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The lack of a direct map between control fields and desired control objectives poses a significant challenge in applying quantum control theory to quantum technologies. Here, we propose an analytical framework to precisely control a limited…

Quantum Physics · Physics 2025-03-05 Qian-Qian Hong , Daoyi Dong , Niels E. Henriksen , Franco Nori , Jun He , Chuan-Cun Shu

We present a combined analytical and numerical investigation to show how an optimal control field can be designed to generate maximum field-free orientation of molecules for three populated rotational states. Based on a model involving pure…

Quantum Physics · Physics 2021-07-28 Qian-Qian Hong , Li-Bao Fan , Chuan-Cun Shu , Niels E. Henriksen

We theoretically explore the precise control of a molecular polariton by strongly coupling the lowest three rotational states of a single molecule with a single-mode cavity. We examine two distinct cavity resonance configurations: a…

Quantum Physics · Physics 2025-02-17 Li-Bao Fan , Hai-Ji Li , Qi Chen , Hang Zhou , Heng Liu , Chuan-Cun Shu

The control of ultrafast molecular rotational motion has benefited from the development of innovative techniques in strong-field laser physics. Here, we theoretically demonstrate a novel type of coherent control by inducing rotation of an…

Chemical Physics · Physics 2018-08-27 Alec Owens , Andrey Yachmenev , Jochen Küpper

We present an analysis of two experimental approaches to controlling the directionality of molecular rotation with ultrashort laser pulses. The two methods are based on the molecular interaction with either a pair of pulses (a "double kick"…

Optics · Physics 2015-06-11 C. Bloomquist , S. Zhdanovich , A. A. Milner , V. Milner

The goal of quantum tracking control is to identify shaped fields to steer observable expectation values along designated time-dependent tracks. The fields are determined via an iteration-free procedure, which is based on inverting the…

Quantum Physics · Physics 2024-02-06 Alicia B. Magann , Tak-San Ho , Christian Arenz , Herschel A. Rabitz

Alignment and orientation of molecules by intense, ultrashort laser fields are crucial for a variety of applications in physics and chemistry. These include control of high harmonics generation, molecular orbitals tomography, control of…

Laser control of molecular rotation is an area of active research. A number of recent studies has aimed at expanding the reach of rotational control to extreme, previously inaccessible rotational states, as well as controlling the…

Quantum Physics · Physics 2015-01-13 V. Milner , J. W. Hepburn

We introduce a new scheme for controlling the sense of molecular rotation. By varying the polarization and the delay between two ultrashort laser pulses, we induce unidirectional molecular rotation, thereby forcing the molecules to rotate…

Quantum Physics · Physics 2015-05-13 Sharly Fleischer , Yuri Khodorkovsky , Yehiam Prior , Ilya Sh. Averbukh

The angular momentum of molecules, or, equivalently, their rotation in three-dimensional space, is ideally suited for quantum control. Molecular angular momentum is naturally quantized, time evolution is governed by a well-known Hamiltonian…

Quantum Physics · Physics 2019-10-23 Christiane P. Koch , Mikhail Lemeshko , Dominique Sugny

Significant molecular orientation can be achieved by time-symmetric single-cycle pulses of zero area, in the THz region. We show that in spite of the existence of a combined time-space symmetry operation, not only large peak instantaneous…

Chemical Physics · Physics 2012-10-22 Juan Ortigoso

We present a combined analytical and numerical study for coherent terahertz control of a single molecular polariton, formed by strongly coupling two rotational states of a molecule with a single-mode cavity. Compared to the bare molecules…

Quantum Physics · Physics 2023-02-08 Li-Bao Fan , Chuan-Cun Shu , Daoyi Dong , Jun He , Niels E. Henriksen , Franco Nori

Quantum tracking control aims to identify applied fields to steer the expectation values of particular observables along desired paths in time. The associated temporal fields can be identified by inverting the underlying dynamical equations…

Quantum Physics · Physics 2018-10-31 Alicia Magann , Tak-San Ho , Herschel Rabitz

We investigate the full control over the orientation of a non-symmetric molecule by using moderate and weak electric fields. Quantum Optimal Control techniques allow us to orient any axis of 6-chloropyridazine-3-carbonitrile, which is taken…

Quantum Physics · Physics 2023-11-21 Rosario González-Férez , Juan J. Omiste

We computationally demonstrate a new method for coherently controlling the rotation-axis direction in asymmetric top molecules with an optical centrifuge. Appropriately chosen electric-field strengths and the centrifuge's acceleration rate…

Chemical Physics · Physics 2021-06-16 Emil J. Zak , Andrey Yachmenev , Jochen Küpper

The extraordinary success in laser cooling, trapping, and coherent manipulation of atoms has energized the efforts in extending this exquisite control to molecules. Not only are molecules ubiquitous in nature, but the control of their…

Atomic Physics · Physics 2022-04-27 D. Mitra , K. H. Leung , T. Zelevinsky

The ability to control and exploit quantum coherence and entanglement drives research across many fields ranging from ultra-cold quantum gases to spin systems in condensed matter. Transcending different physical systems, optical approaches…

Mesoscale and Nanoscale Physics · Physics 2014-08-26 K. Müller , T. Kaldewey , R. Ripszam , J. S. Wildmann , A. Bechtold , M. Bichler , G. Koblmüller , G. Abstreiter , J. J. Finley

Considering the problem of the control of a two-state quantum system by an external field, we establish a general and versatile method that allows the derivation of smooth pulses, suitable for ultrafast applications, that feature the…

Quantum Physics · Physics 2015-06-15 D. Daems , A. Ruschhaupt , D. Sugny , S. Guerin

Precise control over rotational angular momentum is at the heart of recent advances in quantum chemistry, quantum simulation, and quantum computation with ultracold bialkali molecules. Each rotational state comprises a rich manifold of…

Atomic Physics · Physics 2025-11-11 Tom R. Hepworth , Simon L. Cornish , Philip D. Gregory

We present a theoretical framework for universal single-qutrit control in asymmetric-top molecules, advancing molecular quantum information processing. In this approach, the qutrit is encoded in three rotational eigenstates, with an…

Quantum Physics · Physics 2026-05-06 Qian-Qian Hong , Zhi-Jian Zheng , Zhe-Jun Zhang , Xin-Xia Jian , Chuan-Cun Shu
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