Related papers: Modulated Anti-Ferroelectric Smectic Phases with O…
Liquid crystal materials exhibiting up to three nematic phases are reported. Dielectric response measurements show that while the lower temperature nematic phase has ferroelectric order and the highest temperature nematic phase is apolar,…
The polarization and density modulation associated with antiferroelectric ordering is studied experimentally as a function of temperature in two ferroelectric nematic liquid crystals, the prototypical single compound (DIO) and a commercial…
We explore the possibility that the large electroclinic effect observed in ferroelectric liquid crystals arises from the presence of an ordered array of disclination lines and walls. If the spacing of these defects is in the subvisible…
In soft matter, the polar orientational order of molecules can facilitate the coexistence of structural chirality and ferroelectricity. The ferroelectric nematic (NF) state, exhibited by achiral calamitic molecules with large dipole…
Chiral liquid crystals often exhibit periodic modulations in the molecular director; in particular, thin films of the smectic-C* phase show a chiral striped texture. Here, we investigate whether similar chiral modulations can occur in the…
Electronic nematic and smectic liquid crystals are spontaneous symmetry-breaking phases that are seen to precede or coexist with enigmatic unconventional superconducting states in multiple classes of materials. In this Letter we describe…
The smectic C (smC) phase represents a unique class of liquid crystal phases characterised by the layered arrangement of molecules with tilted orientations with respect to layer normals. Building upon the real-valued tensorial smectic A…
Nematics with a broken polar symmetry is one of the fascinating recent discoveries in the field of soft matter. High spontaneous polarisation and the fluidity of the ferroelectric nematic $N_{\mathrm{F}}$ phase make such materials…
Since the recent discoveries, ferroelectric nematics became of upmost interest due to their outstanding ferroelectric properties. In this work, we prepared a series of polar molecules revealing a ferroelectric nematic phase (NF) with a very…
The recent experimental discovery of ferroelectric and splay nematic phases has sparked interest in comprehending the crucial molecular features necessary to stabilize these innovative structures. This study advances the ongoing discourse…
A dynamic light scattering study of director-layer fluctuations in the antiferroelectric smectic-ZA phase of the ferroelectric nematic liquid crystal DIO is reported. The dynamics are consistent with the distinctive feature of the ZA phase…
Using particle-resolved molecular-dynamics simulations, we compute the phase diagram for soft repulsive spherocylinders confined on the surface of a sphere. While crystal (K), smectic (Sm), and isotropic (I) phases exhibit a stability…
The recent discovery of the ferroelectric splay nematic phase has opened the door to experimental investigation of one of the most searched liquid crystal phases in decades, with high expectations for future applications. However, at this…
Fluid molecular ferroelectrics are a new class of organic materials where ferroelectricity is found in conjunction with 3D fluidity whilst still retaining spontaneous polarization values comparable to their traditional solid state…
Recently we have formulated theory of bi-layer-dimerized chiral liquid antiferroelectric crystals. The spontaneous polarization has been increased owing to the strong interaction of the aromatic cores of the rod like liquid crystal…
We have revisited the Kittel model that describes antiferroelectricity (AFE) in terms of two sublattices of spontaneous polarization with antiparallel couplings. By constructing the comprehensive phase diagram including the…
Phenomenological model of chiral polar smectics is introduced with interactions up to the fourth neighboring layers. The minimization of the free energy gives three stable structures: the ferroelectric Sm C$^*$ phase, the antiferroelectric…
We show that development of polar order may spontaneously destroy the lamellar structure of a liquid crystal. This results in an unusual sequence of phases with the ferroelectric nematic phase appearing below a non-polar smectic phase. The…
The recently discovered ferroelectric nematic liquid-crystal material DIO exhibits an antiferroelectric (AF) phase, characterized by a sinusoidally modulated structure between the paraelectric (P) and ferroelectric (F) nematic phases.…
A ternary liquid crystalline mixture was designed to obtain a tilted hexatic smectic phase in the glassy state. Structural, electro-optic, and dielectric properties of the mixture are investigated, and selected measurements are also…