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Related papers: A Comparative Study of Correlation and Relativisti…

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We develop a time-dependent theory to investigate electron dynamics and photoionization processes of diatomic molecules interacting with strong laser fields including electron-electron correlation effects. We combine the recently formulated…

Chemical Physics · Physics 2016-02-02 Henrik R. Larsson , Sebastian Bauch , Lasse Kragh Sørensen , Michael Bonitz

Ionization of highly charged relativistic ions by neutral atoms and ions is considered. Numerical results of recently developed computer codes based on the relativistic Born and the equivalent-photon approximations are presented. The…

Atomic Physics · Physics 2013-05-29 G. Baur , I. L. Beigman , V. P Shevelko , I. Yu. Tolstikhina , Th. Stoehlker

With recent developments in simulating nonadiabatic systems to high accuracy, it has become possible to determine how much energy is attributed to nuclear quantum effects beyond zero-point energy. In this work we calculate the…

Chemical Physics · Physics 2016-08-23 Yubo Yang , Ilkka Kylanpaa , Norm Tubman , Jaron Krogel , Sharon Hammes-Schiffer , David Ceperley

Deep-lying core electrons carry highly localized, site-specific information that forms the basis of X-ray photoelectron spectroscopy. Accurately predicting their associated core ionization potentials (IPs) is a demanding theoretical task,…

Chemical Physics · Physics 2026-04-08 Antoine Marie , Loris Burth , Pierre-François Loos

In this paper we analyze how radiation effects influence the correlation functions, the excess energy, and in turn the electron correlation energy of the quantized electron gas at temperature $T=0$. To that aim we resort to a statistical…

Statistical Mechanics · Physics 2020-08-26 Johan S. Høye , Enrique Lomba

Methods for estimating the correlation energy of molecules and other electronic systems are discussed based on the assumption that the correlation energy can be partitioned between atomic regions. In one method, the electron density is…

Chemical Physics · Physics 2022-05-16 Jerry L. Whitten

We employ a fully relativistic coupled-cluster theory to calculate the ground-state electric dipole polarizability and electron correlation energy of superheavy elements Cn, Nh$^+$ and Og. To assess the trend of electron correlation as…

Atomic Physics · Physics 2021-06-09 Ravi Kumar , S. Chattopadhyay , D. Angom , B. K. Mani

We investigate electron correlation effects in internuclear-distance-dependent enhanced ionization of $\mathrm{H}_2$, $\mathrm{LiH}$, and $\mathrm{HF}$ molecules by intense near-infrared laser pulses using a 3D description of the systems…

Atomic Physics · Physics 2019-02-27 Siddhartha Chattopadhyay , Lars Bojer Madsen

We present electric dipole polarizabilities ($\alpha_d$) of the alkali-metal negative ions, from H$^-$ to Fr$^-$, by employing four-component relativistic many-body methods. Differences in the results are shown by considering Dirac-Coulomb…

Atomic Physics · Physics 2021-01-07 B. K. Sahoo

Quantum correlations between two neighbor atoms are studied. It is assumed that one atomic system comprises a single auto-ionizing level and the other atom does not contain any auto-ionizing level. The excitation of both atoms is achieved…

Quantum Physics · Physics 2015-06-22 Vlasta Peřinová , Antonín Lukš , Jaromír Křepelka , Jan Peřina

For molecules and solids containing heavy elements, accurate electronic structure calculations require accounting not only for electronic correlations but also for relativistic effects. In molecules, relativity can lead to severe changes in…

Chemical Physics · Physics 2025-10-17 Gaurav Harsha , Vibin Abraham , Dominika Zgid

The concept of correlation is central to all approaches that attempt the description of many-body effects in electronic systems. Multipartite correlation is a quantum information theoretical property that is attributed to quantum states…

Accurate predictions for hydrogen molecular levels require the treatment of electrons and nuclei on an equal footing. While nonrelativistic theory has been effectively formulated this way, calculation of relativistic and quantum…

Chemical Physics · Physics 2024-01-24 Krzysztof Pachucki , Jacek Komasa

Atomic properties such as field shift constants, magnetic dipole and electric quadrupole hyperfine structure constants, Land\'e $g_J$ factors, and electric quadrupole moments that are described by electronic operators with different ranks…

Atomic Physics · Physics 2018-03-14 Pradeep Kumar , Cheng-Bin Li , B. K. Sahoo

The non-resonant two-photon one-electron ionization of neutral atoms is studied theoretically in the framework of relativistic second-order perturbation theory and independent particle approximation. In particular, the importance of…

Atomic Physics · Physics 2016-12-14 Jiri Hofbrucker , Andrey V. Volotka , Stephan Fritzsche

Electron and ion energization (i.e., heating and nonthermal acceleration) is a fundamental, but poorly understood, outcome of plasma turbulence. In this work, we present new results on this topic from particle-in-cell simulations of driven…

High Energy Astrophysical Phenomena · Physics 2019-02-13 Vladimir Zhdankin , Dmitri A. Uzdensky , Gregory R. Werner , Mitchell C. Begelman

We calculate vacuum polarization corrections to the binding energies in neutral alkali atoms Na through to the superheavy element E119. We employ the relativistic Hartree-Fock method to demonstrate the importance of relaxation of the…

Atomic Physics · Physics 2016-05-04 J. S. M. Ginges , J. C. Berengut

In this study, we report a comprehensive calculation of static dipole polarizabilities for group 12 elements using the finite-field approach in conjunction with the relativistic coupled-cluster method, including single, double, and…

Atomic Physics · Physics 2025-02-13 YingXing Cheng

Roles of electron correlation effects in the determination of attachment energies, magnetic dipole hyperfine structure constants and electric dipole (E1) matrix elements of the low-lying states in the singly charged cadmium ion (Cd$^+$)…

Atomic Physics · Physics 2018-03-14 Cheng-Bin Li , Yan-Mei Yu , B. K. Sahoo

Within a fully relativistic framework, the one-loop self-energy correction for a bound electron is derived and extended to incorporate the effects of external thermal radiation. In a series of previous works, it was shown that in quantum…

Atomic Physics · Physics 2026-03-17 M. A. Reiter , D. A. Solovyev , A. A. Bobylev , D. A. Glazov , T. A. Zalialiutdinov