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Scalar relativistic corrections to atomization energies of 1st-and 2nd-row molecules can be rationalized in terms of a simple additive model, linear in changes in atomic s populations. In a sample of 200 first-and second-row molecules, such…

Chemical Physics · Physics 2018-08-13 Jan M. L. Martin , Nitai Sylvetsky

We investigate the role of the electron correlation effects in the calculations of the electric dipole polarizabilities (\alpha) of elements belonging to three different groups of periodic table. To understand the propagation of the…

Atomic Physics · Physics 2014-05-21 Yashpal Singh , B. K. Sahoo

We consider correlated transfer ionization in relativistic collisions between a highly charged ion and a light atom. In this process two quasi-free electrons of the atom interact with each other during the short collision time that results…

Atomic Physics · Physics 2015-06-18 O. Yu. Andreev , E. A. Mistonova , A. B. Voitkiv

Variational and perturbative relativistic energies are computed and compared for two-electron atoms and molecules with low nuclear charge numbers. In general, good agreement of the two approaches is observed. Remaining deviations can be…

Chemical Physics · Physics 2022-09-21 Dávid Ferenc , Péter Jeszenszki , Edit Mátyus

The interplay of kinetic electron physics and atomic processes in ultrashort laser-plasma interactions provides a comprehensive understanding of electron energy distribution's impact on plasma properties. Notably, non-equilibrium electrons…

Plasma Physics · Physics 2024-03-27 M. S. Cho , H. -K. Chung , M. E. Foord , S. B. Libby , B. I. Cho

The total cross section for double ionization of lithiumlike ions by a high-energy photon is calculated in leading order of the nonrelativistic perturbation theory. The partial contributions due to simultaneous and sequential emissions of…

Atomic Physics · Physics 2009-11-11 A. I. Mikhailov , I. A. Mikhailov , A. V. Nefiodov , G. Plunien

The relativistic nuclear recoil, higher-order interelectronic-interaction, and screened QED corrections to the transition energies in Li-like ions are evaluated. The calculation of the relativistic recoil effect is performed to all orders…

We present a relativistic correction scheme to improve the accuracy of 1s core-level binding energies calculated from Green's function theory in the $GW$ approximation, which does not add computational overhead. An element-specific…

Chemical Physics · Physics 2020-09-23 Levi Keller , Volker Blum , Patrick Rinke , Dorothea Golze

Nonlinear relativistic ionization phenomena induced by a strong linearly polarized laser field are considered. The starting point is the classical relativistic action for a free electron moving in the electromagnetic field created by a…

Atomic Physics · Physics 2017-08-23 J. Ortner , V. M. Rylyuk

Positron binding to silver and gold atoms was studied using a fully {\it ab initio} relativistic method, which combines the configuration interaction method with many-body perturbation theory. It was found that the silver atom forms a bound…

Atomic Physics · Physics 2009-11-06 V. A. Dzuba , V. V. Flambaum , C. Harabati

A new relativistic method based on the Dirac equation for calculating fully differential cross sections for ionization in ion-atom collisions is developed. The method is applied to ionization of the atomic hydrogen by antiproton impact, as…

Atomic Physics · Physics 2017-06-07 A. I. Bondarev , Y. S. Kozhedub , I. I. Tupitsyn , V. M. Shabaev , G. Plunien

The effects of small relativistic corrections to the off-resonant polarizability, hyperpolarizability, and second hyperpolarizability are investigated. Corrections to linear and nonlinear optical coefficients are demonstrated in the…

Quantum Physics · Physics 2015-06-22 Nathan J. Dawson

Electron correlation and higher-order relativistic effects are probed in the evaluation of scalar and tensor static electric dipole (E1) polarizabilities ($\alpha_d$) of several even- and odd-parity states in cesium (Cs) using the…

Atomic Physics · Physics 2025-07-08 A. Chakraborty , B. K. Sahoo

Short range correlations are introduced using unitary correlation method in a relativistic approach to the equation of state of the infinite nuclear matter in the framework of the Hartree-Fock approximation. It is shown that the…

Nuclear Theory · Physics 2011-07-19 P. K. Panda , João da Providência , Constança Providência

The attosecond ultrafast ionization dynamics of correlated two- or many-electron systems have, so far, been mainly addressed investigating atomic systems. In the case of single ionization, it is well known that electron-electron correlation…

In quantum chemistry calculations, the correlation energy is defined as the difference between the Hartree-Fock limit energy and the exact solution of the nonrelativistic Schrodinger equation. With this definition, the electron correlation…

Quantum Physics · Physics 2009-11-11 Zhen Huang , Sabre Kais

We investigate roles of electron correlation effects in the determination of the $g_j$ factors of the $4s ~ ^2S_{1/2}$, $4p ~ ^2P_{1/2}$, $4p ~ ^2P_{3/2}$, $3d ~ ^2D_{3/2}$, and $3d ~ ^2D_{5/2}$ states, representing to different parities…

Atomic Physics · Physics 2017-07-26 B. K. Sahoo , Pradeep Kumar

In order to trace the initial interaction in ultra-relativistic heavy ion collision in all azimuthal directions, two azimuthal multiplicity-correlation patterns -- neighboring and fixed-to-arbitrary angular-bin correlation patterns -- are…

Nuclear Theory · Physics 2009-09-17 Meijuan Wang , Lianshou Liu , Yuanfang Wu

In this work, the calculation of complexity on atomic systems is considered. In order to unveil the increasing of this statistical magnitude with the atomic number due to the relativistic effects, recently reported in [A. Borgoo, F. De…

Chaotic Dynamics · Physics 2008-06-12 Jaime Sanudo , Ricardo Lopez-Ruiz

We develop a theoretical method within the framework of relativistic many-body theory to accurately treat correlation corrections in atoms with few valence electrons. This method combines the all-order approach currently used in precision…

Atomic Physics · Physics 2009-09-01 M. S. Safronova , M. G. Kozlov , W. R. Johnson , Dansha Jiang