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Related papers: Phase Transitions as Emergent Geometric Phenomena:…

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While classical theory of phase transitions deals with systems where shape variation is energetically neutral, the account of rigidity can lead to the emergence of new thermodynamic features. One of them is a special type of critical points…

Materials Science · Physics 2024-04-18 Yury Grabovsky , Lev Truskinovsky

We develop a geometric theory of phase transitions (PTs) for Hamiltonian systems in the microcanonical ensemble. This theory allows to reformulate Bachmann's classification of PTs for finite-size systems in terms of geometric properties of…

Statistical Mechanics · Physics 2022-06-29 Loris Di Cairano

We discuss here the use of generalized forms of entropy, taken as information measures, to characterize phase transitions and critical behavior in thermodynamic systems. Our study is based on geometric considerations pertaining to the space…

Statistical Mechanics · Physics 2009-04-14 M. Portesi , F. Pennini , A. Plastino

The relation between thermodynamic phase transitions in classical systems and topological changes in their configuration space is discussed for two physical models and contains the first exact analytic computation of a topologic invariant…

Statistical Mechanics · Physics 2007-05-23 Lapo Casetti , Marco Pettini , E. G. D. Cohen

The topological theory of phase transitions has its strong point in two theorems proving that, for a wide class of physical systems, phase transitions necessarily stem from topological changes of some submanifolds of configuration space. It…

Statistical Mechanics · Physics 2016-02-04 Matteo Gori , Roberto Franzosi , Marco Pettini

The deep problems caused from the limitations of theoretical framework itself can only be clarified by extending and reconstructing of the theoretical framework, we extend classical theoretical framework of thermodynamics, break through the…

Chemical Physics · Physics 2025-01-17 Tang Suye

It has been shown that contact geometry is the proper framework underlying classical thermodynamics and that thermodynamic fluctuations are captured by an additional metric structure related to Fisher's Information Matrix. In this work we…

Mathematical Physics · Physics 2015-08-27 A. Bravetti , C. S. Lopez-Monsalvo , F. Nettel

The Hamiltonian dynamics associated to classical, planar, Heisenberg XY models is investigated for two- and three-dimensional lattices. Besides the conventional signatures of phase transitions, here obtained through time averages of…

Statistical Mechanics · Physics 2009-10-31 M. Cerruti-Sola , C. Clementi , M. Pettini

A new point of view about the deep origin of thermodynamic phase transitions is sketched. The main idea is to link the appearance of phase transitions to some major topology change of suitable submanifolds of phase space instead of linking…

Statistical Mechanics · Physics 2017-08-23 Marco Pettini , Roberto Franzosi , Lionel Spinelli

The thermodynamics and topology of mean-field models with 2+k body interaction terms (generalizing XY model) are derived. Focusing on two particular cases (2+4 and 2+6 body interaction terms), a comparison between thermodynamic (phase…

Statistical Mechanics · Physics 2009-11-13 L. Angelani , G. Ruocco

Certain geometric properties of submanifolds of configuration space are numerically investigated for classical lattice phi^4 models in one and two dimensions. Peculiar behaviors of the computed geometric quantities are found only in the…

Statistical Mechanics · Physics 2009-10-31 Roberto Franzosi , Lapo Casetti , Lionel Spinelli , Marco Pettini

Based on the study of saddle points of the potential energy landscapes of generic classical many-particle systems, we present a necessary criterion for the occurrence of a thermodynamic phase transition. Remarkably, this criterion imposes…

Statistical Mechanics · Physics 2008-04-25 Michael Kastner , Oliver Schnetz

Thermodynamic conventions suffer from describing dynamical distinctions, especially when the structural and energetic changes induced by localized rare events are insignificant. By using the ensemble theory in the trajectory space, we…

Statistical Mechanics · Physics 2023-03-30 Qi-Jun Ye , Xin-Zheng Li

Equilibrium phase transitions may be defined as nonanalytic points of thermodynamic functions, e.g., of the canonical free energy. Given a certain physical system, it is of interest to understand which properties of the system account for…

Statistical Mechanics · Physics 2008-01-08 Michael Kastner

Thermal behavior in subsystems of closed quantum systems is commonly attributed to dynamical chaos, quantum ergodicity, canonical typicality, or the eigenstate thermalization hypothesis, suggesting a fundamentally statistical origin of…

Quantum Physics · Physics 2026-04-13 Uttam Singh , Nicolas J. Cerf

Distinct from the dynamical phase, in a cyclic evolution, a system's state may acquire an additional component, a.k.a. geometric phase. The latter is a manifestation of a closed path in state space. Geometric phases underlie various…

We assume that markovian dynamics on a finite graph enjoys a gauge symmetry under local scalings of the probability density, derive the transformation law for the transition rates and interpret the thermodynamic force as a gauge potential.…

Statistical Mechanics · Physics 2015-05-30 Matteo Polettini

Considering a nonlinear charged black hole as a thermodynamics system, we study the geometric description of its phase transitions. Using the formalism of geometrothermodynamics we show that the geometry of the space of thermodynamic…

Mathematical Physics · Physics 2014-04-28 Gustavo Arciniega , Alberto Sánchez

Given the evolution of an arbitrary open quantum system, we formulate a general and unambiguous method to separate the internal energy change of the system into an entropy-related contribution and a part causing no entropy change,…

Quantum Physics · Physics 2022-10-26 S. Alipour , A. T. Rezakhani , A. Chenu , A. del Campo , T. Ala-Nissila

We present the formalism of phenomenological thermodynamics in terms of the even-dimensional symplectic geometry, and argue that it catches its geometric essence in a more profound and clearer way than the popular odd-dimensional contact…

Mathematical Physics · Physics 2018-07-25 Jerzy Kocik