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Related papers: Segregation-Controlled Diffusion-Induced Grain Bou…

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We present a novel phase-field approach for investigating solute segregation in a moving grain boundary. In our model, the correct choice of various parameters can control the solute-grain boundary interaction potential, resulting in…

Materials Science · Physics 2023-08-17 Sandip Guin , Miral Verma , Soumya Bandyopadhyay , Yu-Chieh Lo , Rajdip Mukherjee

Solute segregation in alloys is a key phenomenon which affects various material characteristics such as embrittlement, grain growth and precipitation kinetics. In this work, the segregation energies of Y, Zr, and Nb to a \textgreek{S}5…

Materials Science · Physics 2025-03-06 Hariharan Umashankar , Daniel Scheiber , Vsevolod I. Razumovskiy , Matthias Militzer

The response of Ni-Cr alloys to exposure to molten chloride and fluoride salts is typically characterized by Cr dealloying with the formation of a Cr-depleted bi-continuous porous subsurface layer. The exact mechanism behind the loss of Cr…

Materials Science · Physics 2026-04-15 Konnor Walter , Jagadeesh Sure , Adrien Couet , Emmanuelle A. Marquis

This work investigates how grain boundaries (GBs) modify magnetic exchange interactions in bcc iron, with particular focus on the effect of phosphorus segregation. Using density-functional theory combined with the…

Materials Science · Physics 2026-04-14 Martin Zelený , Martin Heczko , Petr Šesták , Denis Ledue , Renaud Patte , Miroslav Černý

Recent experimental measurements of Ag impurity diffusion in the {\Sigma}5 (310) grain boundary (GB) in Cu revealed an unusual non-Arrhenius behavior suggestive of a possible structural transformation [Divinski et al., Phys. Rev. B 85,…

Materials Science · Physics 2013-06-24 T. Frolov , S. V. Divinski , M. Asta , Y. Mishin

Grain boundary embrittlement occurs when a solute enriches at a grain boundary and lowers its cohesive energy. While grain boundary enrichment is often attributed to equilibrium segregation effects, most models of embrittlement consider…

Materials Science · Physics 2015-08-18 Michael A. Gibson , Christopher A. Schuh

Grain structure plays a key role in the mechanical properties of alloy materials. Engineering the grain structure requires a comprehensive understanding of the evolution of grain boundaries (GBs) when a material is subjected to various…

Materials Science · Physics 2021-10-26 Junyan He , Nikhil Chandra Admal

The grain boundary (GB) mobility relates GB velocity to the thermodynamic driving forces and is central to our understanding of microstructure evolution in polycrystals. Recent molecular dynamics (MD) and experimental studies have shown…

Materials Science · Physics 2020-11-18 Kongtao Chen , Jian Han , David J. Srolovitz

Grain boundary (GB) segregation is a powerful approach for optimizing the thermal and mechanical properties of metal alloys. In this study, we report significant GB interstitial segregation in a representative substitutional binary alloy…

Materials Science · Physics 2025-05-27 Zuoyong Zhang , Chuang Deng

Computing the grain boundary (GB) counterparts to bulk phase diagrams represents an emerging research direction. Using a classical embrittlement model system Ga-doped Al alloy, this study demonstrates the feasibility of computing…

Materials Science · Physics 2022-01-20 Chongze Hu , Yanwen Li , Zhiyang Yu , Jian Luo

First-principles calculations were carried out to study the segregation behavior of Mg, and Cu and their effect on the energy and mechanical properties of different Al grain boundaries (GBs). Four symmetrical tilt GBs were selected for…

Materials Science · Physics 2023-05-29 Xuan Zhang , Liang Zhang , Zhihui Zhang , Xiaoxu Huang

Grain boundaries (GB) profoundly influence the electrical properties of polycrystalline ionic solids. Yet, precise control of their transport characteristics has remained elusive, thereby limiting the performance of solid-state…

Polycrystalline materials can be viewed as composites of crystalline particles or grains separated from one another by thin amorphous grain boundary (GB) regions. While GB have been exhaustively investigated at low temperatures, where these…

Materials Science · Physics 2015-05-13 Hao Zhang , David J. Srolovitz , Jack F. Douglas* , James A. Warren

Grain boundary segregations were investigated by Atom Probe Tomography in an Al-Mg alloy, a carbon steel and Armco\trademark Fe processed by severe plastic deformation (SPD). In the non-deformed state, the GBs of the aluminium alloy are Mg…

Materials Science · Physics 2012-11-22 Xavier Sauvage , Artur Ganeev , Yulia Ivanisenko , Nariman Enikeev , Maxim Murashkin , R. Z. Valiev

Grain boundary (GB) diffusion in polycrystalline materials is a physical phenomenon of great fundamental interest and practical significance. Although the accelerated ("short circuit") atomic transport along GBs has been known for decades,…

Materials Science · Physics 2022-08-02 Ian Chesser , Yuri Mishin

Grain boundary tracer diffusion of Ni, Fe and Cr was studied in a Ni-base 602CA coarse-grained alloy. A co-existence of several short-circuit contributions was distinguished at higher temperatures in Harrison's B-type regime (773-873 K),…

Mg alloys are promising lightweight structural materials due to their low density and excellent mechanical properties. However, their limited formability and ductility necessitate improvements in these properties, specifically through…

We present a multiscale modelling framework that integrates density functional theory (DFT) with a phase-field model (PFM) to explore the intricate dynamics of grain growth in nanocrystalline {\alpha}-Fe single-phase alloy in the presence…

Materials Science · Physics 2024-06-13 Sandip Guin , Albert Linda , Yu-Chieh Lo , Somanth Bhowmick , Rajdip Mukherjee

Grain boundary (GB) segregation of solute atoms plays an important role in the microstructure and macroscopic mechanical properties of materials. The study of GB segregation of solute atoms using computational simulation has become one of…

Materials Science · Physics 2023-05-29 Zhihui Zhang , Liang Zhang , Xuan Zhang , Xiaoxu Huang

Grain boundaries (GBs) trigger structure-specific chemical segregation of solute atoms. According to the three-dimensional (3D) topology of grains, GBs - although defined as planar defects - cannot be free of curvature. This implies…