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We present an analytical many-body formalism for systems of spherical particles carrying arbitrary free charge distributions and interacting in a polarizable electrolyte solution, that we model within the linearized Poisson--Boltzmann…

Soft Condensed Matter · Physics 2025-12-15 Sergii V. Siryk , Walter Rocchia

We present an exact many-body framework for electrostatic interactions among $N$ arbitrarily charged spheres in an electrolyte, modeled by the linearized Poisson--Boltzmann equation. Building on a spectral analysis of nonstandard…

Soft Condensed Matter · Physics 2025-12-12 Sergii V. Siryk , Walter Rocchia

We present a fully analytical integration of the Maxwell stress tensor and derive exact relations for interparticle forces in systems of multiple dielectric spheres immersed in a polarizable ionic solvent, within the framework of the…

Soft Condensed Matter · Physics 2025-12-12 Sergii V. Siryk , Walter Rocchia

This paper builds on two previous works, Lindgren et al. J. Comp. Phys. 371, 712-731 (2018) and Quan et al. arXiv:1807.05384 (2018), to devise a new method to solve the problem of calculating electrostatic interactions in a system composed…

Soft Condensed Matter · Physics 2019-02-20 Eric B. Lindgren , Chaoyu Quan , Benjamin Stamm

In this paper, we develop a general mathematical framework for analyzing electostatics within multi-layered metamaterial structures. The multi-layered structure can be designed by nesting complementary negative and regular materials…

Analysis of PDEs · Mathematics 2025-12-18 Youjun Deng , Lingzheng Kong , Zijia Peng , Liyan Zhu

We are interested in a kinetic equation intended to describe the interaction of particles with their environment. The environment is modeled by a collection of local vibrational degrees of freedom. We establish the existence of weak…

Analysis of PDEs · Mathematics 2016-03-14 Stephan De Bièvre , Arthur Vavasseur , Thierry Goudon

Equilibrium distribution of interacting ionic particles in a charged disordered background is studied using the nonlinear Poisson-Boltzmann equation. For an arbitrarily given realization of the disorder, an exact solution of the equation is…

Disordered Systems and Neural Networks · Physics 2009-11-07 Ramin Golestanian

We describe a procedure to solve an up to $2N$ problem where the particles are separated topologically in $N$ groups with at most two particles in each. Arbitrary interactions are allowed between the (two) particles within one group. All…

Quantum Physics · Physics 2015-01-30 J. R. Armstrong , A. G. Volosniev , D. V. Fedorov , A. S. Jensen , N. T. Zinner

The purpose of this paper is to investigate the spectral nature of the Neumann-Poincar\'e operator on the intersecting disks, which is a domain with the Lipschitz boundary. The complete spectral resolution of the operator is derived, which…

Analysis of PDEs · Mathematics 2015-01-14 Hyeonbae Kang , Mikyoung Lim , Sanghyeon Yu

Using Poisson-Boltzmann equation and linear response theory, we derive an effective interaction potential due to a fixed charge distribution in a solution containing polyelectrolytes and point salt. We obtain an expression for the effective…

Soft Condensed Matter · Physics 2016-01-08 Sandipan Dutta , and Y. S. Jho

In this paper we present a model based on dynamics of the electrons in the plasma using a simplified Boltzmann equation coupled with a Poisson equation. The motivation arose to simulate active plasma resonance spectroscopy which is used for…

Numerical Analysis · Mathematics 2012-01-13 Juergen Geiser , Thomas Zacher

A numerical method using implicit surface representations is proposed to solve the linearized Poisson-Boltzmann equations that arise in mathematical models for the electrostatics of molecules in solvent. The proposed method used an implicit…

Numerical Analysis · Mathematics 2018-04-04 Yimin Zhong , Kui Ren , Richard Tsai

We consider an analytic way to make the interacting N-body problem tractable by using harmonic oscillators in place of the relevant two-body interactions. The two body terms of the N-body Hamiltonian are approximated by considering the…

Quantum Gases · Physics 2012-05-16 J. R. Armstrong , N. T. Zinner , D. V. Fedorov , A. S. Jensen

In this thesis we study the lateral electrostatic interaction between a pair of non-identical, moderately charged colloidal particles trapped at an electrolyte interface in the limit of short inter-particle separations. Using a simplified…

Soft Condensed Matter · Physics 2017-10-17 Timo Schmetzer

We introduce a theorem currently proved unique by the asymptotic behaviors of eigenvalues of a compact operator. Specifically, a problem of partitions is considered and the Neumann--Poincar\'e operator is employed as the compact linear…

Spectral Theory · Mathematics 2023-05-04 Yoshihisa Miyanishi

We present a fast and accurate method to calculate the electrostatic energy and forces of interacting particles with the boundary conditions appropriate to surfaces, i.e periodic in the two directions parallel to the surface and free in the…

Computational Physics · Physics 2009-11-13 S. Alireza Ghasemi , Alexey Neelov , Stefan Goedecker

The computational study of chemical reactions in complex, wet environments is critical for applications in many fields. It is often essential to study chemical reactions in the presence of applied electrochemical potentials, taking into…

Materials Science · Physics 2016-01-20 G. Fisicaro , L. Genovese , O. Andreussi , N. Marzari , S. Goedecker

We derive a master equation for the motion of a polarizable particle weakly interacting with one or several strongly pumped cavity modes. We focus here on massive particles with complex internal structure such as large molecules and…

Quantum Physics · Physics 2010-08-04 Stefan Nimmrichter , Klemens Hammerer , Peter Asenbaum , Helmut Ritsch , Markus Arndt

In this paper a spectral-Lagrangian method for the Boltzmann equation for a multi-energy level gas is proposed. Internal energy levels are treated as separate species and inelastic collisions (leading to internal energy excitation and…

Numerical Analysis · Mathematics 2014-03-05 Alessandro Munafo , Jeffrey R. Haack , Irene M. Gamba , Thierry E. Magin

The Poisson--Boltzmann equation is widely used to model electrostatics in molecular systems. Available software packages solve it using finite difference, finite element, and boundary element methods, where the latter is attractive due to…

Computational Physics · Physics 2025-12-24 Michal Bosy , Matthew W. Scroggs , Timo Betcke , Erik Burman , Christopher D. Cooper
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