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Mean-field theories of the glass transition predict a phase transition to a dynamically arrested state, yet no such transition is observed in experiments or simulations of finite-dimensional systems. We resolve this long-standing…

Soft Condensed Matter · Physics 2025-12-16 Corentin C. L. Laudicina , Liesbeth M. C. Janssen , Grzegorz Szamel

To describe the slow dynamics of a system out of equilibrium, but close to a dynamical arrest, we generalize the ideas of previous work to the case where time-translational invariance is broken. We introduce a model of the dynamics that is…

Disordered Systems and Neural Networks · Physics 2016-08-31 P. De Gregorio , F. Sciortino , P. Tartaglia , E. Zaccarelli , K. A. Dawson

The standard field-theoretical procedure to study the effect of long wavelength fluctuations on a genuine second-order phase transition is applied to the Mode-Coupling-Theory (MCT) dynamical singularity at $T_c$ in the $\beta$ regime.…

Disordered Systems and Neural Networks · Physics 2013-07-17 Tommaso Rizzo

The effect of long wavelength fluctuations on the Mode-Coupling-Theory (MCT) dynamical singularity at $T_c$ in the $\beta$ regime is studied by means of the standard field-theoretical procedure for a genuine second-order phase transition.…

Disordered Systems and Neural Networks · Physics 2015-06-19 Tommaso Rizzo

Generalized mode-coupling theory (GMCT) constitutes a systematically correctable, first-principles theory to study the dynamics of supercooled liquids and the glass transition. It is a hierarchical framework that, through the incorporation…

Statistical Mechanics · Physics 2021-02-03 Chengjie Luo , Liesbeth M. C. Janssen

Mode-coupling theory (MCT) is conjectured to be a mean-field description of dynamics of the structural glass transition and the replica theory to be its thermodynamic counterpart. However, the relationship between the two theories remains…

Soft Condensed Matter · Physics 2015-05-18 Atsushi Ikeda , Kunimasa Miyazaki

The validity of mode coupling theory (MCT) is restricted by an uncontrolled factorization approximation of density correlations. The factorization can be delayed and ultimately avoided, however, by explicitly including higher order…

Statistical Mechanics · Physics 2007-05-23 Peter Mayer , Kunimasa Miyazaki , David R. Reichman

Facilitated spin models on random graphs provide an ideal microscopic realization of the mode-coupling theory of supercooled liquids: they undergo a purely dynamic glass transition with no thermodynamic singularity. In this paper we study…

Statistical Mechanics · Physics 2015-06-11 Silvio Franz , Mauro Sellitto

For over 30 years, mode-coupling theory (MCT) has been the de facto theoretic description of dense fluids and the liquid-glass transition. MCT, however, is limited by its ad hoc construction and lacks a mechanism to institute corrections.…

Soft Condensed Matter · Physics 2015-08-12 David D. McCowan

Mode coupling theory (MCT) has been successful in explaining the observed sequence of time relaxations in dense fluids. Previous expositions of this theory showing this sequence have required the existence of an ideal glass transition…

Condensed Matter · Physics 2009-10-22 Gene F. Mazenko , Joonhyun Yeo

We present mode-coupling equations for the description of the slow dynamics observed in supercooled molecular liquids close to the glass transition. The mode-coupling theory (MCT) originally formulated to study the slow relaxation in simple…

Soft Condensed Matter · Physics 2009-10-31 L. Fabbian , A. Latz , R. Schilling , F. Sciortino , P. Tartaglia , C. Theis

We extend Mode-Coupling Theory (MCT) to inhomogeneous situations, relevant for supercooled liquid in pores, close to a surface, or in an external field. We compute the response of the dynamical structure factor to a static inhomogeneous…

Statistical Mechanics · Physics 2009-11-11 Giulio Biroli , Jean-Philippe Bouchaud , Kunimasa Miyazaki , David R. Reichman

We derive the Mode Coupling Theory (MCT) of the glass transition as a Landau theory, formulated as an expansion of the exact dynamical equations in the difference between the correlation function and its plateau value. This sheds light on…

Statistical Mechanics · Physics 2015-05-13 A. Andreanov , G. Biroli , J. -P. Bouchaud

In this set of lecture notes we review the mode-coupling theory of the glass transition from several perspectives. First, we derive mode-coupling equations for the description of density fluctuations from microscopic considerations with the…

Soft Condensed Matter · Physics 2010-04-16 David R. Reichman , Patrick Charbonneau

The predictions of the mode-coupling theory of the glass transition (MCT) for the tagged-particle density-correlation functions and the mean-squared displacement curves are compared quantitatively and in detail to results from Newtonian-…

Statistical Mechanics · Physics 2009-11-10 Th. Voigtmann , A. M. Puertas , M. Fuchs

We provide extended evidence that mode-coupling theory (MCT) of supercooled liquids for the ${\mathsf F}_{12}$ schematic model admits a microscopic realization based on facilitated spin models with tunable facilitation. Depending on the…

Disordered Systems and Neural Networks · Physics 2012-08-24 Jeferson J. Arenzon , Mauro Sellitto

The mode-coupling theory of the glass transition treats the dynamics of supercooled liquids in terms of two-point density correlation functions. Here we consider a generalized, hierarchical formulation of schematic mode-coupling equations…

Statistical Mechanics · Physics 2014-11-27 Liesbeth M. C. Janssen , Peter Mayer , David R. Reichman

We present an extensive treatment of the generalized mode-coupling theory (GMCT) of the glass transition, which seeks to describe the dynamics of glass-forming liquids using only static structural information as input. This theory amounts…

Statistical Mechanics · Physics 2016-07-05 Liesbeth M. C. Janssen , Peter Mayer , David R. Reichman

Mode-coupling theory (MCT) constitutes one of the few first-principles-based approaches to describe the physics of the glass transition, but the theory's inherent approximations compromise its accuracy in the activated glassy regime. Here…

Statistical Mechanics · Physics 2021-02-03 Chengjie Luo , Liesbeth M. C. Janssen

Mode-coupling theory for uniformly sheared underdamped systems with an isothermal condition is presented. As a result of the isothermal condition, it is shown that the shear stress exhibits significant relaxation at the alpha-relaxation…

Statistical Mechanics · Physics 2013-02-27 Koshiro Suzuki , Hisao Hayakawa
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