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Advancing the functional performance of bismuth ferrite (BiFeO$_3$) requires precise control over phase stability and microstructure, challenges often complicated by secondary phase formation within the Bi$_2$O$_3$-Fe$_2$O$_3$ system. In…

Materials Science · Physics 2025-11-27 Subir Majumder , Paul Ben Ishai , Gilad Orr

Proximity effects allow for the adjustment of magnetic properties in a physically elegant way. If two thin ferromagnetic (FM) films are brought into contact, electronic coupling alters their magnetic exchange interaction at their interface.…

We review recent results on the properties of materials with correlated electrons obtained within the LDA+DMFT approach, a combination of a conventional band structure approach based on the local density approximation (LDA) and the…

Strongly Correlated Electrons · Physics 2015-03-13 J. Kunes , I. Leonov , M. Kollar , K. Byczuk , V. I. Anisimov , D. Vollhardt

Effects of Coulomb correlation on LaOFeAs electronic structure have been investigated by LDA+DMFT(QMC) method. The calculation results show that LaOFeAs is in the regime of intermediate correlation strength with significant part of the…

Strongly Correlated Electrons · Physics 2009-11-13 A. O. Shorikov , M. A. Korotin , S. V. Streltsov , S. L. Skornyakov , D. M. Korotin , V. I. Anisimov

The formalism of electronic density-functional-theory, with Hubbard-U corrections (DFT+U), is employed in a computational study of the energetics of U_{1-x} Ce_x O_2 mixtures. The computational approach makes use of a procedure which…

Materials Science · Physics 2012-03-08 B. E. Hanken , C. R. Stanek , N. Grønbech-Jensen , M. Asta

We present a joint theoretical and experimental study of the oxygen $K$-edge spectra for LaFeO$_3$ and homovalent Ni-substituted LaFeO$_3$ (LaFe$_{0.75}$Ni$_{0.25}$O$_3$), using first-principles simulations based on density-functional…

UCd$_{11}$ is an antiferromagnetic uranium intermetallic compound ($T_{\rm N}$ = 5.3K) with enhanced electron mass and uranium-uranium spacings nearly twice the Hill limit, suggesting a weakly hybridized 5$f$ electronic character. Various…

Heterostructures are ubiquitous in many optoelectronic devices and as photocatalysts. One of the key features of a heterojunction is the proper band alignment between the two materials. Estimation of the correct relative band positions with…

Mesoscale and Nanoscale Physics · Physics 2024-08-13 Raheel Hammad , Snehith Adabala , Soumya Ghosh

The Fe$_{n}$GeTe$_{2}$ systems are newly discovered two-dimensional van-der-Waals materials, exhibiting magnetism at room temperature. The sub-systems belonging to Fe$_{n}$GeTe$_{2}$ class are special because they show site-dependent…

Materials Science · Physics 2022-12-19 Sukanya Ghosh , Soheil Ershadrad , Vladislav Borisov , Biplab Sanyal

The effective on-site Coulomb interaction (Hubbard $U$) between 5$f$ electrons in actinide metals (Th-Cf) is calculated with the framework of density-functional theory (DFT) using linear response approach. The $U$ values seldom rely on the…

Materials Science · Physics 2020-01-14 Ruizhi Qiu , Bingyun Ao , Li Huang

Transition-metal compounds pose serious challenges to first-principles calculations based on density-functional theory (DFT), due to the inability of most approximate exchange-correlation functionals to capture the localization of valence…

Materials Science · Physics 2019-03-13 Matteo Cococcioni , Nicola Marzari

We present an efficient method for incorporating the dynamical effects of the screening of the Hubbard U by electronic degrees of freedom in the solid into the single site dynamical mean field approximation. The formalism is illustrated by…

Strongly Correlated Electrons · Physics 2010-04-08 Philipp Werner , Andrew J. Millis

The dynamical mean-field theory (DMFT) combined with the fluctuation exchange (FLEX) method, namely FLEX+DMFT, is an approach for correlated electron systems to incorporate both local and non-local long-range correlations in a…

Superconductivity · Physics 2015-08-20 Motoharu Kitatani , Naoto Tsuji , Hideo Aoki

We present results of an {\it ab initio} density functional theory study of three bismuth-based multiferroics, BiFeO$_{3}$, Bi$_{2}$FeCrO$_{6}$, and BiCrO$_{3}$. We disuss differences in the crystal and electronic structure of the three…

Materials Science · Physics 2007-05-23 Pio Baettig , Claude Ederer , Nicola A. Spaldin

Iron-based superconductors offer an ideal platform for studying topological superconductivity and Majorana fermions. In this paper, we carry out a comprehensive study of the band topology and topological surface states of a number of…

Superconductivity · Physics 2022-09-13 Xiaobo Ma , Guangwei Wang , Rui Liu , Tianye Yu , Yiran Peng , Pengyu Zheng , Zhiping Yin

Typical density-functional theory calculations that wrongly predict undoped cuprates to be metallic also predict Cu-O half- and full-breathing phonon energies that are significantly softer than observed, presumably because of weak on-site…

Strongly Correlated Electrons · Physics 2021-11-03 Tyler C. Sterling , Dmitry Reznik

Materials with correlated electrons often respond very strongly to external or internal influences, leading to instabilities and states of matter with broken symmetry. This behavior can be studied theoretically either by evaluating the…

Strongly Correlated Electrons · Physics 2017-08-15 J. Kunes , I. Leonov , P. Augustinsky , V. Krapek , M. Kollar , D. Vollhardt

First-principles Hubbard-corrected approximate density-functional theory (DFT+U) is a low-cost, potentially high throughput method of simulating materials, but it has been hampered by empiricism and inconsistent band-gap correction in…

Materials Science · Physics 2025-06-16 Daniel S. Lambert , David D. O'Regan

We have synthesized Gd$_{2}$FeCrO$_{6}$ (GFCO) double perovskite which is crystallized in a monoclinic structure with P2$_{1}/$n space group. The UV-visible and photoluminescence spectroscopic analyses confirmed its direct bandgap…

Materials Science · Physics 2021-11-04 Subrata Das , M. D. I. Bhuyan , M. A. Basith

Complex functional materials are characterized by intricate and competing bond orders, making them an excellent platform for evaluating the newly developed Strongly Constrained and Appropriately Normed (SCAN) density functional. In this…

Materials Science · Physics 2024-09-23 Da Ke , Jianwei Sun , Yubo Zhang