English

Microscopic Theory of a Fluctuation-Induced Dynamical Crossover in Supercooled Liquids

Soft Condensed Matter 2025-12-16 v1 Disordered Systems and Neural Networks Statistical Mechanics Chemical Physics

Abstract

Mean-field theories of the glass transition predict a phase transition to a dynamically arrested state, yet no such transition is observed in experiments or simulations of finite-dimensional systems. We resolve this long-standing discrepancy by incorporating critical dynamical fluctuations into a microscopic mode-coupling framework. We show that these fluctuations round off the mean-field singularity and restore ergodicity at all finite densities (or temperatures) without invoking activated dynamics or facilitation. The resulting effective theory describes the order parameter as a stochastic process with self-induced, annealed disorder, determined self-consistently at the mean-field level. In the β\beta-relaxation regime it reduces to stochastic beta-relaxation theory, thereby unifying mode-coupling and replica-based approaches beyond mean-field. All parameters of the stochastic β\beta-relaxation theory are fixed by the static structure, enabling parameter-free predictions that extend mean-field theory into finite dimensions.

Keywords

Cite

@article{arxiv.2512.13082,
  title  = {Microscopic Theory of a Fluctuation-Induced Dynamical Crossover in Supercooled Liquids},
  author = {Corentin C. L. Laudicina and Liesbeth M. C. Janssen and Grzegorz Szamel},
  journal= {arXiv preprint arXiv:2512.13082},
  year   = {2025}
}

Comments

5 pages, 1 figure