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Rabi oscillations typify the inherent nonlinearity of optical excitations in quantum dots. Using an integral kernel formulation to solve the 3D Maxwell-Bloch equations in ensembles of up to $10^4$ quantum dots, we observe features in Rabi…

Atomic and Molecular Clusters · Physics 2017-09-13 Connor Glosser , B. Shanker , Carlo Piermarocchi

A model designed to mimic the implications of the collective optical response of molecular ensembles in optical cavities on molecular vibronic dynamics is investigated. Strong molecule-radiation field coupling is often reached when a large…

Chemical Physics · Physics 2022-10-05 Bingyu Cui , Abraham Nitzan

The strong coupling of an IR-active molecular transition with an optical mode of the cavity results in vibrational polaritons, which opens a new way to control chemical reactivity via confined electromagnetic fields of the cavity. In this…

From the high vibrational dipolar strength offered by molecular liquids, we demonstrate that a molecular vibration can be ultra-strongly coupled to multiple IR cavity modes, with Rabi splittings reaching $24\%$ of the vibration frequencies.…

We show how the switching-on of an electron transport through a system of two parallel quantum dots embedded in a short quantum wire in a photon cavity can trigger coupled Rabi and collective electron-photon oscillations. We select the…

Mesoscale and Nanoscale Physics · Physics 2015-07-22 Vidar Gudmundsson , Anna Sitek , Pei-yi Lin , Nzar Rauf Abdullah , Chi-Shung Tang , Andrei Manolescu

Following our recent numerical study [arXiv:2601.16299 (2026)], we investigate vibrational excitation induced by transient optical driving in molecular ensembles strongly coupled to a cavity mode using the field-driven…

We propose collective nuclear polaritons formed by hybridizing a 229Th nuclear ensemble with a vacuum-ultraviolet cavity mode generated via four-wave mixing, achieving a collective light-matter coupling that scales as $\sqrt{N}$. In the…

Quantum Physics · Physics 2026-03-17 Liufeng Yang , Jinling Wang , Huijun Li , Junhui Cao , Alexey Kavokin , Congjun Wu

Recent advances in polaritonic chemistry suggest that chemical reactions can be controlled via collective vibrational strong coupling (VSC) in a cavity. In this fully analytical work, we demonstrate that the collective vibrations of a…

Quantum Physics · Physics 2025-04-15 Vasil Rokaj , Ilia Tutunnikov , H. R. Sadeghpour

Cavity polaritons, quasiparticles formed by coherent light-matter coupling, are at the heart of fundamental concepts of quantum optics. The quintessential signature of this coherent coupling is the Rabi oscillation, which results from the…

Quantum Physics · Physics 2025-07-28 Ishaan Ganti , Jianshu Cao

Semiconductor quantum dots in photonic cavities are strongly coupled light-matter systems with prospective applications in optoelectronic devices and quantum information processing. Here we present a theoretical study of the coupled…

Mesoscale and Nanoscale Physics · Physics 2020-06-16 K. Jürgens , F. Lengers , T. Kuhn , D. E. Reiter

Molecular polaritons are hybrid light-matter states that enable the exploration of potential cavity-modified chemistry. The development of dynamical, first-principles approaches for simulating molecular polaritons is important for…

Chemical Physics · Physics 2025-07-18 Millan F. Welman , Tao E. Li , Sharon Hammes-Schiffer

Strong coupling between molecular excitations and quantized electromagnetic fields in optical cavities provides a powerful means to control the physical and chemical properties of molecular systems. Here, we study electron transfer (ET)…

Chemical Physics · Physics 2026-03-02 Takumi Hidaka , Tomohiro Fukushima , Nguyen Thanh Phuc

For a small fraction of hot CO2 molecules immersed in a liquid-phase CO2 thermal bath, classical cavity molecular dynamics simulations show that forming collective vibrational strong coupling (VSC) between the C=O asymmetric stretch of CO2…

Chemical Physics · Physics 2021-05-11 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

The experimental realization of strong light-matter coupling with molecules initiated the rapidly evolving field of molecular polaritonics. Most studies focus on how exciton polaritons, which combine electronic excitations with confined…

Chemical Physics · Physics 2025-09-10 Lucas Borges , Thomas Schnappinger , Markus Kowalewski

Coherent light-matter interaction at the single photon and electronic qubit level promises the remarkable potential for nonclassical information processing. Against the efforts of improving the figure of merit of the cavities, here we…

Quantum Physics · Physics 2015-06-19 Yong-Chun Liu , Xingsheng Luan , Hao-Kun Li , Qihuang Gong , Chee Wei Wong , Yun-Feng Xiao

Recent experiments have observed that the chemical and photophysical properties of molecules can be modified inside an optical Fabry-Perot microcavity under collective vibrational strong coupling (VSC) conditions, and such modification is…

Mesoscale and Nanoscale Physics · Physics 2021-03-09 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

Understanding the dynamical behavior of quasiparticles is essential for uncovering novel quantum many-body phenomena. Among these phenomena, the polaron in ultracold atomic gases has attracted considerable interest due to its precise…

Quantum Gases · Physics 2025-04-21 Zeyu Liu , Pengfei Zhang

We examine cold atomic collisions within a resonant optical cavity. The quantized cavity mode can be used to manipulate the collisions between the cold atoms, such that periodic exchange of excitations between the atoms and the…

Quantum Physics · Physics 2009-11-07 J. I. Kim , P. Nussenzveig

Molecular polaritons have become an emerging platform for remotely controlling molecular properties through strong light-matter interactions. Herein, a semiclassical approach is developed for describing molecular polaritons by…

Chemical Physics · Physics 2022-04-19 Tao E. Li , Zhen Tao , Sharon Hammes-Schiffer

We consider an ensemble of homonuclear diatomic molecules coupled to the two polarization directions of a Fabry-P\'erot cavity via fully quantum simulations. Accompanied by analytical results, we identify a coupling mechanism mediated…

Chemical Physics · Physics 2024-01-22 Niclas Krupp , Oriol Vendrell
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