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The dependence of the actual/effective ionic concentration on the nominal salt concentration is experimentally investigated for aqueous solutions of NaCl and KCl. The actual ionic bulk density is determined by means of the impedance…

Chemical Physics · Physics 2022-04-04 G. Barbero , N. G. Fytas , I. Lelidis , J. V. da Silva Andrade , F. C. M. Freire , A. J. Santana

A system of reduced equations is proposed for the electron motion in the strongly-radiation dominated regime for an arbitrary electromagnetic field configuration. The developed approach is used to analyze various scenarios of an electron…

Plasma Physics · Physics 2023-01-06 A. S. Samsonov , E. N. Nerush , I. Yu. Kostyukov

A theoretical description of time correlation functions for electron properties in the presence of a positive ion of charge number Z is given. The simplest case of an electron gas distorted by a single ion is considered. A semi-classical…

Statistical Mechanics · Physics 2009-11-13 Jeffrey M. Wrighton , James W. Dufty

We study, globaly in time, the velocity distribution $f(v,t)$ of a spatially homogeneous system that models a system of electrons in a weakly ionized plasma, subjected to a constant external electric field $E$. The density $f$ satisfies a…

Plasma Physics · Physics 2009-10-30 E. Carlen , R. Esposito , J. L. Lebowitz , R. Marra , A. Rokhlenko

Studies of the thermodynamics of complex coacervation of pairs of symmetric, strongly ionizable, oppositely charged polyelectrolyte chains are abundant. To generalize such understanding to asymmetric chain lengths and variable ionizability…

Soft Condensed Matter · Physics 2023-06-07 Souradeep Ghosh , Soumik Mitra , Arindam Kundagrami

We study dynamics of clustering in systems containing active particles that are immersed in an explicit solvent. For this purpose we have adopted a hybrid simulation method, consisting of molecular dynamics and multi-particle collision…

Soft Condensed Matter · Physics 2021-01-01 Arabinda Bera , Soudamini Sahoo , Snigdha Thakur , Subir K. Das

We developed a new physical model to predict macroscopic properties of inorganic molten systems using a realistic description of inter-atomic interactions. Unlike the conventional approach, which tends to overestimate viscosity by several…

Materials Science · Physics 2015-06-04 Vitaly V. Chaban , Yuriy V. Pereverzev , Oleg V. Prezhdo

A mesoscopic theory for water-in-salt electrolytes combining density functional and field-theoretic methods is developed in order to explain the unexpectedly large period of the oscillatory decay of the disjoining pressure observed in…

Soft Condensed Matter · Physics 2021-09-29 Oksana Patsahan , Alina Ciach

Understanding electron and ion heating phenomenon in capacitively coupled radio-frequency plasma discharges is vital for many plasma processing applications. In this article, using particle-in-cell simulation technique we investigate the…

Plasma Physics · Physics 2023-09-26 Sarveshwar Sharma , Nishant Sirse , Miles M Turner , Animesh Kuley

Rayleigh-Taylor (RT) instability commonly arises in compressible systems with time-dependent acceleration in practical applications. To capture the complex dynamics of such systems, a two-component discrete Boltzmann method is developed to…

Fluid Dynamics · Physics 2025-04-08 Huilin Lai , Chuandong Lin , Hao Xu , Hailong Liu , Demei Li , Bailing Chen

Interacting-Particle Reaction Dynamics (iPRD) simulates the spatiotemporal evolution of particles that experience interaction forces and can react with one another. The combination of interaction forces and reactions enable a wide range of…

Chemical Physics · Physics 2018-07-20 Christoph Fröhner , Frank Noé

We propose that the space-time evolution of strongly coupled matter formed by ultra-relativistic heavy ion collisions can be modelled by phenomenological equations involving the energy-momentum tensor and conserved currents alone. These…

High Energy Physics - Theory · Physics 2011-11-18 Ramakrishnan Iyer , Ayan Mukhopadhyay

Phase separation in salt-free symmetric mixtures of oppositely charged rodlike polyelectrolytes is studied using quasi-analytical calculations. Stability analyses for the isotropic-isotropic and the isotropic-nematic phase transitions in…

Soft Condensed Matter · Physics 2010-07-20 Rajeev Kumar , Debra Audus , Glenn H. Fredrickson

Classical theory of the electric double layer is based on the fundamental assumption of a dilute solution of point ions. There are a number of situations such as high applied voltages, high concentration of electrolytes, systems with…

Fluid Dynamics · Physics 2015-06-11 Brian D. Storey , Martin Z. Bazant

The dynamics of electrons in the presence of a positive ion is considered for conditions of weak electron-electron couping but strong electron-ion coupling. The equilibrium electron density and electric field time correlation functions are…

Statistical Mechanics · Physics 2007-05-23 James W. Dufty , Ilya V. Pogorelov , Bernard Talin , Annette Calisti

A crucial aspect in the simulation of electrochemical interfaces consists in treating the distribution of electronic charge of electrode materials that are put in contact with an electrolyte solution. Recently, it has been shown how a…

Materials Science · Physics 2024-07-16 Andrea Grisafi , Mathieu Salanne

Ionic liquids are promising candidates for novel electrolytes as they possess large electrochemical and thermodynamic stability and offer a high degree of tunability. As purely-ionic electrolyte without neutral solvent they exhibit…

Chemical Physics · Physics 2022-01-12 Max Schammer , Birger Horstmann , Arnulf Latz

We present a rigorous thermodynamic treatment of irreversible binary aggregation. We construct the Smoluchowski ensemble as the set of discrete finite distributions generated from the same initial state of all monomers upon fixed number…

Statistical Mechanics · Physics 2020-11-16 Themis Matsoukas

We investigate the effect of adsorption-desorption phenomenon of ions in an asymmetric electrolytic cell at open circuit conditions. Our approach is based on the Poisson-Nernst-Planck theory for electrolytes and the kinetic model of…

Chemical Physics · Physics 2017-12-06 S. Bousiadi , I. Lelidis

We develop a first-principle equation of state of salt-free polyelectrolyte solution in the limit of infinitely long flexible polymer chains in the framework of a field-theoretical formalism beyond the linear Debye-Hueckel theory and…

Soft Condensed Matter · Physics 2015-08-04 Yu. A. Budkov , A. L. Kolesnikov , N. Georgi , E. A. Nogovitsyn , M. G. Kiselev
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