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We present here a study of the magnetic properties of the antiferromagnetic dimer material CuVOF$_4$(H$_2$O)$_6\cdot$H$_2$O, in which the dimer unit is composed of two different $S = 1/2$ species, Cu(II) and V(IV). An applied magnetic field…

We investigate magnetic properties of the $s$ = 1/2 compound K$_{2}$Cu$_{3}$(MoO$_{4}$)$_{4}$ by combining magnetic susceptibility, magnetization, specific heat, and electron spin resonance (ESR) with density functional calculations. Its…

We present the synthesis and a detailed investigation of structural and magnetic properties of metal-organic compound Cu$_2$(IPA)$_2$(DMF)(H$_2$O) by means of x-ray diffraction, magnetization, and heat capacity measurements. Single crystals…

Materials Science · Physics 2017-06-07 S. Thamban , U. Arjun , M. Padmanabhan , R. Nath

The magnetic phase diagram and the thermodynamic properties of a square lattice containing antiferromagnetically coupled spin-1/2 triangles are studied. A Heisenberg Hamiltonian with three strong intra-triangle exchange coupling constants…

Strongly Correlated Electrons · Physics 2009-10-31 Stefan Wessel , Stephan Haas

We calculate the static and dynamic properties of single crystal, single molecule magnets consisting of equal spin $S=1/2$ or 5/2 dimers. The spins in each dimer interact with each other via the Heisenberg exchange interaction and with the…

Statistical Mechanics · Physics 2009-11-07 Dmitri V. Efremov , Richard A. Klemm

We present a multi-frequency Electron Spin Resonance (ESR) study in the range of 4 GHz to 420 GHz of the quasi-one-dimensional, non-dimerized, quarter-filled Mott insulators, delta-(EDT-TTF-CONMe_2)_2X (X=AsF_6, Br). In the high temperature…

Strongly Correlated Electrons · Physics 2010-07-15 Bálint Náfrádi , Areta Olariu , László Forró , Cécile Mézière , Patrick Batail , András Jánossy

We report on a comprehensive characterization of the newly synthesized Cu$^{2+}$-based molecular magnet [Cu(pz)$_2$(2-HOpy)$_2$](PF$_6$)$_2$ (CuPOF), where pz = C$_4$H$_4$N$_2$ and 2-HOpy = C$_5$H$_4$NHO. From a comparison of theoretical…

Magnetization and specific heat measurements have been carried out on Cs$_2$Cu$_3$ZrF$_{12}$ and Cs$_2$Cu$_3$HfF$_{12}$ single crystals, in which Cu$^{2+}$ ions with spin-1/2 form a regular Kagom\'{e} lattice. The antiferromagnetic exchange…

Strongly Correlated Electrons · Physics 2015-06-25 Y. Yamabe , T. Ono , T. Suto , H. Tanaka

We use a hydrodynamic approach to investigate dynamic spin susceptibility of the antiferromagnetic spin-$1/2$ Heisenberg chain with a uniform Dzyaloshinskii-Moriya (DM) interaction in the presence of an external magnetic field. We find that…

Strongly Correlated Electrons · Physics 2022-06-06 Ren-Bo Wang , Anna Keselman , Oleg A. Starykh

We report on magnetization and electron spin resonance (ESR) measurements of Sr$_{2}$VO$_4$ with orthorhombic symmetry. In this dimer system the $V^{4+}$ ions are in tetrahedral environment and are coupled by an antiferromagnetic…

We present a numerical study of the spin-1/2 bilayer Heisenberg antiferromagnet with random interlayer dimer dilution. From the temperature dependence of the uniform susceptibility and a scaling analysis of the spin correlation length we…

Disordered Systems and Neural Networks · Physics 2009-11-07 O. P. Vajk , M. Greven

We have studied the spin and exchange coupling of Ti atoms on a Cu$_2$N/Cu(100) surface using density functional theory. We find that individual Ti have a spin of 1.0 (i.e., 2 Bohr Magneton) on the Cu$_2$N/Cu(100) surface instead of…

Materials Science · Physics 2013-05-29 Raghani Pushpa , Jesus Cruz , Barbara Jones

We discuss the ground state of the spin-orbital model for spin-one ions with partially filled $t_{2g}$ levels on a honeycomb lattice. We find that the orbital degrees of freedom induce a spontaneous dimerization of spins and drive them into…

Strongly Correlated Electrons · Physics 2008-04-12 G. Jackeli , D. I. Khomskii

High-field magnetization of the spin-$1/2$ antiferromagnet $\alpha$-Cu$_2$V$_2$O$_7$ was measured in pulsed magnetic fields of up to 56 T in order to study its magnetic phase diagram. When the field was applied along the easy axis (the…

Strongly Correlated Electrons · Physics 2017-06-21 G. Gitgeatpong , M. Suewattana , Shiwei Zhang , A. Miyake , P. Chanlert , N. Kurita , H. Tanaka , T. J. Sato , Y. Zhao , K. Matan

We report on high-field magnetization, specific-heat and electron spin resonance (ESR) studies of the quasi-two-dimensional spin-1/2 Heisenberg antiferromagnet [Cu(pyz)2(HF2)]PF6. The frequency-field diagram of ESR modes below TN = 4.38 K…

Strongly Correlated Electrons · Physics 2011-03-10 E. Cizmar , S. A. Zvyagin , R. Beyer , M. Uhlarz , M. Ozerov , Y. Skourski , J. L. Manson , J. A. Schlueter , J. Wosnitza

Spin-1/2 compounds A3Cu3AlO2(SO4)4 (A=K, Rb, and Cs) have one-dimensional (1D) inequilateral diamond chains. We analyze the temperature dependence of the magnetic susceptibility and determine the magnetic exchange interactions. In contrast…

We measured the temperature dependence of the magnetic susceptibility and specific heat and the magnetic-field dependence of the magnetization of CuInVO$_5$. An antiferromagnetically ordered state appears below $T_{\rm N} = 2.7$ K. We…

Strongly Correlated Electrons · Physics 2016-12-21 Masashi Hase , Masashige Matsumoto , Akira Matsuo , Koichi Kindo

Sr$_{3}$Cr$_{2}$O$_{8}$ consist of a lattice of spin-1/2 Cr$^{5+}$ ions, which form hexagonal bilayers and which are paired into dimers by the dominant antiferromagnetic intrabilayer coupling. The dimers are coupled three-dimensionally by…

We report a combined experimental and theoretical study of the spin S=1/2 nanomagnet Cu5(OH)2(NIPA)4*10H2O (Cu5-NIPA). Using thermodynamic, electron spin resonance and 1H nuclear magnetic resonance measurements on one hand, and ab initio…

We report structural and magnetic properties of the spin-$\frac12$ quantum antiferromagnet Cu[C$_6$H$_2$(COO)$_4$][C$_2$H$_5$NH$_3$]$_2$ by means of single-crystal x-ray diffraction, magnetization, heat capacity, and electron spin resonance…

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