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Mode-coupling theory (MCT) constitutes one of the few first-principles-based approaches to describe the physics of the glass transition, but the theory's inherent approximations compromise its accuracy in the activated glassy regime. Here…

Statistical Mechanics · Physics 2021-02-03 Chengjie Luo , Liesbeth M. C. Janssen

Generalized mode-coupling theory (GMCT) constitutes a systematically correctable, first-principles theory to study the dynamics of supercooled liquids and the glass transition. It is a hierarchical framework that, through the incorporation…

Statistical Mechanics · Physics 2021-02-03 Chengjie Luo , Liesbeth M. C. Janssen

When the center of fluctuations, i.e., the nonequilibrium eigenphase, undergoes transformation, there emerge critical parameters that demonstrate insensitivity to fluctuation perturbations and even independence from the molecular physical…

Statistical Mechanics · Physics 2025-03-11 Yikun Ren , Feixiang Xu , Ming Lin

Mode-coupling theory (MCT) is conjectured to be a mean-field description of dynamics of the structural glass transition and the replica theory to be its thermodynamic counterpart. However, the relationship between the two theories remains…

Soft Condensed Matter · Physics 2015-05-18 Atsushi Ikeda , Kunimasa Miyazaki

Many qualitative observations on the glass transition in classical fluids are well described by the mode coupling theory (MCT) but the extent of the non-ergodicity domain is often over-estimated by this theory. Making it more quantitative…

Statistical Mechanics · Physics 2012-10-04 S. Amokrane , F. Tchangnwa Nya , J. M. Ndjaka

We present an extensive treatment of the generalized mode-coupling theory (GMCT) of the glass transition, which seeks to describe the dynamics of glass-forming liquids using only static structural information as input. This theory amounts…

Statistical Mechanics · Physics 2016-07-05 Liesbeth M. C. Janssen , Peter Mayer , David R. Reichman

Mean-field theories of the glass transition predict a phase transition to a dynamically arrested state, yet no such transition is observed in experiments or simulations of finite-dimensional systems. We resolve this long-standing…

Soft Condensed Matter · Physics 2025-12-16 Corentin C. L. Laudicina , Liesbeth M. C. Janssen , Grzegorz Szamel

The aim of this paper is to test numerically the predictions of the Mode Coupling Theory (MCT) of the glass transition and study its finite size scaling properties in a model with an exact MCT transition, which we choose to be the fully…

Disordered Systems and Neural Networks · Physics 2009-09-24 Thomas Sarlat , Alain Billoire , Giulio Biroli , Jean-Philippe Bouchaud

Often the current mode coupling theory (MCT) of glass transitions is compared with mean field theories. We explore this possible correspondence. After showing a simple-minded derivation of MCT with some difficulties we give a concise…

Statistical Mechanics · Physics 2009-11-07 Kyozi Kawasaki , Bongsoo Kim

We derive the Mode Coupling Theory (MCT) of the glass transition as a Landau theory, formulated as an expansion of the exact dynamical equations in the difference between the correlation function and its plateau value. This sheds light on…

Statistical Mechanics · Physics 2015-05-13 A. Andreanov , G. Biroli , J. -P. Bouchaud

For over 30 years, mode-coupling theory (MCT) has been the de facto theoretic description of dense fluids and the liquid-glass transition. MCT, however, is limited by its ad hoc construction and lacks a mechanism to institute corrections.…

Soft Condensed Matter · Physics 2015-08-12 David D. McCowan

The emergence of glassy dynamics and the glass transition in dense disordered systems is still not fully understood theoretically. Mode-coupling theory (MCT) has shown to be effective in describing some of the non-trivial features of glass…

Soft Condensed Matter · Physics 2021-07-20 Simone Ciarella , Chengjie Luo , Vincent E. Debets , Liesbeth M. C. Janssen

We provide extended evidence that mode-coupling theory (MCT) of supercooled liquids for the ${\mathsf F}_{12}$ schematic model admits a microscopic realization based on facilitated spin models with tunable facilitation. Depending on the…

Disordered Systems and Neural Networks · Physics 2012-08-24 Jeferson J. Arenzon , Mauro Sellitto

Understanding the physics of glass formation remains one of the major unsolved challenges of condensed matter science. As a material solidifies into a glass, it exhibits a spectacular slowdown of the dynamics upon cooling or compression,…

Statistical Mechanics · Physics 2018-10-03 Liesbeth M. C. Janssen

We report recent progress on the test of mode coupling theory for molecular liquids (MMCT) for molecules of arbitrary shape. The MMCT equations in the long time limit are solved for supercooled water including all molecular degrees of…

Soft Condensed Matter · Physics 2007-05-23 C. Theis , F. Sciortino , A. Latz , R. Schilling , P. Tartaglia

Mesoscopic theory for self-assembling systems near a planar confining surface is developed. Euler- Lagrange (EL) equations and the boundary conditions (BC) for the local volume fraction and the correlation function are derived from the DFT…

Statistical Mechanics · Physics 2020-01-03 A. Ciach

The mode-coupling theory (MCT) of the glass transition ranks among the most successful first-principles kinetic theories to describe glassy dynamics. However, MCT does not fully account for crucial aspects of the dynamics near the glass…

Soft Condensed Matter · Physics 2024-08-22 Ilian Pihlajamaa , Liesbeth M. C. Janssen

We show that the glass transition predicted by the Mode-Coupling Theory (MCT) is a critical phenomenon with a diverging length and time scale associated to the cooperativity of the dynamics. We obtain the scaling exponents nu and z that…

Statistical Mechanics · Physics 2009-11-10 Giulio Biroli , Jean-Philippe Bouchaud

Mode coupling theory (MCT) has been successful in explaining the observed sequence of time relaxations in dense fluids. Previous expositions of this theory showing this sequence have required the existence of an ideal glass transition…

Condensed Matter · Physics 2009-10-22 Gene F. Mazenko , Joonhyun Yeo

The predictions of the mode-coupling theory of the glass transition (MCT) for the tagged-particle density-correlation functions and the mean-squared displacement curves are compared quantitatively and in detail to results from Newtonian-…

Statistical Mechanics · Physics 2009-11-10 Th. Voigtmann , A. M. Puertas , M. Fuchs
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