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We construct a novel approach, based on thermodynamic geometry, to characterize first-order phase transitions from a microscopic perspective, through the scalar curvature in the equilibrium thermodynamic state space. Our method resolves key…

Statistical Mechanics · Physics 2013-05-30 George Ruppeiner , Anurag Sahay , Tapobrata Sarkar , Gautam Sengupta

A fundamental result of thermodynamic geometry is that the optimal, minimal-work protocol that drives a nonequilibrium system between two thermodynamic states in the slow-driving limit is given by a geodesic of the friction tensor, a…

Statistical Mechanics · Physics 2024-10-24 Adrianne Zhong , Michael R. DeWeese

We characterize finite-time thermodynamic processes of multidimensional quadratic overdamped systems. Analytic expressions are provided for heat, work, and dissipation for any evolution of the system covariance matrix. The Bures-Wasserstein…

Statistical Mechanics · Physics 2022-11-28 Paolo Abiuso , Viktor Holubec , Janet Anders , Zhuolin Ye , Federico Cerisola , Martí Perarnau-Llobet

A fundamental problem in modern thermodynamics is how a molecular-scale machine performs useful work, while operating away from thermal equilibrium without excessive dissipation. To this end, we derive a friction tensor that induces a…

Statistical Mechanics · Physics 2012-05-09 David A. Sivak , Gavin E. Crooks

By combining different ideas, a general and efficient protocol to deal with discontinuous phase transitions at low temperatures is proposed. For small $T$'s, it is possible to derive a generic analytic expression for appropriate order…

Statistical Mechanics · Physics 2015-06-03 C. E. Fiore , M. G. E. da Luz

We study information geometry of the thermodynamics of first and second order phase transitions, and beyond criticality, in magnetic and liquid systems. We establish a universal microscopic characterization of such phase transitions via the…

Statistical Mechanics · Physics 2011-11-30 Anshuman Dey , Pratim Roy , Tapobrata Sarkar

Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We…

Quantum Physics · Physics 2021-08-31 Paolo Abiuso , Harry J. D. Miller , Martí Perarnau-Llobet , Matteo Scandi

A model in statistical mechanics, characterised by the corresponding Gibbs measure, is a subset of the totality of probability distributions on the phase space. The shape of this subset, i.e., the geometry, then plays an important role in…

Condensed Matter · Physics 2007-05-23 D. C. Brody , A. Ritz

Constructing optimal thermodynamic processes in quantum systems relies on managing the balance between the average excess work and its stochastic fluctuations. Recently it has been shown that two different quantum generalisations of…

Quantum Physics · Physics 2021-12-06 Mohammad Mehboudi , Harry J. D. Miller

We study geodesics on the parameter manifold, for systems exhibiting second order classical and quantum phase transitions. The coupled non-linear geodesic equations are solved numerically for a variety of models which show such phase…

Statistical Mechanics · Physics 2015-06-11 Prashant Kumar , Subhash Mahapatra , Prabwal Phukon , Tapobrata Sarkar

In this work we explore the use of thermodynamic length to improve the performance of experimental protocols. In particular, we implement Landauer erasure on a driven electron level in a semiconductor quantum dot, and compare the standard…

Mesoscale and Nanoscale Physics · Physics 2023-02-03 Matteo Scandi , David Barker , Sebastian Lehmann , Kimberly A. Dick , Ville F. Maisi , Martí Perarnau-Llobet

We elucidate the geometry of quantum adiabatic evolution. By minimizing the deviation from adiabaticity we find a Riemannian metric tensor underlying adiabatic evolution. Equipped with this tensor, we identify a unified geometric…

Quantum Physics · Physics 2010-10-28 Ali T. Rezakhani , Damian F. Abasto , Daniel A. Lidar , Paolo Zanardi

Shortcut schemes can accelerate quasi-static processes in passive systems by adding auxiliary controls to realize swift transitions between equilibrium states. In active systems, however, inherently directed motion driven by free energy…

Statistical Mechanics · Physics 2026-04-08 Guodong Cheng , Z. C. Tu , Geng Li

A deeper understanding of nonequilibrium phenomena is needed to reveal the principles governing natural and synthetic molecular machines. Recent work has shown that when a thermodynamic system is driven from equilibrium then, in the linear…

Statistical Mechanics · Physics 2012-10-30 Patrick R. Zulkowski , David A. Sivak , Gavin E. Crooks , Michael R. DeWeese

In addition to the Riemannian metricization of the thermodynamic state space, local relaxation times offer a natural time scale, too. Generalizing existing proposals, we relate {\it thermodynamic} time scale to the standard kinetic…

Condensed Matter · Physics 2008-02-03 L. Diosi , K. Kulacsy , B. Lukacs , A. Rácz

Geometrical approach to the phenomenological theory of phase transitions of the second kind at constant pressure $P$ and variable temperature $T$ is proposed. Equilibrium states of a system at zero external field and fixed $P$ and $T$ are…

Condensed Matter · Physics 2019-08-17 A. K. Kanyuka , V. S. Glukhov

We show that energy dissipation in slowly-driven, Markovian quantum systems at low temperature is linked to the geometry of the driving protocol through the quantum (or Fubini-Study) metric. Utilizing these findings, we establish lower…

Quantum Physics · Physics 2025-03-21 Iliya Esin , Étienne Lantagne-Hurtubise , Frederik Nathan , Gil Refael

Using the formalism of geometrothermodynamics, we investigate the geometric properties of the equilibrium manifold for diverse thermodynamic systems. Starting from Legendre invariant metrics of the phase manifold, we derive thermodynamic…

General Relativity and Quantum Cosmology · Physics 2011-03-28 H. Quevedo , A. Sanchez , S. Taj , A. Vazquez

We perform a microcanonical study of classical lattice phi^4 field models in 3 dimensions with O(n) symmetries. The Hamiltonian flows associated to these systems that undergo a second order phase transition in the thermodynamic limit are…

High Energy Physics - Theory · Physics 2011-07-19 Lando Caiani , Lapo Casetti , Cecilia Clementi , Giulio Pettini , Marco Pettini , Raoul Gatto

Accelerating controlled thermodynamic processes requires an auxiliary Hamiltonian to steer the system into instantaneous equilibrium states. An extra energy cost is inevitably needed in such finite-time operation. We recently develop a…

Statistical Mechanics · Physics 2023-01-18 Geng Li , C. P. Sun , Hui Dong
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