English
Related papers

Related papers: Non-Dichroic Enantio-Sensitive Chiroptical Spectro…

200 papers

We present a comprehensive study of enantioselective orientation of chiral molecules excited by a pair of delayed cross-polarized femtosecond laser pulses. We show that by optimizing the pulses' parameters, a significant (~ 10%) degree of…

Optics · Physics 2022-07-20 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

Inspired by a sea creature, we identify a robust chiral optical force that pushes the opposite enantiomers of a chiral molecule towards regions of orthogonal linear polarization in an optical field via electric dipole interactions. Our…

We propose an enantio-detection method of chiral molecules in a cavity with external drive. The chiral molecules are coupled with a quantized cavity field and two classical light fields to form the cyclic three-level systems. The…

Quantum Physics · Physics 2022-02-15 Yu-Yuan Chen , Jian-Jian Cheng , Chong Ye , Yong Li

We propose an approach to sensitively probe the chirality of molecules by measuring their coherent optical absorption spectra. It is shown that quantum dynamics of the cyclic three-level chiral molecules driven by appropriately-designed…

Quantum Physics · Physics 2015-05-28 W. Z. Jia , L. F. Wei

The absorptive chiral metasurface shows evidence of giant nonlinear chiroptical effects, including chiral third harmonic generation, chiral saturated absorption, and chiral reverse saturable absorption. We finally demonstrate proof of…

Ultrafast imaging of molecular chirality is a key step towards the dream of imaging and interpreting electronic dynamics in complex and biologically relevant molecules. Here, we propose a new ultrafast chiral phenomenon exploiting recent…

As much as chiral metasurfaces are significant in stereochemistry and polarization control, tunable chiroptical response is important for their dynamic counterparts. A single metasurface device with invertible chiral states can selectively…

Optics · Physics 2023-06-07 Andrew S. Kim , Anjan Goswami , Mohammad Taghinejad , Wenshan Cai

We investigate high-order harmonic spectra from aligned diatomic molecules in intense driving fields whose components have orthogonal polarizations. We focus on how the driving-field ellipticity influences structural interference patterns…

X-ray circular dichroism, arising from the contrast in X-ray absorption between opposite photon helicities, serves as a spectroscopic tool to measure the magnetization of ferromagnetic materials and identify the handedness of chiral…

A light beam can carry both spin angular momentum (SAM) and orbital angular momentum (OAM). SAM is commonly evidenced by circular dichroism (CD) experiments {\em i. e.} differential absorption of left and right-handed circularly polarized…

Recently, we proposed a metasurface design for chiral sensing that (i) results in enhanced chiroptical signals by more than two orders of magnitude for ultrathin, subwavelength, chiral samples over a uniform and accessible area, (ii) allows…

Optics · Physics 2021-08-18 Sotiris Droulias , Lykourgos Bougas

Chiral circularly polarized (CP) light is central to many photonic technologies, from optical communication of spin information to novel display and imaging technologies. As such, there has been significant effort in the development of…

Materials Science · Physics 2023-07-25 Li Wan , Yizhou Liu , Matthew J. Fuchter , Binghai Yan

Locally chiral light is an emerging tool for probing and controlling molecular chirality. It can generate large and freely adjustable enantioselectivities in purely electric-dipole effects, offering its major advantages over traditional…

Optics · Physics 2023-10-19 Chong Ye , Yifan Sun , Libin Fu , Xiangdong Zhang

Directional radiation and scattering play an essential role in light manipulation for various applications in integrated nanophotonics, antenna and metasurface designs, quantum optics, etc. The most elemental system with this property is…

Classical Physics · Physics 2023-06-21 Yuqiong Cheng , Kayode Adedotun Oyesina , Bo Xue , Dangyuan Lei , Alex M. H. Wong , Shubo Wang

Chiral molecule sensing is currently performed using chromatography, electrophoresis, enzymatic-assays, mass spectrometry, and chiroptical sensing techniques. Currently polarimetry is the only method having in-vivo sensing capabilities,…

Medical Physics · Physics 2024-01-22 Swathi Padmanabhan , Jaya Prakash

We investigate how optimal control theory can be used to improve Circular Dichroism (CD) signals for A--band of fenchone measured via the photoionization yield upon further excitation. These transitions are electric dipole forbidden to…

Spin polarization in chiral molecules is a magnetic molecular response associated with electron transport and enantioselective bond polarization that occurs even in the absence of an external magnetic field. An unexpected finding by Santos…

For paraxial and non-paraxial light, numerous measures of electromagnetic attribute are expressible in terms of photon annihilation and creation. Accordingly, energy, angular momentum and chirality measures acquire a consistent…

Optics · Physics 2018-02-14 Matt M. Coles , David L. Andrews

A highly-efficient method for optical detection and separation of left- and right-handed chiral molecules is presented. The method utilizes a closed-loop three-state system in which the population dynamics depends on the phases of the three…

Quantum Physics · Physics 2019-05-08 Nikolay V. Vitanov , Michael Drewsen

Photons with spin angular momentum possess intrinsic chirality which underpins many phenomena including nonlinear optics1, quantum optics2, topological photonics3 and chiroptics4. Intrinsic chirality is weak in natural materials, and recent…