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Crystal structure searching and ab initio calculations have been used here to explore low-energy structures of boron carbides under high pressure. Under pressures of 85-110 GPa, a metastable B6C with R-3m symmetry is found to be…

Materials Science · Physics 2018-01-01 Kang Xia , Mengdong Ma , Cong Liu , Hao Gao , Qun Chen , Julong He , Jian Sun , Hui-Tian Wang , Yongjun Tian , Dingyu Xing

Hexagonal BC$_{2}$N is a superhard material recently identified to be comparable to or even harder than cubic boron nitride (c-BN) due the full $sp^3$ bonding character and the higher number of C-C and B-N bonds compared to C-N and…

Materials Science · Physics 2020-03-30 Safoura Nayeb Sadeghi , S. Mehdi Vaez Allaei , Mona Zebarjadi , Keivan Esfarjani

We explore both experimental and theoretical aspects of the superconducting properties in the distinctive layered caged compound, Ba$_{3}$Ir$_{4}$Ge$_{16}$. Our approach integrates muon spin rotation and relaxation ($\mu$SR) measurements…

Boron in MgB_2 forms layers of honeycomb lattices with magnesium as a space filler. Band structure calculations indicate that Mg is substantially ionized, and the bands at the Fermi level derive mainly from B orbitals. Strong bonding with…

Superconductivity · Physics 2009-11-07 J. Kortus , I. I. Mazin , K. D. Belashchenko , V. P. Antropov , L. L. Boyer

Iron chalcogenide superconductors are multi-band systems with strong electron correlations. Here we use angle-resolved photoemission spectroscopy to study band dependent correlation effects in single-layer FeSe/Nb:BaTiO3/KTaO3, a new iron…

Superconductivity · Physics 2016-09-28 Y. J. Pu , Z. C. Huang , H. C. Xu , D. F. Xu , Q. Song , C. H. P. Wen , R. Peng , D. L. Feng

Engineering materials with high thermal conductivity are of fundamental interest for efficiently dissipating heat in micro/nanoelectronics. Using first principles computations we report an ultra-high thermal conductivity of 2090 Wm-1K-1…

Materials Science · Physics 2021-07-12 Rajmohan Muthaiah , Jivtesh Garg

Being the simplest element with just one electron and proton the electronic structure of the Hydrogen atom is known exactly. However, this does not hold for the complex interplay between them in a solid and in particular not at high…

Materials Science · Physics 2014-06-23 Sam Azadi , Thomas D. Kühne

Due to its low atomic mass hydrogen is the most promising element to search for high-temperature phononic superconductors. However, metallic phases of hydrogen are only expected at extreme pressures (400 GPa or higher). The measurement of a…

Superconductivity · Physics 2016-03-23 José A. Flores-Livas , Antonio Sanna , E. K. U. Gross

We model monolayer graphene-like materials with BC$_6$N stoichiometry where the bonding between the B and the N atoms plays an important role for their physical and chemical properties. Two types of BC$_6$N are found based on the BN bonds:…

Mesoscale and Nanoscale Physics · Physics 2020-08-26 Nzar Rauf Abdullah , Hunar Omar Rashid , Chi-Shung Tang , Andrei Manolescu , Vidar Gudmundsson

Superconductivity in two-dimensional compounds is widely concerned, not only due to its application in constructing nano-superconducting devices, but also for the general scientific interests. Very recently, borophene (two-dimensional boron…

Superconductivity · Physics 2017-01-13 Miao Gao , Qi-Zhi Li , Xun-Wang Yan , Jun Wang

The uniquely characteristic macrostructures of binary hydrogen-clathrate compounds $M$H$_\textrm{n}$ formed at high pressure, a cage of hydrogens surrounding a central-atom host, is theoretically predicted in various studies to include…

Superconductivity · Physics 2020-06-22 Dale R. Harshman , Anthony T. Fiory

Crystalline two-dimensional (2D) superconductors with low carrier density are an exciting new class of materials in which superconductivity coexists with strong interactions, the effects of complex topology are not obscured by disorder, and…

Since the discovery of superconductivity at 200 K in H3S [1] similar or higher transition temperatures, Tcs, have been reported for various hydrogen-rich compounds under ultra-high pressures [2]. Superconductivity was experimentally proved…

Hexagonal boron nitride (h-BN) is unique among two-dimensional materials, with a large band gap (~6 eV) and high thermal conductivity (>400 W/m/K), second only to diamond among electrical insulators. Most electronic studies to date have…

Two possible phases of superhard material BC3 originating from the cubic diamond structure are investigated by ab initio pseudopotential density functional method using generalized gradient approximation (GGA). We calculate their elastic…

Superconductivity · Physics 2010-02-06 M. M. Ali , A. K. M. A. Islam , F. Parvin , M. Aftabuzzaman

Cs$_3$C$_{60}$ in the A15 structure is an antiferromagnet at ambient pressure in contrast with other superconducting trivalent fullerides. Superconductivity is recovered under pressure and reaches the highest critical temperature of the…

Superconductivity · Physics 2012-10-23 G. Giovannetti , M. Capone

The two-dimensional electron gas at the LaTiO3/SrTiO3 or LaAlO3/SrTiO3 oxide interfaces becomes superconducting when the carrier density is tuned by gating. The measured resistance and superfluid density reveal an inhomogeneous…

Recent experimental developments in hydrogen-rich materials in high pressures have put this class of materials above others in the race toward room temperature superconductivity. As it is the basis of all the materials in this class, the…

Superconductivity · Physics 2022-02-03 Mehmet Dogan , Sehoon Oh , Marvin L. Cohen

Recently, a honeycomb borophene was reported to grow successfully on Al(111) surface. Since the metallic $\sigma$-bonding bands of honeycomb boron sheet play a crucial role in the 39 K superconductivity of MgB$_2$, it is physically…

Superconductivity · Physics 2019-07-12 Miao Gao , Xun-Wang Yan , Jun Wang , Zhong-Yi Lu , Tao Xiang

Fullerene solids doped with alkali metals (A$_3$C$_{60}$, A = K, Rb, Cs) exhibit a superconducting transition temperature ($T_c$) as high as 40 K, and their unconventional superconducting properties have been a subject of debate. With…

Superconductivity · Physics 2023-10-24 Jianyu Li , Zhangkai Cao , Jiahao Su , Ruipeng Wang , Haipeng Li , Yusuke Nomura , Xiaosen Yang , Ho-Kin Tang