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The optical hybridization of the electronic states in strongly coupled molecule-cavity systems have revealed unique properties such as lasing, room temperature polariton condensation, and the modification of excited electronic landscapes…

We demonstrate that collective vibrational strong coupling of molecules in thermal equilibrium can give rise to significant local electronic polarizations in the thermodynamic limit. We do so by first showing that the full non-relativistic…

We propose a physical mechanism which enables permanent Rabi oscillations in driven-dissipative condensates of exciton-polaritons in semiconductor microcavities subjected to external magnetic fields. The method is based on incoherent…

Mesoscale and Nanoscale Physics · Physics 2018-07-10 I. Y. Chestnov , S. S. Demirchyan , S. M. Arakelian , A. P. Alodjants , Y. G. Rubo , A. V. Kavokin

Strong molecule-light interaction enables the control of molecular structures and dynamical processes. A model with strong laser drive is proposed to greatly enhance the intermolecular distance of resonant energy transfer, where the…

Quantum Physics · Physics 2021-01-27 Xuanhua Wang , Zhedong Zhang , Jin Wang

Cold atoms are promising platforms for metrology and quantum computation, yet their many-body dynamics remains largely unexplored. We here investigate Rabi oscillations from optically-thick cold clouds, driven by high-intensity coherent…

Atomic Physics · Physics 2026-01-15 Mateus A. F. Biscassi , Robin Kaiser , Mathilde Hugbart , Romain Bachelard

We propose a cavity QED approach to describe light-matter interaction between an individual anharmonic molecular vibration and an infrared cavity field. Starting from a generic Morse oscillator with quantized nuclear motion, we derive a…

Chemical Physics · Physics 2019-10-16 Federico Hernández , Felipe Herrera

Under vibrational strong coupling (VSC), the formation of molecular polaritons may significantly modify the photo-induced or thermal properties of molecules. In an effort to understand these intriguing modifications, both experimental and…

Chemical Physics · Physics 2022-04-07 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

Polaritons have gained significant attention for the tantalizing possibility of modifying chemical properties and dynamics by coupling molecules to resonant cavity modes to create hybrid light-matter quantum states. Herein, we implement the…

Chemical Physics · Physics 2025-06-24 Scott M. Garner , Xiaosong Li , Sharon Hammes-Schiffer

We study the elastic response of a stationarily driven system of a cavity field strongly coupled with molecular excitons, taking into account the main dissipation channels due to the finite cavity linewidth and molecular vibrations. We show…

Quantum Physics · Physics 2021-02-24 Kalle S. U. Kansanen , J. Jussi Toppari , Tero T. Heikkilä

We study theoretically the quantum dynamics and spectroscopy of rovibrational polaritons formed in a model system composed of a single rovibrating diatomic molecule, which interacts with two degenerate, orthogonally polarized modes of an…

Chemical Physics · Physics 2023-01-11 Eric W. Fischer , Peter Saalfrank

The collective dynamics of two non-interacting two-level emitters, which are coupled to a structured wave guide that supports two-photon bound states, is investigated. Tuning the energy of the two emitters such that they are in resonance…

Quantum Gases · Physics 2023-01-25 J. Talukdar , D. Blume

Strong coupling between excitons and confined modes of light presents a promising pathway to tunable and enhanced energy transport in organic materials. By forming hybrid light-matter quasiparticles, exciton-polaritons, electronic…

Chemical Physics · Physics 2024-11-01 Niclas Krupp , Gerrit Groenhof , Oriol Vendrell

Recent experiments have revealed the profound effect of strong light-matter interactions in optical cavities on the electronic ground state of molecular systems. This phenomenon, known as vibrational strong coupling (VSC), can modify…

Quantum Physics · Physics 2023-12-19 Thomas Schnappinger , Markus Kowalewski

We theoretically analyze exciton-photon oscillatory dynamics within a homogenous polariton gas in presence of energy detuning between the cavity and quantum well modes. Whereas pure Rabi oscillations consist of the particle exchange between…

Mesoscale and Nanoscale Physics · Physics 2015-11-17 Nina Voronova , Andrei Elistratov , Yurii Lozovik

We study the resonant electronic excitation dynamics for ultracold atoms trapped in a deep optical lattice prepared in a Mott insulator state. Excitons in these artificial crystals are similar to Frenkel excitons in Noble atom or molecular…

Quantum Physics · Physics 2009-08-11 Hashem Zoubi , Helmut Ritsch

Polaritons, in particular microcavity exciton-polaritons, have attracted much attention in recent years, as the phenomena of Bose-Einstein condensation and superfluidity have been observed for these quasiparticles. While the basic physics…

Quantum Gases · Physics 2015-09-07 David Snoke

We propose a novel physical mechanism for creation of long lived macroscopic exciton-photon qubits in semiconductor microcavities with embedded quantum wells in the strong couping regime. We argue that the coherence time of Rabi…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 S. S. Demirchyan , I. Yu. Chestnov , A. P. Alodjants , M. M. Glazov , A. V. Kavokin

Polariton chemistry exploits the strong interaction between quantized excitations in molecules and quantized photon states in optical cavities to affect chemical reactivity. Molecular polaritons have been experimentally realized by the…

Chemical Physics · Physics 2023-09-06 Jonathan J. Foley , Jonathan F. McTague , A. Eugene DePrince

We demonstrate coherent one-color photoassociation of a Bose-Einstein condensate, which results in Rabi oscillations between atomic and molecular condensates. We attain atom-molecule Rabi frequencies that are comparable to decoherence rates…

Atomic Physics · Physics 2013-10-11 Mi Yan , B. J. DeSalvo , Ying Huang , P. Naidon , T. C. Killian

We propose a scheme of enhancement of Rabi coupling between two identical atomic ensembles trapped inside an optical cavity in a membrane-in-the-middle set up. The cavity modes dispersively interact with the ensembles and the effective…

Quantum Physics · Physics 2017-03-08 Anil K. Chauhan , Asoka Biswas