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In this work, a novel ring polymer representation for multi-level quantum system is proposed for thermal average calculations. The proposed presentation keeps the discreteness of the electronic states: besides position and momentum, each…

Chemical Physics · Physics 2017-05-24 Jianfeng Lu , Zhennan Zhou

Nuclear quantum effects (NQEs) remain a major challenge for molecular simulations, as rigorous treatment requires imaginary-time path-integral methods with heavy computational overhead. Neglecting NQEs leads to systematic errors in…

Chemical Physics · Physics 2026-04-14 Jing Shen , Ziyan Ye , Ming-Zheng Du , Shi-Yu He , Dong H. Zhang , Jia-Xi Zeng , Venkat Kapil , Wei Fang

Gaussian Boson Sampling (GBS) generate random samples of photon-click patterns from a class of probability distributions that are hard for a classical computer to sample from. Despite heroic demonstrations for quantum supremacy using GBS,…

Quantum Physics · Physics 2024-02-07 Mushkan Sureka , Saikat Guha

Quantum Generative Modelling (QGM) relies on preparing quantum states and generating samples from these states as hidden - or known - probability distributions. As distributions from some classes of quantum states (circuits) are inherently…

Quantum Physics · Physics 2023-10-09 Sachin Kasture , Oleksandr Kyriienko , Vincent E. Elfving

Recently, there have been several advancements in quantum algorithms for Gibbs sampling. These algorithms simulate the dynamics generated by an artificial Lindbladian, which is meticulously constructed to obey a detailed-balance condition…

Quantum Physics · Physics 2025-12-02 Štěpán Šmíd , Richard Meister , Mario Berta , Roberto Bondesan

Gibbs sampling from continuous real-valued functions is a challenging problem of interest in machine learning. Here we leverage quantum Fourier transforms to build a quantum algorithm for this task when the function is periodic. We use the…

Quantum Physics · Physics 2024-07-23 Arsalan Motamedi , Pooya Ronagh

Multitime quantum correlation functions are central objects in physical science, offering a direct link between experimental observables and the dynamics of an underlying model. While experiments such as 2D spectroscopy and quantum control…

Chemical Physics · Physics 2024-07-10 Thomas Sayer , Andrés Montoya-Castillo

P-splines provide a flexible setting for modeling nonlinear model components based on a discretized penalty structure with a relatively simple computational backbone. Under a Bayesian inferential framework based on Markov chain Monte Carlo,…

Methodology · Statistics 2025-11-03 Oswaldo Gressani , Paul H. C. Eilers

This study employed an artificial intelligence-enhanced molecular simulation framework to enable efficient Path Integral Molecular Dynamics (PIMD) simulations. Owing to its modular architecture and high-throughput capabilities, the…

Chemical Physics · Physics 2025-04-01 Cheng Fan , Maodong Li , Sihao Yuan , Zhaoxin Xie , Dechin Chen , Yi Isaac Yang , Yi Qin Gao

We provide a noisy intermediate-scale quantum framework for simulating the dynamics of open quantum systems, generalized time evolution, non-linear differential equations and Gibbs state preparation. Our algorithm does not require any…

Quantum Physics · Physics 2023-01-31 Tobias Haug , Kishor Bharti

In this thesis, I present several results on quantum statistical inference in the following two directions. Firstly, I demonstrate that quantum algorithms can be applied to enhance the computing and training of Gaussian processes (GPs), a…

Quantum Physics · Physics 2018-12-13 Zhikuan Zhao

Boltzmann machine is a powerful machine learning model with many real-world applications, for example by constructing deep belief networks. Statistical inference on a Boltzmann machine can be carried out by sampling from its posterior…

Quantum Physics · Physics 2023-11-23 Mārtiņš Kālis , Andris Locāns , Rolands Šikovs , Hassan Naseri , Andris Ambainis

Estimating thermal expectation values of observables is a fundamental task in quantum physics, quantum chemistry, and materials science. While recent quantum algorithms have enabled efficient quantum preparation of thermal states,…

Quantum Physics · Physics 2026-02-16 Jiaqing Jiang , Jiaqi Leng , Lin Lin

In molecular dynamics (MD) simulations, accessing transition probabilities between states is crucial for understanding kinetic information, such as reaction paths and rates. However, standard MD simulations are hindered by the capacity to…

Chemical Physics · Physics 2025-08-07 Yanbin Wang , Jakub Rydzewski , Ming Chen

Mean-field molecular dynamics based on path integrals is used to approximate canonical quantum observables for particle systems consisting of nuclei and electrons. A computational bottleneck is the sampling from the Gibbs density of the…

Numerical Analysis · Mathematics 2023-11-30 Xin Huang , Petr Plechac , Mattias Sandberg , Anders Szepessy

We consider Bayesian inference from multiple time series described by a common state-space model (SSM) structure, but where different subsets of parameters are shared between different submodels. An important example is disease-dynamics,…

Methodology · Statistics 2022-10-17 Anna Wigren , Fredrik Lindsten

Studying finite-temperature properties with tensor networks is notoriously difficult, especially at low temperatures, due to the rapid growth of entanglement and the complexity of thermal states. Existing methods like purification and…

Strongly Correlated Electrons · Physics 2026-01-15 Tomoya Takahashi , Wei-Lin Tu , Ji-Yao Chen , Yusuke Nomura

Graphical models are useful tools for describing structured high-dimensional probability distributions. Development of efficient algorithms for generating unbiased and independent samples from graphical models remains an active research…

Quantum Physics · Physics 2026-04-02 Nico Piatkowski , Christa Zoufal

Gaussian wave packets (GWPs) are well suited as basis functions to describe the time evolution of arbitrary wave functions in systems with nonsingular smooth potentials. They are less so in atomic systems on account of the singular behavior…

Atomic Physics · Physics 2015-05-13 Tomaž Fabčič , Jörg Main , Günter Wunner

We develop a rigorous and implementable framework for Gibbs sampling of infinite-dimensional quantum systems governed by unbounded Hamiltonians. Extending dissipative Gibbs samplers beyond finite dimensions raises fundamental obstacles,…

Quantum Physics · Physics 2026-04-02 Simon Becker , Cambyse Rouzé , Robert Salzmann