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The coexistence of multiple structural phases and field induced short-range to long-range order transition in ferroelectric materials, leads to a strong electrocaloric effect (ECE) and electrical energy storage density (Wrec) in the…

Compression of greenhouse gases still dominates the market of refrigeration devices. Although well stablished and efficient, this technology is neither safe for the environment nor able to be scaled down to nanoscale. Solid-state cooling…

Mesoscale and Nanoscale Physics · Physics 2022-10-14 Tatiana Naomi Yamamoto Silva , Alexandre F. Fonseca

Analytical results obtained within Landau-Ginzburg-Devonshire approach and effective media models, predict that the synergy of size effects and Vegard stresses can significantly enhance the electrocaloric cooling (up to 7 times) of the…

Solid-state cooling applications based on the electrocaloric (EC) effect are particularly promising from a technological point of view due to their downsize scalability and natural implementation in circuitry. However, EC effects typically…

Materials Science · Physics 2023-07-19 César Menéndez , Claudio Cazorla

An atomistic effective Hamiltonian is used to investigate electrocaloric (EC) effects of Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) relaxor ferroelectrics in its ergodic regime, and subject to electric fields applied along the pseudocubic [111]…

Materials Science · Physics 2018-04-03 Zhijun Jiang , Y. Nahas , S. Prokhorenko , S. Prosandeev , D. Wang , Jorge Íñiguez , L. Bellaiche

Electrocaloric (EC) materials show promise in eco-friendly solid-state refrigeration and integrable on-chip thermal management. While direct measurement of EC thin-films still remains challenging, a generic theoretical framework for…

Materials Science · Physics 2021-04-21 Yuping Shi , Limin Huang , Ai Kah Soh , George J. Weng , Shuangyi Liu , Simon A. T. Redfern

Relaxor ferroelectric thin films are recognized for their ultrahigh power density, rendering them highly promising for energy storage applications in electrical and electronic systems. However, achieving high energy storage performance with…

The electrocaloric (EC) effect and energy storage properties of eco-friendly ferroelectric Ba0.9Sr0.1Ti1-xSnxO3 (BSTS-x) ceramics prepared by the conventional solid-state reaction method were studied. Significant energy efficiency exceeding…

Elastocaloric cooling has been identified as a promising alternative to high global warming potential vapor compression cooling. Two key bottlenecks to adoption are the need for bulky/expensive actuators to provide sufficient uniaxial…

Materials Science · Physics 2021-05-19 Darin J. Sharar , Joshua Radice , Ronald Warzoha , Brendan Hanrahan , Andrew Smith

Atomistic effective Hamiltonian simulations are used to investigate electrocaloric (EC) effects in the lead-free Ba(Zr$_{0.5}$Ti$_{0.5}$)O$_{3}$ (BZT) relaxor ferroelectric. We find that the EC coefficient varies non-monotonically with the…

Materials Science · Physics 2017-07-25 Zhijun Jiang , Sergei Prokhorenko , Sergey Prosandeev , Y. Nahas , D. Wang , J. Íñiguez , E. Defay , L. Bellaiche

Combining our comprehensive investigations of polarization evolution, soft-mode by Raman scattering and microstructure by TEM, and the results reported in the literatures, we show that prototypical relaxor Pb(Mg1/3Nb2/3)O3 (PMN) is…

Materials Science · Physics 2013-01-17 Desheng Fu , Hiroki Taniguchi , Mitsuru Itoh , Shigeo Mori

The electrocaloric (EC) effect offers a promising energy-efficient and clean cooling technology. We present the first direct measurements of EC temperature change in a new family of EC fluids, ferroelectric nematic liquid crystals (FNLCs),…

Electric field dependent mechanical properties of relaxor ferroelectric material Pb(Mn1/3Nb2/3)O3-PbTiO3 are investigated with the nanoindentation technique. Giant electric-field-tunable apparent elastic modulus (up to -39%), hardness (-9%…

Mesoscale and Nanoscale Physics · Physics 2014-02-12 Hao Zhou , Yongmao Pei , Faxin Li , Haosu Luo , Daining Fang

Using a combination of resistance fluctuation (noise) and dielectric spectroscopy we investigate the nature of relaxor-type electronic ferroelectricity in the organic conductor $\kappa$-(BETS)$_2$Mn[N(CN)$_2$]$_3$, a system representative…

Spatial variability of polarization relaxation kinetics in relaxor ferroelectric 0.9Pb(Mg1/3Nb2/3)O3-0.1PbTiO3 is studied using time-resolved Piezoresponse Force Microscopy. Local relaxation attributed to the reorientation of polar…

Materials Science · Physics 2013-05-29 S. V. Kalinin , B. J. Rodriguez , J. D. Budai , S. Jesse , A. N. Morozovska , A. A. Bokov , Z. -G. Ye

Sodium niobate (NaNbO$_{3}$) is a perovskite oxide and a key component of emerging lead-free antiferroelectric capacitors for high-energy-density applications. However, its performance can be hindered by irreversible phase transitions and…

Materials Science · Physics 2026-05-19 Mohammad Amirabbasi , Lorenzo Villa , Elaheh Ghorbani , Jochen Rohrer , Karsten Albe

Giant electrocaloric (EC) effect is observed in BaTiO3 multilayer thick film structure. The temperature change is as high as 4.0 oC under an applied electric field of 352 kV/cm. Most importantly, the EC effect is found to depend on the…

Materials Science · Physics 2015-05-18 Yang Bai , Guang-Ping Zheng , San-Qiang Shi

The electrocaloric effect (ECE) in normal and relaxor ferroelectrics is investigated in the framework of a thermodynamic approach based on the Maxwell relation and a Landau-type free energy model. The static dielectric response of relaxors…

Disordered Systems and Neural Networks · Physics 2015-05-20 R. Pirc , Z. Kutnjak , R. Blinc , Q. M. Zhang

Perovskite-type Ba0.9Sr0.1Ti0.9Sn0.1O3(BSTSn) ceramic was synthesized by the sol gel method. The P E hysteresis loops were recorded at different temperatures to investigate the ferroelectric and energy storage properties of BSTSn ceramic.…

Materials Science · Physics 2023-06-13 S. Khardazi , H. Zaitouni , S. Belkhadir , D. Mezzane , M. Amjoud , Y. Gagou , B. Asbani , I. Lukyanchuk , S. Terenchuk

An atomistic effective Hamiltonian technique is used to investigate the finite-temperature energy storage properties of a ferroelectric nanocomposite consisting of an array of BaTiO$_{3}$ nanowires embedded in a SrTiO$_{3}$ matrix, for…

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