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Optimally-shaped electromagnetic fields have the capacity to coherently control the dynamics of quantum systems and thus offer a promising means for controlling molecular transformations relevant to chemical, biological, and materials…

Quantum Physics · Physics 2021-06-08 Alicia B. Magann , Matthew D. Grace , Herschel A. Rabitz , Mohan Sarovar

Complex control protocols and sensitivity to experimental imperfections have limited the practical implementation of quantum gate operations. Here, we present an analytical framework for universal single-qubit gates using rotational states…

Quantum Physics · Physics 2026-05-06 Qi Chen , Hao-Xuan Luo , Jin-Kang Guo , Qian-Qian Hong , Li-Bao Fan , Chuan-Cun Shu

Preparing molecules at rest and in a highly pure quantum state is a long standing dream in chemistry and physics, so far achieved only for a select set of molecules in dedicated experimental setups. Here, a quantum-limited combination of…

Quantum Physics · Physics 2015-05-30 D. Leibfried

Quantum state control is a fundamental tool for quantum technologies. In this work, we propose and analyze the use of quantum optimal control to exploit the dipolar interaction of ultracold atoms on a lattice ring, focusing on the…

Sufficient conditions for complete controllability of $N$-level quantum systems subject to a single control pulse that addresses multiple allowed transitions concurrently are established. The results are applied in particular to Morse and…

Quantum Physics · Physics 2009-11-06 S. G. Schirmer , H. Fu , A. I. Solomon

We show that quantum interference-based coherent control is a highly efficient tool for tuning ultracold molecular collision dynamics, and is free from the limitations of commonly used methods that rely on external electromagnetic fields.…

Atomic Physics · Physics 2021-04-21 Adrien Devolder , Paul Brumer , Timur V. Tscherbul

This paper describes a general method for manipulation of nuclear spins in zero magnetic field. In the absence of magnetic fields, the spins lose the individual information on chemical shifts and inequivalent spins can only be distinguished…

Laser cooling and trapping of atoms and atomic ions has led to numerous advances including the observation of exotic phases of matter, development of exquisite sensors and state-of-the-art atomic clocks. The same level of control in…

Implementing fast and high-fidelity quantum operations using open-loop quantum optimal control relies on having an accurate model of the quantum dynamics. Any deviations between this model and the complete dynamics of the device, such as…

Quantum Physics · Physics 2024-10-31 Elie Genois , Noah J. Stevenson , Noah Goss , Irfan Siddiqi , Alexandre Blais

We show that a combination of a half-cycle pulse and a short nonresonant laser pulse produces a strongly enhanced postpulse orientation. Robust transients that display both efficient and long-lived orientation are obtained. The mechanism is…

Quantum Physics · Physics 2007-05-23 D. Daems , S. Guérin , D. Sugny , H. R. Jauslin

A fundamental goal in the manipulation of quantum systems is the achievement of many coherent oscillations within the characteristic dephasing time T2*[1]. Most manipulations of electron spins in quantum dots have focused on the…

We apply two recent generalizations of monotonically convergent optimization algorithms to the control of molecular orientation by laser fields. We show how to minimize the control duration by a step-wise optimization and maximize the…

Quantum Physics · Physics 2019-02-25 M. Ndong , C. Koch , D. Sugny

Single flux quantum pulses are a natural candidate for on-chip control of superconducting qubits. We show that they can drive high-fidelity single-qubit rotations---even in leaky transmon qubits---if the pulse sequence is suitably…

Quantum Physics · Physics 2016-09-07 Per J. Liebermann , Frank K. Wilhelm

We present a theoretical study of the shaping of the time-evolution of field-free orientation of linear molecules. We show the extend to which the degree of orientation can be steered along a desired periodic time-dependent signal. The…

Quantum Physics · Physics 2019-05-15 R. Tehini , K. Hamraoui , D. Sugny

Achieving high-fidelity control of quantum systems is of fundamental importance in physics, chemistry and quantum information sciences. However, the successful implementation of a high-fidelity quantum control scheme also requires…

Quantum Physics · Physics 2018-06-05 Yu Guo , Daoyi Dong , Chuan-Cun Shu

We explore the possibility of forming a oriented polar molecule directly from a pair of colliding atoms. The process comprises the photoassociation and vibrational stabilization along with the molecular orientation. These processes are…

Quantum Physics · Physics 2026-01-14 Murilo D. Forlevesi , Edson Denis Leonel , Emanuel F. de Lima

We present a theoretical investigation of coherent control over the orientation of an individual molecule strongly coupled with a cavity using chirped-pulse driving. Specifically, we explore the dynamics of carbonyl sulfide (OCS) molecules…

Quantum Physics · Physics 2026-05-28 Li-Bao Fan , Yu Guo , Shan Ma , Chuan-Cun Shu

Accurate control of two-level systems is a longstanding problem in quantum mechanics. One such quantum system is the frequency-bin qubit: a single photon existing in superposition of two discrete frequency modes. %and a potential building…

Quantum Physics · Physics 2020-09-16 Hsuan-Hao Lu , Emma M. Simmerman , Pavel Lougovski , Andrew M. Weiner , Joseph M. Lukens

Coherent control, a central concept in physics and chemistry, has sparked significant interest due to its ability to fine-tune interference effects in atoms and individual molecules for applications ranging from light-harvesting complexes…

Quantum Physics · Physics 2026-01-07 Juan M. Scarpetta , Omar Calderón-Losada , Morten Hjorth-Jensen , John H. Reina

Supersonic beams of polar molecules are deflected using inhomogeneous electric fields. The quantum-state selectivity of the deflection is used to spatially separate molecules according to their quantum state. A detailed analysis of the…