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Exciton-phonon interactions play a central role in defining the optical response of hexagonal boron nitride (hBN), yet their quantitative determination has remained incomplete. Here, we reveal the Fr\"ohlich-type exciton-phonon coupling in…

Mesoscale and Nanoscale Physics · Physics 2026-05-21 Ioannis Chatzakis , Timur Abdilov , Elliot Walker , Jaime Freitas , Song Liu , James H. Edgar

Despite its simple crystal structure, layered boron nitride features a surprisingly complex variety of phonon-assisted luminescence peaks. We present a combined experimental and theoretical study on ultraviolet-light emission in hexagonal…

We show that the optical absorption spectra of boron nitride (BN) nanotubes are dominated by strongly bound excitons. Our first-principles calculations indicate that the binding energy for the first and dominant excitonic peak depends…

Materials Science · Physics 2013-08-07 Ludger Wirtz , Andrea Marini , Angel Rubio

Quantum emitters in hexagonal Boron Nitride (hBN) were recently reported to hol a homogeneous linewidth according to the Fourier-Transform limit up to room temperature. This unusual observation was traced back to decoupling from in-plane…

Mesoscale and Nanoscale Physics · Physics 2020-10-02 Michael Hoese , Prithvi Reddy , Andreas Dietrich , Michael K. Koch , Konstantin G. Fehler , Marcus W. Doherty , Alexander Kubanek

Optically addressable defect qubits in wide band gap materials are favorable candidates for room temperature quantum information processing. The two-dimensional (2D) hexagonal boron nitride (hBN) is an attractive solid state platform with a…

Materials Science · Physics 2024-09-10 Song Li , Anton Pershin , Adam Gali

Theoretical and numerical calculations of the optical absorption spectra of excitons interacting with longitudinal-optical phonons in quasi-2D polar semiconductors are presented. In II-VI semiconductor quantum wells, exciton binding energy…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 F. J. Rodriguez

We report $ab$ $initio$ band diagram and optical absorption spectra of hexagonal boron nitride ($h$-BN), focusing on unravelling how the completeness of basis set for $GW$ calculations and how electron-phonon interactions (EPIs) impact on…

Materials Science · Physics 2020-07-22 Tong Shen , Xiao-Wei Zhang , Honghui Shang , Min-Ye Zhang , Xinqiang Wang , En-Ge Wang , Hong Jiang , Xin-Zheng Li

The effects of the electron-phonon interaction on optical excitations can be understood in terms of exciton-phonon coupling, and require a careful treatment in low-dimensional materials with strongly bound excitons or strong electron-hole…

Materials Science · Physics 2022-02-17 Gabriel Antonius , Steven G. Louie

We study experimentally and theoretically the exciton-phonon interaction in MoSe2 monolayers encapsulated in hexagonal BN, which has an important impact on both optical absorption and emission processes. The exciton transition linewidth…

Monolayer of hexagonal boron nitride (h-BN), commonly known as "white graphene" is a promising wide bandgap semiconducting material for deep-ultaviolet optoelectronic devices. In this report, the light absorption of a single layer hexagonal…

Mesoscale and Nanoscale Physics · Physics 2011-09-26 Aniruddha Konar , Raj Jana , Tian Fang , Guowang Li , William O'Brien , Debdeep Jena

We show that hexagonal boron nitride (hBN), a two-dimensional insulator, when subjected to an external superlattice potential forms a new paradigm for electrostatically tunable excitons in the near- and mid-ultraviolet (UV). The imposed…

Mesoscale and Nanoscale Physics · Physics 2024-08-08 Pedro Ninhos , Christos Tserkezis , N. Asger Mortensen , Nuno M. R. Peres

A newly synthesized layered material C2N was investigated based on many- body perturbation theory using GW plus Bethe-Salpeter equation approach. The electronic band gap was determined to be ranging from 3.75 to 1.89 eV from monolayer to…

Materials Science · Physics 2016-11-03 Jiuyu Sun , Ruiqi Zhang , Xingxing Li , Jinlong Yang

Phonon polaritons are quasiparticles resulting from strong coupling of photons with optical phonons. Excitation and control of these quasiparticles in 2D materials offer the opportunity to confine and transport light at the nanoscale. Here,…

Mesoscale and Nanoscale Physics · Physics 2015-01-13 Zhiwen Shi , Hans A. Bechte , Samuel Berweger , Yinghui Sun , Bo Zeng , Chenhao Jin , Henry Chang , Michael C. Martin , Markus B. Raschke , Feng Wang

Microcavity exciton-polaritons are two-dimensional bosonic quasiparticles composed by excitons and photons. Using model Hamiltonian with parameters generated from ab initio density-functional theory and Bathe-Salpeter Equation calculations,…

Materials Science · Physics 2021-12-01 Huaiyuan Yang , Xinqiang Wang , Xin-Zheng Li

We investigate the influence of vibrational screening on the excitonic and optical properties of solids based on first-principles electronic-structure calculations. We solve the Bethe-Salpeter equation - the state-of-the-art description of…

Materials Science · Physics 2024-09-24 Maximilian Schebek , Pasquale Pavone , Claudia Draxl , Fabio Caruso

Understanding the collective behavior of the quasiparticles in solid-state systems underpins the field of non-volatile electronics, including the opportunity to control many-body effects for well-desired physical phenomena and their…

Hexagonal boron nitride (hBN) has been attracting great attention because of its strong excitonic effects. Taking into account few-layer systems, we investigate theoretically the effects of the number of layers on quasiparticle energies,…

We report an investigation of the bulk optical, bulk acoustic, and surface acoustic phonons in thin films of turbostratic boron nitride (t-BN) and cubic boron nitride (c-BN) grown on B-doped polycrystalline and single-crystalline diamond…

Linear and nonlinear optical properties of low dimensional nanostructures have attracted a large interest in the scientific community as tools to probe the strong confinement of the electrons and for possible applications in optoelectronic…

Materials Science · Physics 2017-03-08 C. Attaccalite , E. Cannuccia , M. Grüning

Cubic boron nitride (cBN) is an ultra-wide bandgap, super-hard material with potential for extreme-temperature and -pressure applications. A proof-of-principle p-n junction using cBN was demonstrated almost three decades ago. However, to…

Materials Science · Physics 2022-02-04 Tamanna Joshi , Pankaj Kumar , Bipul Poudyal , Sean Paul Russell , Priyanka Manchanda , Pratibha Dev