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Solar cells based on hybrid perovskites have shown high efficiency while possessing simple processing methods. To gain a fundamental understanding of their properties on an atomic level, we investigate single crystals of CH3NH3PbI3 with a…

Materials Science · Physics 2017-07-14 T. A. Tyson , W. Gao , Y. -S. Chen , S. Ghose , Y. Yan

Excitonic/electronic coupling and cooperative interactions in self-assembled lead halide perovskite nanocrystals were reported to give rise to a collective low energy emission peak with accelerated dynamics. Here we report that similar…

Size- and shape- dependent unique properties of the metal halide perovskite nanocrystals make them promising building blocks for constructing various electronic and optoelectronic devices. These unique properties together with their easy…

Materials Science · Physics 2023-06-07 Athanasia Kostopoulou , Ioannis Konidakis , Emmanuel Stratakis

Scintillators cover an important wide range of applications in detection and imaging. In this paper we are presenting growth and performance results of several advanced large diameter thallium-based ternary halide crystals are presented.…

Instrumentation and Detectors · Physics 2023-09-14 Rastgo Hawrami

Metal halide perovskites have emerged as an exciting class of materials for applications in solar energy harvesting, optical devices, catalysis, and other photophysical applications. Many of the exciting properties of halide perovskites are…

Materials Science · Physics 2024-04-18 Colin M. Hylton-Farrington , Richard C. Remsing

Outstanding optoelectronic properties and a facile synthesis render halide perovskite nanocrystals (NCs) a promising material for nanostructure-based devices. However, the commercialization is hindered mainly by the lack of NC stability…

Mesoscale and Nanoscale Physics · Physics 2022-09-26 Michèle G. Greiner , Andreas Singldinger , Nina A. Henke , Carola Lampe , Ulrich Leo , Moritz Gramlich , Alexander S. Urban

In recent years, halide perovskite materials have been used to make high performance solar cell and light-emitting devices. However, material defects still limit device performance and stability. Here, we use synchrotron-based Bragg…

Halide perovskites are a promising class of materials for optoelectronic applications, due to their excellent optoelectronic performance. However, they suffer several dynamical degradation problems, the characterization of which is…

Materials Science · Physics 2021-11-01 Sander Raaijmakers , Mike Pols , José Manuel Vicent-Luna , Shuxia Tao

We correlate spatially resolved fluorescence (-lifetime) measurements with X-ray nanodiffraction to reveal surface defects in supercrystals of self-assembled caesium lead halide perovskite nanocrystals and study their effect on the…

Two-dimensional colloidal halide perovskite nanocrystals are promising materials for light emitting applications. In addition, they can be used as components to create a variety of materials through physical and chemical transformations.…

The organic-inorganic hybrid perovskite CH3NH3PbI3 has attracted significant interest for its high performance in converting solar light into electrical power with an efficiency exceeding 20%. Unfortunately, chemical stability is one major…

Materials Science · Physics 2018-03-02 Yue-Yu Zhang , Shiyou Chen , Peng Xu , Hongjun Xiang , Xin-Gao Gong , Aron Walsh , Su-Huai Wei

Recent observations indicated that the photoelectric conversion properties of perovskite materials are intimately related to the presence of superlattice structures and other unusual nanoscale features in them. The low dimensional or mixed…

Mesoscale and Nanoscale Physics · Physics 2021-05-11 Susmita Bhattacharya , Goutam Kumar Chandra , P. Predeep

Previous theoretical calculations show azetidinium has the right radial size to form a 3D perovskite with lead halides [1], and has been shown to impart, as the A-site cation of ABX3 unit, beneficial properties to ferroelectric perovskites…

Lead-halide perovskites are a promising material platform as semiconductors in next-generation solar cells because of their solution processability, defect tolerance, and tunable optoelectronic properties. While iodide-bromide perovskite…

Metal halide perovskites (MHPs) have had a profound impact on numerous emerging optoelectronic technologies, achieving performance metrics that rival or exceed incumbent materials. This impact is underpinned by the exceptional properties of…

Surface-defect passivation is key to achieving high photoluminescence quantum yield in lead halide perovskite nanocrystals. However, in perovskite light-emitting diodes these surface ligands also have to enable balanced charge injection…

The fabrication of large, high-quality single crystals (SCs) of all-inorganic cesium lead bromide (CsPbBr$_3$) via accessible methods remains a significant challenge. This work presents a systematic approach to optimize the antisolvent…

Materials Science · Physics 2025-12-30 I. O. Simonenko , R. G. Nazmitdinov , T. N. Vershinina

Instability of hybrid organic-inorganic halide perovskites hinders their development for photovoltaic applications. First-principle calculations are used for evaluation of a decomposition reaction enthalpy of hybrid halide perovskites,…

Materials Science · Physics 2017-06-19 Chao Zheng , Oleg Rubel

Halide perovskites are highly promising light-harvesting materials with strong ionic character, enabling in principle the combination of a solar cell and a Li-ion battery in one integrated photo-battery device. Here, we investigate Li ions…

Materials Science · Physics 2024-03-05 Wei Wei , Julian Gebhardt , Daniel F. Urban , Christian Elsässer

The structural, electronic, optical and elastic properties of perovskites of the $\alpha$-, $\beta$- and $\gamma$-phase family CsSnI$_{3-x}$Cl$_x$ (x = 0, 1, 2, 3) are analyzed by ab initio methods using GGA, SCAN and HSE06. It is found…