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We consider a fluid of hard spheres bearing one or two uniform circular adhesive patches, distributed so as not to overlap. Two spheres interact via a ``sticky'' Baxter potential if the line joining the centers of the two spheres intersects…

Statistical Mechanics · Physics 2009-11-13 Riccardo Fantoni , Domenico Gazzillo , Achille Giacometti , Mark A. Miller , Giorgio Pastore

One versatile route to the creation of two-dimensional crystal structures on the nanometer to micrometer scale is the self-assembly of colloidal particles at an interface. Here, we explore the crystal phases that can be expected from the…

Soft Condensed Matter · Physics 2020-05-29 Etienne Fayen , Anuradha Jagannathan , Giuseppe Foffi , Frank Smallenburg

Self-assembly of colloidal particles is a promising avenue to control the shape and dynamics of larger aggregates. However, achieving the necessary fine control over the dynamics and specificity of the bonds between such particles remains a…

Soft Condensed Matter · Physics 2024-09-26 Muraleedharapai Mayarani , Justine Laurent , Martin Lenz , Olivia du Roure , Julien Heuvingh

Membrane-induced interactions have been predicted to be important for the organization of membrane proteins. Measurements of the interactions between two and three membrane deforming objects have revealed their non-additive nature. They are…

Soft Condensed Matter · Physics 2024-03-11 Ali Azadbakht , Thomas R. Weikl , Daniela J. Kraft

The ordering of nanoparticles into predetermined configurations is of importance to the design of advanced technologies. In this work, we moderate the surface anchoring against the bulk elasticity of liquid crystals to dynamically shape…

Soft Condensed Matter · Physics 2023-12-01 Lisa Tran , Hye-Na Kim , Ningwei Li , Shu Yang , Kathleen J. Stebe , Randall D. Kamien , Martin F. Haase

The rapid progress in precisely designing the surface decoration of patchy colloidal particles offers a new, yet unexperienced freedom to create building entities for larger, more complex structures in soft matter systems. However, it is…

Soft Condensed Matter · Physics 2012-06-14 G. Doppelbauer , E. G. Noya , E. Bianchi , G. Kahl

Elucidating the interplay of stress and geometry is a fundamental scientific question arising in multiple fields. In this work, we investigate the geometric frustration of crystalline caps confined on the sphere in both elastic and plastic…

Soft Condensed Matter · Physics 2022-07-22 Jingyuan Chen , Zhenwei Yao

Particles added to a fluid interface can be used as a surface stabilizer in the food, oil and cosmetic industries. As an alternative to rigid particles, it is promising to consider highly deformable particles that can adapt their…

Soft Condensed Matter · Physics 2016-10-27 Hadi Mehrabian , Jens Harting , Jacco H. Snoeijer

On microscopic scales, the crystallinity of flexible tethered or cross linked membranes determines their mechanical response. We show that by controlling the type, number and distribution of defects on a spherical elastic shell, it is…

Soft Condensed Matter · Physics 2013-06-12 Ee Hou Yong , David R. Nelson , L. Mahadevan

Spontaneous self-assembly of hard convex polyhedra are known to form orientationally disordered crystalline phases, where particle orientations do not follow the same pattern as the positional arrangement of the crystal. A distinct type of…

Soft Condensed Matter · Physics 2024-12-02 Sumitava Kundu , Kaustav Chakraborty , Avisek Das

Impurity-induced defects play a crucial role for the properties of crystals, but little is known about impurities with anisotropic shape. Here, we study how colloidal dumbbells distort and interact with a hexagonal crystal of charged…

Soft Condensed Matter · Physics 2020-10-02 Vera Meester , Casper van der Wel , Ruben W. Verweij , Giovanni Biondaro , Daniela J. Kraft

Contacts between particles in dense, sheared suspensions are believed to underpin much of their rheology. Roughness and adhesion are known to constrain the relative motion of particles, and thus globally affect the shear response, but an…

We investigate a class of "shape allophiles" that fit together like puzzle pieces as a method to access and stabilize desired structures by controlling directional entropic forces. Squares are cut into rectangular halves, which are shaped…

Soft Condensed Matter · Physics 2017-09-08 Eric S. Harper , Ryan L. Marson , Joshua A. Anderson , Greg van Anders , Sharon C. Glotzer

In this paper, we have successfully identified the triangular-shaped defect structures with stacking fault tetrahedra. These structure often appeared in hard-sphere (HS) crystals grown on a square pattern under gravity. We have, so far,…

Soft Condensed Matter · Physics 2014-09-18 Atsushi Mori , Yoshihisa Suzuki

Amorphous materials of homogeneous structures usually suffer from nonuniform deformation under shear, which can develop into shear localization and eventually destructive shear band. One approach to tackle this issue is to introduce an…

Materials Science · Physics 2019-02-01 Guo-Jie J. Gao , Yun-Jiang Wang , Shigenobu Ogata

During directional solidification of the solvent in a colloidal suspension, the colloidal particles segregate from the growing solid, forming high-particle-density regions with structure on a hierarchy of length scales ranging from that of…

Soft Condensed Matter · Physics 2011-03-09 Melissa Spannuth , S. G. J. Mochrie , S. S. L. Peppin , J. S. Wettlaufer

We demonstrate that nascent polymer crystals (i.e., nuclei) are anisotropic entities, with neither spherical nor cylindrical geometry, in contrast to previous assumptions. In fact, cylindrical, spherical, and other high symmetry geometries…

Soft Condensed Matter · Physics 2020-01-08 Kyle Wm. Hall , Timothy W. Sirk , Simona Percec , Michael L. Klein , Wataru Shinoda

When colloidal particles form a crystal phase on a spherical template, their packing is governed by the effective interaction between them and the elastic strain of bending the growing crystal. For example, if growth commences under…

Soft Condensed Matter · Physics 2017-08-09 Stefan Paquay , Gert-Jan Both , Paul van der Schoot

Colloidal crystal structures with complexity and diversity rivaling atomic and molecular crystals have been predicted and obtained for hard particles by entropy maximization. However, so far homochiral colloidal crystals, which are…

Soft Condensed Matter · Physics 2015-10-13 Pablo F. Damasceno , Andrew S. Karas , Benjamin A. Schultz , Michael Engel , Sharon C. Glotzer

Designing reconfigurable materials based on deformable nanoparticles (NPs) hinges on an understanding of the energetically-favored shapes these NPs can adopt. Using simulations, we show that hollow, deformable patchy NPs tailored with…

Soft Condensed Matter · Physics 2021-01-04 Nicholas E. Brunk , JCS Kadupitiya , Vikram Jadhao
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