English

Beyond Linear Response: Equivalence between Thermodynamic Geometry and Optimal Transport

Statistical Mechanics 2024-10-24 v4

Abstract

A fundamental result of thermodynamic geometry is that the optimal, minimal-work protocol that drives a nonequilibrium system between two thermodynamic states in the slow-driving limit is given by a geodesic of the friction tensor, a Riemannian metric defined on control space. For overdamped dynamics in arbitrary dimensions, we demonstrate that thermodynamic geometry is equivalent to L2L^2 optimal transport geometry defined on the space of equilibrium distributions corresponding to the control parameters. We show that obtaining optimal protocols past the slow-driving or linear response regime is computationally tractable as the sum of a friction tensor geodesic and a counterdiabatic term related to the Fisher information metric. These geodesic-counterdiabatic optimal protocols are exact for parameteric harmonic potentials, reproduce the surprising non-monotonic behavior recently discovered in linearly-biased double well optimal protocols, and explain the ubiquitous discontinuous jumps observed at the beginning and end times.

Keywords

Cite

@article{arxiv.2404.01286,
  title  = {Beyond Linear Response: Equivalence between Thermodynamic Geometry and Optimal Transport},
  author = {Adrianne Zhong and Michael R. DeWeese},
  journal= {arXiv preprint arXiv:2404.01286},
  year   = {2024}
}

Comments

Main text made more concise, two SM sections moved to Appendices. Main text has 8 pages, 2 figures; supplementary material has 6 pages, 2 figures. (PDF in v3 did not render.)

R2 v1 2026-06-28T15:40:32.658Z