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Astrochemistry has been widely developed as a power tool to probe physical properties of the interstellar medium (ISM) in various conditions of the Milky Way (MW) Galaxy, and in near and distant galaxies. Most current studies conventionally…

Because of new telescopes that will dramatically improve our knowledge of the interstellar medium, chemical models will have to be used to simulate the chemistry of many regions with diverse properties. To make these models more robust, it…

Astrophysics of Galaxies · Physics 2011-03-16 V. Wakelam , E. Herbst , J. Le Bourlot , F. Hersant , F. Selsis , S. Guilloteau

Cosmic-rays are the primary initiators of interstellar chemistry, and getting a better understanding of the varying impact they have on the chemistry of interstellar clouds throughout the Milky Way will not only expand our understanding of…

Astrophysics of Galaxies · Physics 2018-11-28 Tobias Albertsson , Jens Kauffmann , Karl M. Menten

Many astrochemical models today explicitly consider the species that comprise the bulk of interstellar dust grain ice-mantles separately from those in the top few monolayers. Bombardment of these ices by ionizing radiation - whether in the…

Astrophysics of Galaxies · Physics 2019-05-29 Christopher N. Shingledecker , Anton Vasyunin , Eric Herbst , Paola Caselli

Detections of molecular lines, mainly from H2$ and CO, reveal molecular material in planetary nebulae. Observations of a variety of molecules suggest that the molecular composition in these objects differs from that found in interstellar…

Astrophysics of Galaxies · Physics 2012-06-28 Rafael K. Kimura , Ruth Gruenwald , Isabel Aleman

While most chemical reactions in the interstellar medium take place in the gas phase, those occurring on the surfaces of dust grains play an essential role. Chemical models based on rate equations including both gas phase and grain surface…

Astrophysics · Physics 2009-11-07 Azi Lipshtat , Ofer Biham

We survey the current situation regarding chemical modelling of the synthesis of molecules in the interstellar medium. The present state of knowledge concerning the rate coefficients and their uncertainties for the major gas-phase processes…

Molecules in space are synthesized via a large variety of gas-phase reactions, and reactions on dust-grain surfaces, where the surface acts as a catalyst. Especially, saturated, hydrogen-rich molecules are formed through surface chemistry.…

Astrophysics of Galaxies · Physics 2022-02-11 H. M. Cuppen , A. Fredon , T. Lamberts , E. M. Penteado , M. Simons , C. Walsh

Methanol, one of the simplest complex organic molecules in the Interstellar Medium (ISM), has been shown to be present and extended in cold environments such as starless cores. We aim at studying methanol emission across several starless…

Astrophysics of Galaxies · Physics 2021-12-22 S. Spezzano , A. Fuente , P. Caselli , A. Vasyunin , D. Navarro-Almaida , M. Rodríguez-Baras , A. Punanova , C. Vastel , V. Wakelam

Astrochemical models are essential to bridge the gap between the timescales of reactions, experiments, and observations. Ice chemistry in these models experiences a large computational complexity as a result of the many parameters required…

Astrophysics of Galaxies · Physics 2026-02-18 Tobias M. Dijkhuis , Thanja Lamberts , Serena Viti , Herma M. Cuppen

Context. The presence of dust in the interstellar medium has profound consequences on the chemical composition of regions where stars are forming. Recent observations show that many species formed onto dust are populating the gas phase,…

Solar and Stellar Astrophysics · Physics 2015-12-16 M. Minissale , F. Dulieu , S. Cazaux , S. Hocuk

The results of experiments on the formation of molecular hydrogen on low density and high density amorphous ice surfaces are analyzed using a rate equation model. The activation energy barriers for the relevant diffusion and desorption…

With the advent of large spectroscopic surveys the amount of high quality chemo-dynamical data in the Milky Way (MW) increased tremendously. Accurately and correctly capturing and explaining the detailed features in the high-quality…

Methanol is the most complex molecule securely identified in interstellar ices and is a key chemical species for understanding chemical complexity in astrophysical environments. Important aspects of the methanol ice photochemistry are still…

Astrophysics of Galaxies · Physics 2023-05-10 W. R. M. Rocha , P. Woitke , S. Pilling , W. -F. Thi , J. K. Jørgensen , L. E. Kristensen , G. Perotti , I. Kamp

We examine several different simplified approaches for modelling the chemistry of CO in three-dimensional numerical simulations of turbulent molecular clouds. We compare the different models both by looking at the behaviour of integrated…

Astrophysics of Galaxies · Physics 2015-05-27 S. C. O. Glover , P. C. Clark

We propose a new model for treating solid-phase photoprocesses in interstellar ice analogues. In this approach, photoionization and photoexcitation are included in more detail, and the production of electronically-excited (suprathermal)…

For the first time, we report a unified microscopic-macroscopic Monte Carlo simulation of gas-grain chemistry in cold interstellar clouds in which both the gas-phase and the grain surface chemistry are simulated by a stochastic technique.…

Astrophysics of Galaxies · Physics 2015-06-11 Qiang Chang , Eric Herbst

We present results from high-resolution three-dimensional simulations of turbulent interstellar gas that self-consistently follow its coupled thermal, chemical and dynamical evolution, with a particular focus on the formation and…

Solar and Stellar Astrophysics · Physics 2015-05-13 S. C. O. Glover , C. Federrath , M. -M. Mac Low , R. S. Klessen

This study focuses on the formation of two molecules of astrobiological importance - glycolaldehyde (HC(O)CH2OH) and ethylene glycol (H2C(OH)CH2OH) - by surface hydrogenation of CO molecules. Our experiments aim at simulating the CO…

Astrophysics of Galaxies · Physics 2017-05-26 Gleb Fedoseev , Herma M. Cuppen , Sergio Ioppolo , Thanja Lamberts , Harold Linnartz

The thermal history of the intergalactic medium is full of extremely useful data in the field of astrophysics and cosmology. In other words, by examining this environment in different redshifts, the effects of cosmology and astrophysics can…

Cosmology and Nongalactic Astrophysics · Physics 2023-06-23 S. Mobina Hosseini , Bahareh Soleimanpour Salmasi , Seyed Sajad Tabasi , Javad T. Firouzjaee