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We discuss models that astrochemists have developed to study the chemical composition of the interstellar medium. These models aim at computing the evolution of the chemical composition of a mixture of gas and dust under as- trophysical…

Astrophysics of Galaxies · Physics 2013-10-01 Valentine Wakelam , Herma M. Cuppen , Eric Herbst

Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…

Astrophysics of Galaxies · Physics 2015-05-14 H. M. Cuppen , E. F. van Dishoeck , E. Herbst , A. G. G. M. Tielens

Ice is ubiquitous in the interstellar medium. We model the formation of the main constituents of interstellar ices, including H2O, CO2 , CO, and CH3 OH. We strive to understand what physical or chemical parameters influence the final…

Astrophysics of Galaxies · Physics 2023-07-26 A. Clément , A. Taillard , V. Wakelam , P. Gratier , J. -C. Loison , E. Dartois , F. Dulieu , J. A. Noble , M. Chabot

Formaldehyde is a key precursor in the formation routes of many complex organic molecules (COMs) in space. It is also an intermediate step in CO hydrogenation sequence that leads to methanol formation on the surface of interstellar grains…

Astrophysics of Galaxies · Physics 2025-02-04 A. F. Punanova , K. Borshcheva , G. S. Fedoseev , P. Caselli , D. S. Wiebe , A. I. Vasyunin

In studies of the interstellar medium in galaxies, radiative transfer models of molecular emission are useful for relating molecular line observations back to the physical conditions of the gas they trace. However, doing this requires…

Astrophysics of Galaxies · Physics 2019-10-02 Damien de Mijolla , Serena Viti , Jonathan Holdship , Ioanna Manolopoulou , Jeremy Yates

We present and test chemical models for three-dimensional hydrodynamical simulations of galaxies. We explore the effect of changing key parameters such as metallicity, radiation and non-equilibrium versus equilibrium metal cooling…

Astrophysics of Galaxies · Physics 2016-05-04 Stefano Bovino , Tommaso Grassi , Pedro R. Capelo , Dominik R. G. Schleicher , R. Banerjee

Abridged: We detail and benchmark two sophisticated chemical models developed by the Heidelberg and Bordeaux astrochemistry groups. The main goal of this study is to elaborate on a few well-described tests for state-of-the-art astrochemical…

Astrophysics of Galaxies · Physics 2015-05-19 D. Semenov , F. Hersant , V. Wakelam , A. Dutrey , E. Chapillon , St. Guilloteau , Th. Henning , R. Launhardt , V. Pietu , K. Schreyer

Glycoaldehyde, ethylene glycol, and methyl formate are complex organic molecules that have been observed in dark molecular clouds. Because there is no efficient gas-phase route to produce these species, it is expected that a low-temperature…

Solar and Stellar Astrophysics · Physics 2020-02-12 M. A. J. Simons , T. Lamberts , H. M. Cuppen

Astrochemical modeling is needed for understanding the formation and evolution of interstellar molecules, and for extracting physical information from spectroscopic observations of interstellar clouds. The modeling usually involves handling…

Solar and Stellar Astrophysics · Physics 2021-05-05 Fujun Du

AIM: We have recently developed a microscopic Monte Carlo approach to study surface chemistry on interstellar grains and the morphology of ice mantles. The method is designed to eliminate the problems inherent in the rate-equation formalism…

Astrophysics · Physics 2009-11-13 Q. Chang , H. M. Cuppen , E. Herbst

Hydrogenation reactions of CO in inter- and circumstellar ices are regarded as an important starting point in the formation of more complex species. Previous laboratory measurements by two groups on the hydrogenation of CO ices resulted in…

Solar and Stellar Astrophysics · Physics 2009-06-15 G. W. Fuchs , H. M. Cuppen , S. Ioppolo , C. Romanzin , S. E. Bisschop , S. Andersson , E. F. van Dishoeck , H. Linnartz

Astrochemistry aims at studying chemical processes in astronomical environments. This discipline -- located at the crossroad between astrophysics and chemistry -- is rapidly evolving and explores the issue of the formation of molecules of…

Astrophysics of Galaxies · Physics 2013-05-28 M. De Becker

Molecular hydrogen has an important role in the early stages of star formation as well as in the production of many other molecules that have been detected in the interstellar medium. In this review we show that it is now possible to study…

Chemical models have been developed over the years by astrophysicists to study the pro- cesses at play in the various environments of the interstellar medium (ISM) that define the chemical composition of the gas and the dust. These…

Astrophysics of Galaxies · Physics 2013-10-15 Marcelino Agundez , Valentine Wakelam

Astrochemistry is a well-established multidisciplinary field devoted to study molecules in space. While most astrochemists are oriented to observe molecules in the gas phase and reproduce their abundances by modeling the physical conditions…

Astrophysics of Galaxies · Physics 2025-12-10 Guillermo M. Muñoz Caro , Héctor Carrascosa de Lucas , Rafael Martín-Doménech

In astrochemistry, computational methods play a crucial role in addressing fundamental astronomical questions. Interstellar molecules profoundly influence the chemistry and physics of the interstellar medium (ISM), playing pivotal roles in…

Astrophysics of Galaxies · Physics 2024-07-23 D. Campisi , J. Perrero , N. Balucani

Nearby dwarf irregular galaxies are ideal laboratories for studying the interstellar medium (ISM) at low metallicity, which is expected to be common for galaxies at very high redshift being observed by the James Webb Space Telescope. We…

Astrophysics of Galaxies · Physics 2023-08-02 Chia-Yu Hu , Amiel Sternberg , Ewine F. van Dishoeck

Astrochemical models are important tools to interpret observations of molecular and atomic species in different environments. However, these models are time-consuming, precluding a thorough exploration of the parameter space, leading to…

Instrumentation and Methods for Astrophysics · Physics 2024-06-05 A. Asensio Ramos , C. Westendorp Plaza , D. Navarro-Almaida , P. Rivière-Marichalar , V. Wakelam , A. Fuente

Since molecules are ubiquitous in space, the study of the 'Molecular Universe' could unfold the mystery of the existing Interstellar medium. Star formation is linked to the chemical evolution processes. Thus, an analysis of the formation of…

Astrophysics of Galaxies · Physics 2024-05-29 Bratati Bhat

Laboratory experiments play a key role in deciphering the chemistry of the interstellar medium (ISM) and the role that product complex organic molecules (COMs) may play in the origins of life. However, to date, most studies in experimental…

Earth and Planetary Astrophysics · Physics 2022-01-26 Nigel J. Mason , Perry A. Hailey , Duncan V. Mifsud , James S. Urquhart
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