English

Giant X-ray circular dichroism in a time-reversal invariant altermagnet

Strongly Correlated Electrons 2024-12-18 v2 Materials Science

Abstract

X-ray circular dichroism, arising from the contrast in X-ray absorption between opposite photon helicities, serves as a spectroscopic tool to measure the magnetization of ferromagnetic materials and identify the handedness of chiral crystals. Antiferromagnets with crystallographic chirality typically lack X-ray magnetic circular dichroism because of time-reversal symmetry, yet exhibit weak X-ray natural circular dichroism. Here, we report the observation of giant natural circular dichroism in the Ni L3L_3-edge X-ray absorption of Ni3_3TeO6_6, a polar and chiral antiferromagnet with effective time-reversal symmetry. To unravel this intriguing phenomenon, we propose a phenomenological model that classifies the movement of photons in a chiral crystal within the same symmetry class as that of a magnetic field. The coupling of X-ray polarization with the induced magnetization yields giant X-ray natural circular dichroism, revealing the altermagnetism of Ni3_3TeO6_6. Our findings provide evidence for the interplay between magnetism and crystal chirality in natural optical activity. Additionally, we establish the first example of a new class of magnetic materials exhibiting circular dichroism with time-reversal symmetry.

Keywords

Cite

@article{arxiv.2312.07081,
  title  = {Giant X-ray circular dichroism in a time-reversal invariant altermagnet},
  author = {Jun Okamoto and Ru-Pan Wang and Yen-Yi Chu and Hung-Wei Shiu and Amol Singh and Hsiao-Yu Huang and Chung-Yu Mou and Sucitto Teh and Horng-Tay Jeng and Kai Du and Xianghan Xu and Sang-Wook Cheong and Chao-Hung Du and Chien-Te Chen and Atsushi Fujimori and Di-Jing Huang},
  journal= {arXiv preprint arXiv:2312.07081},
  year   = {2024}
}

Comments

Accepted by Advanced Materials (2024.2.16) Revised title: Giant X-ray circular dichroism in a time-reversal invariant altermagnet Revised drafts: Main 14 pages, 4 figures, and SI 20 pages, 8 figures