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Atomic structure and electronic band structure are fundamental properties for understanding the mechanism of superconductivity. Motivated by the discovery of pressure-induced high-temperature superconductivity at 80 K in the bilayer…

The recent discovery of high-temperature superconductivity in high-pressurized La$_3$Ni$_2$O$_{7-\delta}$ has garnered significant attention. Using density functional theory, we investigate the magnetic properties of…

Materials Science · Physics 2024-12-30 Xiao-Sheng Ni , Yuyang Ji , Lixin He , Tao Xie , Dao-Xin Yao , Meng Wang , Kun Cao

We report an unexpected trans-proximate interlayer correlation (stronger correlation between disjoint layers than the adjacent ones) in the high-pressure phase of the recently discovered La$_4$Ni$_3$O$_{10}$ superconductors. Accompanied by…

Superconductivity · Physics 2025-10-29 Ruoshi Jiang , Zhiyu Fan , Bartomeu Monserrat , Wei Ku

While defects such as oxygen vacancies in correlated materials can modify their electronic properties dramatically, understanding the microscopic origin of electronic correlations in materials with defects has been elusive. Lanthanum…

Strongly Correlated Electrons · Physics 2021-02-24 Xingyu Liao , Vijay Singh , Hyowon Park

We present electronic structure calculations on layered nickelate oxyfluorides derived from the Ruddlesden-Popper arisotype structure in search of unidentified materials that may host nickelate superconductivity. By performing anion…

Oxygen vacancies in nickelates are known to introduce a variety of emergent phenomena and are considered to significantly affect conductivity. Few studies have examined real-space evidence for oxygen vacancies on the surface, particularly…

Materials Science · Physics 2024-10-10 Michael Verhage , Kees Flipse

We report on the in-plane anisotropy of the electronic response in the spin/charge/orbital ordered phase of a half-doped layered-structure manganite. The optical conductivity spectra for a single domain of Eu$_{1/2}$% Ca$_{3/2}$MnO$_{4}$…

Strongly Correlated Electrons · Physics 2009-11-11 Y. S. Lee , S. Onoda , T. Arima , Y. Tokunaga , J. P. He , Y. Kaneko , N. Nagaosa , Y. Tokura

The recently synthesized layered nickelate La$_4$Ni$_3$O$_8$, with its cuprate-like NiO$_2$ layers, seemingly requires a Ni1 ($d^8$)+2Ni2 ($d^9$) charge order, together with strong correlation effects, to account for its insulating…

Strongly Correlated Electrons · Physics 2015-05-19 Victor Pardo , Warren E. Pickett

Understanding the magnetic ground state of Ruddlesden-Popper nickelates is crucial, as these materials exhibit superconductivity under high pressure and host competing electronic orders that may play a key role in the pairing mechanism. In…

The recent discovery of superconductivity in bilayer La$_3$Ni$_2$O$_7$ (327-LNO) under pressure stimulated much interest in layered nickelates. However, superconductivity was not found in another bilayer nickelate system, La$_3$Ni$_2$O$_6$…

Superconductivity · Physics 2024-02-09 Yang Zhang , Ling-Fang Lin , Adriana Moreo , Thomas A. Maier , Elbio Dagotto

Low-valent nickelates R$_{n+1}$Ni$_n$O$_{2n+2}$ (R = rare earth) containing Ni$^{1+}$ (d$^{9}$) with a quasi-two-dimensional (quasi-2D) square planar coordination geometry possess structural and electronic properties that are similar to…

Based on the discovery of high-temperature superconductivity in the bilayer nickelate La$_3$Ni$_2$O$_7$, several Co-based La$_3$Ni$_2$O$_7$-like materials were theoretically predicted as possible high-temperature superconductors by electron…

Strongly Correlated Electrons · Physics 2026-04-02 Si-Yong Jia , Jing-Xuan Wang , Jian-Hong She , Rong-Qiang He , Zhong-Yi Lu

Recently, superconductivity with a $T_c$ up to 78 K has been reported in bulk samples of the bilayer nickelate La$_3$Ni$_2$O$_7$ at pressures above 14 GPa. Important theoretical tasks are the formulation of relevant low-energy models and…

Strongly Correlated Electrons · Physics 2023-11-17 Viktor Christiansson , Francesco Petocchi , Philipp Werner

Superconductivity in La$_{4}$Ni$_{3}$O$_{10}$ has been reported to emerge upon suppression of intertwined spin and charge density wave (SDW/CDW) order, suggesting a possible connection to the pairing mechanism. Here we report a systematic…

Strongly Correlated Electrons · Physics 2025-07-22 Stephen Zhang , Danrui Ni , Ruyi Ke , Guangming Cheng , Nan Yao , Robert J. Cava

Recent neutron scattering measurements reveal spin and charge ordering in the half-doped nickelate, La$_{3/2}$ Sr$_{1/2}$ NiO$_4$. Many of the features of the magnetic excitations have been explained in terms of the spin waves of diagonal…

Strongly Correlated Electrons · Physics 2007-05-23 D. X. Yao , E. W. Carlson

The discovery of high-temperature superconductivity in layered nickelates under pressure has recently triggered enormous interest. Studies of these compounds have revealed a density-wave-like transition at ambient pressure, though its…

Intertwined charge and spin correlations are ubiquitous in a wide range of transition metal oxides and are often perceived as intimately related to unconventional superconductivity. Theoretically envisioned as driven by strong electronic…

We explore the optical properties of La3Ni2O7 bilayer nickelates by using density functional theory including a Coulomb repulsion term. Convincing agreement with recent experimental ambient-pressure spectra is achieved for U=3eV, which…

The series of nickel-oxide compounds LaNiO$_3$ (formal Ni$(d^7)$), La$_2$NiO$_4$ (formal Ni$(d^8)$) and LaNiO$_2$ (formal Ni$(d^9)$) is investigated by first-principles many-body, using a combination of density functional theory,…

Strongly Correlated Electrons · Physics 2022-04-07 Frank Lechermann

The discovery of high-temperature superconductivity in La$_3$Ni$_2$O$_7$ and La$_4$Ni$_3$O$_{10}$ under pressure has drawn extensive attention. Herein, we report systematic investigations on the evolutions of structure, magnetism, and…