficiency of organic photovoltaic solar cells based on blends of donors and acceptors molecules in bulk heterojunction architecture. One of the major losses in organic photovoltaic…

Materials Science · Physics 2013-03-05 Ye Zhang , Tek P. Basel , Bhoj R. Gautam , Xiaomei Yang , Debra J. Mascaro , Feng Liu , Z. Valy Vardeny

Non-fullerene acceptors based on perylenediimides (PDIs) have garnered significant interest as an alternative to fullerene acceptors in organic photovoltaics (OPVs), but their charge transport phenomena are not well understood, especially…

The kinetics of the charge carrier recombination in dye molecule-doped multilayer organic light-emitting diodes (OLEDs) was quantified by transient electroluminescence (EL). Three sets of dye molecules, such as derivatives of naphthalimide…

Materials Science · Physics 2014-11-13 Shengwei Shi , Feng Gao , Zhengyi Sun , Yiqiang Zhan , Mats Fahlman , Dongge Ma

The ABC model has been widely used to describe the carrier recombination rate, in which the rate of non-radiative recombination assisted by deep-level defects is assumed to depend linearly on excess carrier density $\Delta n$, leading to a…

Materials Science · Physics 2025-02-25 Shanshan Wang , Menglin Huang , Su-Huai Wei , Xin-Gao Gong , Shiyou Chen

The photoluminescence in amorphous semiconductors decays according to power law $t^{-delta}$ at long times. The photoluminescence is controlled by dispersive transport of electrons. The latter is usually characterized by the power $alpha$…

Statistical Mechanics · Physics 2009-11-11 Kazuhiko Seki , Mariusz Wojcik , M. Tachiya