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We study theoretically the effects of spatial confinement on the phoretic motion of a dissolved particle driven by composition gradients generated by chemical reactions of its solvent, which are active only on certain parts of the particle…

Soft Condensed Matter · Physics 2010-05-11 M. N. Popescu , S. Dietrich , G. Oshanin

Breaking spatial symmetry is an essential requirement for phoretic active particles to swim at low Reynolds number. This fundamental prerequisite for swimming at the micro-scale is fulfilled either by chemical patterning of the surface of…

Soft Condensed Matter · Physics 2022-04-20 Abdallah Daddi-Moussa-Ider , Andrej Vilfan , Ramin Golestanian

We study theoretically the phoretic motion of a spheroidal particle, which generates solute gradients in the surrounding unbounded solvent via chemical reactions active on its surface in a cap-like region centered at one of the poles of the…

Statistical Mechanics · Physics 2010-07-27 M. N. Popescu , S. Dietrich , M. Tasinkevych , J. Ralston

We study the diffusiophoretic self-propulsion of a colloidal catalytic particle due to a surface chemical reaction in a vicinity of a solid wall. Diffusiophoresis is a chemico-mechanical transduction mechanism in which a concentration…

Soft Condensed Matter · Physics 2016-06-22 Ali Mozaffari , Nima Sharifi-Mood , Joel Koplik , Charles Maldarelli

Phoretic particles self-propel using self-generated physico-chemical gradients at their surface. Within a suspension, they interact hydrodynamically by setting the fluid around them into motion, and chemically by modifying the chemical…

Fluid Dynamics · Physics 2019-02-20 Eva Kanso , Sebastien Michelin

Self-chemophoresis is an appealing and quite successful interpretation of the motility exhibited by certain chemically active colloidal particles suspended in a solution of their "fuel": the particle has a phoretic response to…

Soft Condensed Matter · Physics 2026-01-06 Alvaro Domínguez , Mihail N. Popescu

In the presence of a chemically active particle, a nearby chemically inert particle can respond to a concentration gradient and move by diffusiophoresis. The nature of the motion is studied for two cases: first, a fixed reactive sphere and…

Soft Condensed Matter · Physics 2018-06-25 Shang Yik Reigh , Prabha Chuphal , Snigdha Thakur , Raymond Kapral

We analyse the self-diffusiophoresis of a spherical particle animated by a nonuniform chemical reaction at its boundary. We consider two models of solute absorption, one with a specified distribution of interfacial solute flux, and one…

Fluid Dynamics · Physics 2015-03-03 Ehud Yariv , Sebastien Michelin

The self-diffusion process of a hard sphere fluid confined by two parallel plates separated by a distance on the order of the particle diameter is studied. The starting point is a closed kinetic equation for the distribution function that…

Statistical Mechanics · Physics 2025-10-24 Manuel Mayo , María Isabel García de Soria , Pablo Maynar , José Javier Brey

We study the effect of spatial confinement on the strength of propulsive diffusiophoretic forces acting on a particle that generates density gradients by exploiting the chemical free energy of its environment. Using a recently proposed…

Statistical Mechanics · Physics 2007-09-17 M. N. Popescu , S. Dietrich , G. Oshanin

The mobility of externally-driven phoretic propulsion of particles is evaluated by simultaneously solving the solute conservation equation, interaction potential equation, and the modified Stokes equation. While accurate, this approach is…

Fluid Dynamics · Physics 2024-08-16 Arkava Ganguly , Souradeep Roychowdhury , Ankur Gupta

Colloidal spheres with a partial platinum surface coating perform auto-phoretic motion when suspended in hydrogen peroxide solution. We present a theoretical analysis of the self-propulsion velocity of these particles using a continuum…

Soft Condensed Matter · Physics 2015-02-12 Joost de Graaf , Georg Rempfer , Christian Holm

Artificial phoretic particles swim using self-generated gradients in chemical species (self-diffusiophoresis) or charges and currents (self-electrophoresis). These particles can be used to study the physics of collective motion in active…

Soft Condensed Matter · Physics 2017-10-26 David Sondak , Cory Hawley , Siyu Heng , Rebecca Vinsonhaler , Eric Lauga , Jean-Luc Thiffeault

We study flows generated within a two-dimensional corner by the chemical activity of the confining boundaries. Catalytic reactions at the surfaces induce diffusioosmotic motion of the viscous fluid throughout the domain. The presence of…

Fluid Dynamics · Physics 2026-01-21 Dobromir Nowak , Maciej Lisicki

The dynamics of self-propelled colloidal particles are strongly influenced by their environment through hydrodynamic and, in many cases, chemical interactions. We develop a theoretical framework to describe the motion of confined active…

Fluid Dynamics · Physics 2025-08-29 Günther Turk , Rajesh Singh , Howard A. Stone

The propulsion of active particles by self-diffusiophoresis is driven by asymmetric catalytic reactions on the particle surface that generate a mechanochemical coupling between the fluid velocity and the concentration fields of fuel and…

Statistical Mechanics · Physics 2018-12-24 Pierre Gaspard , Raymond Kapral

Self-diffusiophoretic particles exploit local concentration gradients of a solute species in order to self-propel at the micron scale. While an isolated chemically- and geometrically-isotropic particle cannot swim, we show that it can…

Soft Condensed Matter · Physics 2018-06-12 Akhil Varma , Thomas D. Montenegro-Johnson , Sebastien Michelin

Phoretic self-propulsion is a unique example of force- and torque-free motion on small scales. The classical framework describing the flow field around a particle swimming by self-diffusiophoresis neglects the advection of the solute field…

Fluid Dynamics · Physics 2014-04-25 Sébastien Michelin , Eric Lauga

We study the autophoretic motion of a spherical active particle interacting chemically and hydrodynamically with its fluctuating environment in the limit of rapid diffusion and slow viscous flow. Then, the chemical and hydrodynamic fields…

Soft Condensed Matter · Physics 2024-11-04 Günther Turk , Ronojoy Adhikari , Rajesh Singh

The dynamics of anisotropic particles in viscous flows underpin a wide range of processes in soft matter, microfluidics, and targeted drug delivery. Here, we investigate the motion of externally driven prolate and oblate spheroids suspended…

Soft Condensed Matter · Physics 2026-03-24 Aditya Bhowmik , Kevin Stratford , Oliver Henrich , Sumesh P. Thampi
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