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The most rigorous physical description of non-equilibrium gas dynamics is rooted in the numerical solution of the Boltzmann equation. Yet, the large number of degrees of freedom and the wide range of both spatial and temporal scales render…

Computational Physics · Physics 2024-10-25 Anthony Chang , Narendra Singh , Marco Panesi

Ordinary Boltzmann-Gibbs entropy is inadequate to be used in systems depending on a control parameter that yield different mean energy values. Such systems fail to give the correct comparison between the off-equilibrium and equilibrium…

Statistical Mechanics · Physics 2007-05-23 G. B. Bagci

We study the time evolution of the Boltzmann entropy of a microstate during the non-equilibrium free expansion of a one-dimensional quantum ideal gas. This quantum Boltzmann entropy, $S_B$, essentially counts the "number" of independent…

Small systems consisting of a few particles are increasingly technologically relevant. In such systems, an intense debate in microcanonical statistical mechanics has been about the correctness of Boltzmann's surface entropy versus Gibbs'…

Statistical Mechanics · Physics 2024-09-20 Ananth Govind Rajan

The standard Large Deviation Theory (LDT) mirrors the Boltzmann-Gibbs (BG) factor which describes the thermal equilibrium of short-range Hamiltonian systems, the velocity distribution of which is Maxwellian. It is generically applicable to…

General Physics · Physics 2022-02-03 Ugur Tirnakli , Mauricio Marques , Constantino Tsallis

The Stefan-Boltzmann (SB) law relates the emissivity $q$, given in $Wm^{-2}$, of an ideal black-body cavity at thermal equilibrium to the fourth power of the absolute temperature $T$ as $q=\sigma T^4$, with $\sigma = 5.67 \times 10^{-8} \ W…

Statistical Mechanics · Physics 2022-05-30 Lino Reggiani , Eleonora Alfinito

In 1988, Constantino Tsallis proposed an extension of the Boltzmann statistical mechanics by postulating a new entropy formula, $S_q = k_B\ln_q W$, where $W$ is the number of microstates accessible to the system, and $\ln_q$ defines a…

Statistical Mechanics · Physics 2025-03-03 J. A. S. Lima , M. H. Benetti

Clausius introduced, in the 1860s, a thermodynamical quantity which he named {\it entropy} $S$. This thermodynamically crucial quantity was proposed to be {\it extensive}, i.e., in contemporary terms, $S(N) \propto N$ in the thermodynamic…

Statistical Mechanics · Physics 2011-06-21 Constantino Tsallis

The probability distribution function for thermodynamics and econophysics is obtained by solving an equilibrium equation. This approach is different from the common one of optimizing the entropy of the system or obtaining the state of…

General Physics · Physics 2007-05-23 Diego Saa

The Boltzmann--Gibbs entropy is a functional on the space of probability measures. When a state space is countable, one characterization of the Boltzmann--Gibbs entropy is given by the Shannon--Khinchin axioms, which consist of continuity,…

Mathematical Physics · Physics 2021-11-03 Asuka Takatsu

It has recurrently been proposed that the Boltzmann textbook definition of entropy $S(E)=k\ln \Omega (E)$ in terms of the number of microstates $\Omega (E)$ with energy $E$ should be replaced by the expression $S_G(E)=k\ln \sum_{E^\prime…

Statistical Mechanics · Physics 2014-06-12 Jose M. G. Vilar , J. Miguel Rubi

The paper deals with the generalization of both Boltzmann entropy and distribution in the light of most-probable interpretation of statistical equilibrium. The statistical analysis of the generalized entropy and distribution leads to some…

Quantum Physics · Physics 2009-11-13 C. G. Chakrabarti , Indranil Chakrabarty

The foundations of the Boltzmann-Gibbs (BG) distributions for describing equilibrium statistical mechanics of systems are examined. Broadly, they fall into: (i) probabilistic paaroaches based on the principle of equal a priori probability…

Statistical Mechanics · Physics 2009-11-10 A. K. Rajagopal , Sumiyoshi Abe

In the works on Statistical Mechanics and Statistical Physics, when deriving the distribution of particles of ideal gases, one uses the method of Lagrange multipliers in a formal way. In this paper we treat rigorously this problem for…

Mathematical Physics · Physics 2016-01-12 Constantin Zalinescu

To characterize strongly interacting statistical systems within a thermodynamical framework - complex systems in particular - it might be necessary to introduce generalized entropies, $S_g$. A series of such entropies have been proposed in…

Classical Physics · Physics 2010-07-05 Rudolf Hanel , Stefan Thurner

Conjecture II.3.6 of Spohn in [Spohn '91] and Lecture 7 of Jensen-Yau in [Jensen-Yau '99] ask for a general derivation of universal fluctuations of hydrodynamic limits in large-scale stochastic interacting particle systems. However, the…

Probability · Mathematics 2023-03-21 Kevin Yang

Systems with long-range interactions display a short-time relaxation towards Quasi Stationary States (QSS) whose lifetime increases with the system size. In the paradigmatic Hamiltonian Mean-field Model (HMF) out-of-equilibrium phase…

Statistical Mechanics · Physics 2016-02-15 Gabriele Martelloni , Gianluca Martelloni , Pierre de Buyl , Duccio Fanelli

We consider a system composed of a fixed number of particles with total energy smaller or equal to some prescribed value. The particles are non-interacting, indistinguishable and distributed over fixed number of energy levels. The energy…

Probability · Mathematics 2021-03-23 Tomasz M. Łapiński

The theory of large deviations constitutes a mathematical cornerstone in the foundations of Boltzmann-Gibbs statistical mechanics, based on the additive entropy $S_{BG}=- k_B\sum_{i=1}^W p_i \ln p_i$. Its optimization under appropriate…

Statistical Mechanics · Physics 2011-10-31 Guiomar Ruiz , Constantino Tsallis

The present paper studies a large class of temperature dependent probability distributions and shows that entropy and energy can be defined in such a way that these probability distributions are the equilibrium states of a generalized…

Statistical Mechanics · Physics 2015-06-24 Jan Naudts