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Ge-Sn alloys with a sufficiently high concentration of Sn is a direct bandgap group IV material. Recently, ion implantation followed by pulsed laser melting has been shown to be a promising method to realize this material due to its high…

We unveil the diamondization mechanism of few-layer graphene compressed in the presence of water, providing robust evidence for the pressure-induced formation of 2D diamond. High-pressure Raman spectroscopy provides evidence of a phase…

Mg-Si-Sn solid solutions have interesting and useful semiconducting properties particularly for thermoelectric applications. While cubic solid solutions have been prepared by a variety of methods, solid solutions with a trigonal crystal…

Materials Science · Physics 2017-11-13 Pathikumar Sellappan , Anthony Y. Fong , Masayuki Murata , Yasuhiro Kodera , Javier E. Garay

The structure of the pseudo-binary mercury chalcogenide alloy HgSe0.7S0.3 has been studied by means of X-ray and neutron powder diffraction at pressures up to 8.5 GPa. A phase transition from the cubic zinc blende structure to the hexagonal…

Materials Science · Physics 2009-11-07 D. P. Kozlenko , K. Knorr , L. Ehm , S. Hull , B. N. Savenko , V. V. Shchennikov , V. I. Voronin

The orthorhombic phase of Si-doped Fe carbide is synthesized at high pressures and temperatures using laser-heated diamond anvil cell (LHDAC), followed by its characterization using X-ray diffraction (XRD) measurements, Transmission…

Materials Science · Physics 2020-11-17 Pinku Saha , Konstantin Glazyrin , Goutam Dev Mukherjee

SnxSey crystalline compounds consisting of Sn and Se atoms of varying composition are systematically investigated at pressures from 0 to 100 GPa using the first-principles evolutionary crystal structure search method based on density…

Materials Science · Physics 2017-09-25 Kien Nguyen-Cong , Joseph M. Gonzalez , Brad A. Steele , Ivan I. Oleynik

Alloy formation in ScGaN is explored using rf molecular beam epitaxy over the Sc fraction range x = 0-100%. Optical and structural analysis show separate regimes of growth, namely I) wurtzite-like but having local lattice distortions in the…

Other Condensed Matter · Physics 2009-11-10 Costel Constantin , Hamad Al-Brithen , Muhammad B. Haider , David Ingram , Arthur R. Smith

RF plasma assisted MBE growth of Scandium Nitride (ScN) thin films on GaN (0001)/SiC, AlN (0001)/Al2O3 and on 6H-SiC (0001) hexagonal substrates is found to lead to a face centered cubic (rock-salt) crystal structure with (111) out-of-plane…

Materials Science · Physics 2020-01-08 Joseph Casamento , John Wright , Reet Chaudhuri , Huili Grace Xing , Debdeep Jena

We report on the behavior of Ge-Ge, Ge-Sn, Sn-Sn like and disorder-activated vibrational modes in GeSn semiconductors investigated using Raman scattering spectroscopy. By using an excitation wavelength close to E1 gap, all modes are clearly…

Materials Science · Physics 2020-06-08 Étienne Bouthillier , Simone Assali , Jérôme Nicolas , Oussama Moutanabbir

The rich phenomena in the FeSe and related compounds have attracted great interests as it provides fertile material to gain further insight into the mechanism of high temperature superconductivity. A natural follow-up work was to look into…

Superconductivity · Physics 2021-10-04 T. L. Hung , C. H. Huang , L. Z. Deng , M. N. Ou , Y. Y. Chen , M. K. Wu , S. Y. Huyan , C. W. Chu , P. J. Chen , T. K. Lee

In this work, the optoelectronic characteristics of kesterites of the Cu2NiXS4 system (X = Si, Ge, Sn) were studied. The electronic properties of the Cu2NiXS4 (X = Si, Ge, Sn) system were studied using first-principles calculations within…

Materials Science · Physics 2026-01-07 Dilshod Nematov

The cubic $Ia\bar{3}$ (BC8) and tetragonal $P4_32_12$ (ST12) high pressure modifications of Si and Ge are attractive candidates for applications in optoelectronic, thermoelectric or plasmonic devices. Si$_x$Ge$_{1-x}$ alloys in BC8/ST12…

Materials Science · Physics 2020-08-26 Johannes Wagner , Maribel Núñez-Valdez

We report on the high-pressure synthesis of novel nano- and microcrystalline high-quality diamonds with luminescent Ge-related centers. Observation of the four-line fine structure in luminescence at 2 eV (602 nm) at temperatures below 80 K…

Selective area growth of GaN nanostructures has been performed on full 2" c-sapphire substrates using Si3N4 mask patterned by nanoimprint lithography (array of 400 nm diameter circular holes). A new process has been developed to improve the…

Nanostructured orthorhombic FeSb2 and an amorphous phase were formed by mechanical alloying starting from a mixture of high purity elemental Fe and Sb powders. The effects of high pressures on structural and optical properties were studied…

We use Raman spectroscopy in tandem with transmission electron microscopy and DFT simulations to show that extreme (GPa) pressure converts the phase of silicon nanowires from cubic (Si-I) to hexagonal (Si-IV) while preserving the nanowire's…

Materials Science · Physics 2016-11-06 Bennett E. Smith , Xuezhe Zhou , Paden B. Roder , Evan H. Abramson , Peter J. Pauzauskie

GeSn on Si has attracted much research interest due to its tunable direct bandgap for mid-infrared applications. Recently, short-range order (SRO) in GeSn alloys has been theoretically predicted, which profoundly impacts the band structure.…

We present a comprehensive study on the formation of micrometer-sized, textured hexagonal diamond silicon (hd-Si) crystals via nanoindentation followed by annealing. Utilizing advanced characterization techniques such as polarized Raman…

Silicon undergoes a phase transition from the semiconducting diamond phase to the metallic beta-Sn phase under pressure. We use quantum Monte Carlo calculations to predict the transformation pressure and compare the results to density…

Materials Science · Physics 2014-04-23 R. G. Hennig , A. Wadehra , K. P. Driver , W. D. Parker , C. J. Umrigar , J. W. Wilkins

Simple binary oxide glasses can exhibit a compression behavior distinct from that of their crystalline counterparts. In this study, we employed high-pressure X-ray absorption spectroscopy coupled to the diamond anvil cell to investigate in…