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We report a joint experimental and theoretical study of the structural, vibrational, and electronic properties of layered monoclinic arsenic sulfide (alpha-As2S3), aka mineral orpiment, under compression. X-ray diffraction and Raman…

The adsorption of lysozyme, cytochrome c and myoglobin, similar-sized globular proteins of approximately 1.5 nm radius, into the mesoporous silica material Santa Barbara Amorphous-15 (SBA-15) with 3.3 nm mean pore radius has been studied…

Soft Condensed Matter · Physics 2015-12-15 Sebastian T. Moerz , Patrick Huber

The formation of plasmons through the collective excitation of charge density has generated intense discussions, offering insights to fundamental sciences and potential applications. While the underlying physical principles have been…

The structure of the fluid carbon phase in the pressure region of the graphite, diamond, and BC8 solid phase is investigated. We find increasing coordination numbers with an increase in density. From zero to $30$ GPa, the liquid shows a…

Plasma Physics · Physics 2020-01-29 J. Vorberger , K. U. Plageman , R. Redmer

Yttrium superhydrides has attracted much attention due to their multiple stoichiometries and excellent superconductivities under high pressure. Especially, YH9 have a Tc of 243 K, which is the second highest Tc among all binary hydrides. It…

Superconductivity · Physics 2023-02-10 Mingyang Du , Zonglun Li , Defang Duan , Tian Cui

Resistivity and magnetic susceptibility measurements under external pressure were performed on single-crystals NaFe1-xCoxAs (x=0, 0.01, 0.028, 0.075, 0.109). The maximum Tc enhanced by pressure in both underdoped and optimally doped…

Superconductivity · Physics 2012-12-03 A. F. Wang , Z. J. Xiang , J. J. Ying , Y. J. Yan , P. Cheng , G. J. Ye , X. G. Luo , X. H. Chen

Pressure-sensitive adhesives (PSAs) are soft polymeric materials that exhibit complex rheological and mechanical behavior gov- erned by the interplay between polymer architecture, crosslink density, and entanglement constraints. Predicting…

Terahertz time-domain spectroscopy and differential scanning calorimetry were used to study the role of the dynamics of biomolecules decoupled from solvent effects. Lyophilised sucrose exhibited steadily increasing absorption with…

Disordered Systems and Neural Networks · Physics 2023-05-11 Johanna Kölbel , Moritz L. Anuschek , Ivonne Stelzl , Supawan Santitewagun , Wolfgang Frieß , J. Axel Zeitler

Rough diamond anvils (rough-DA) are introduced to intensify all occurring processes during an in-situ study of heterogeneous compression of strongly pre-deformed Zr in diamond anvil cell (DAC). Crystallite size and dislocation density of Zr…

Materials Science · Physics 2023-05-26 Feng Lin , Valery Levitas , Krishan Pandey , Sorb Yesudhas , Changyong Park

This paper summarizes 0 GPa to 0.6 GPa neutron diffraction measurements of a nickel hexacyanochromate coordination polymer (NiCrPB) that has the face-centered cubic, Prussian blue structure. Deuterated powders of NiCrPB contain ~100 nm…

Materials Science · Physics 2015-06-23 D. M. Pajerowski , S. E. Conklin , J. B. Leão , D. Phelan , L. W. Harriger

A quantitative understanding of aggregation mechanisms leading to the formation of inorganic nanoparticles (NPs) and protein composites in aqueous media is of paramount interest for colloid chemistry. In particular, the interactions between…

We report the interplay between In incorporation and strain relaxation kinetics in high-In-content InxGa1-xN (x = 0.3) layers grown by plasma-assisted molecular-beam epitaxy. For In mole fractions x = 0.13-0.48, best structural and…

Quantum molecular dynamic simulations are introduced to study the shock compressed oxygen. The principal Hugoniot points derived from the equation of state agree well with the available experimental data. With the increase of pressure,…

Materials Science · Physics 2015-05-14 Cong Wang , Ping Zhang

Optical and synchrotron x-ray diffraction diamond anvil cell experiments have been combined with first principles theoretical structure predictions to investigate mixed N2 and H2 up to 55 GPa. We found the formation of oligomeric NxH (x>1)…

AC susceptibility measurements have been carried out on superconducting LaO1-xFxFeAs for x=0.07 and 0.14 under He-gas pressures to about 0.8 GPa. Not only do the measured values of dTc/dP differ substantially from those obtained in previous…

Superconductivity · Physics 2015-05-14 W. Bi , H. B. Banks , J. S. Schilling , H. Takahashi , H. Okada , Y. Kamihara , M. Hirano , H. Hosono

In this article, we discuss metal-protein interactions in the Ag-lysozyme complex by spectroscopic measurements. The analysis of the variation in relative intensities of SERS bands reveal the orientation and the change in conformation of…

Biological Physics · Physics 2016-09-08 Goutam Chandra , Kalyan S. Ghosh , Swagata Dasgupta , Anushree Roy

We report relaxation dynamics of glycerol-water mixtures as probed by megahertz-to-terahertz dielectric spectroscopy in a frequency range from 50 MHz to 0.5 THz at room temperature. The dielectric relaxation spectra reveal several…

Chemical Physics · Physics 2019-09-04 Ali Charkhesht , Djamila Lou , Ben Sindle , Chengyuan Wen , Shengfeng Cheng , Nguyen Q. Vinh

X-ray Photon Correlation Spectroscopy (XPCS) enables direct access to atomic-scale dynamics in disordered materials, revealing both spontaneous and X-ray-induced relaxation processes. Here, we study two compositionally similar alloy glasses…

We report here the evidences of hydrogen bond symmetrization in the simplest amino acid- carboxylic acid complex, glycinium oxalate, at moderate pressures of 8 GPa using in-situ infrared and Raman spectroscopic investigations combined with…

Liquid-liquid phase separation (LLPS) of protein solutions is governed by highly complex protein-protein interactions. Nevertheless, it has been suggested that based on the extended law of corresponding states (ELCS), as proposed for…

Soft Condensed Matter · Physics 2023-02-08 Jan Hansen , Stefan U. Egelhaaf , Florian Platten