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Near-term quantum computers will be limited in the number of qubits on which they can process information as well as the depth of the circuits that they can coherently carry out. To-date, experimental demonstrations of algorithms such as…

Chemical Physics · Physics 2023-10-18 Joel Bierman , Yingzhou Li , Jianfeng Lu

The theory of nilpotent orbits of simple Lie algebras has seen tremendous developments over the past decades. In this context an important role is played by the component group of the stabilizer of a nilpotent element. In this work, the aim…

Representation Theory · Mathematics 2024-07-17 Emanuele Di Bella , Willem A. De Graaf

Adaptive variational quantum eigensolvers (ADAPT-VQEs) are promising candidates for simulations of strongly correlated systems on near-term quantum hardware. To further improve the noise resilience of these algorithms, recent efforts have…

Combinatorial optimization on near-term quantum devices is a promising path to demonstrating quantum advantage. However, the capabilities of these devices are constrained by high noise or error rates. In this paper, we propose an iterative…

Quantum Physics · Physics 2022-05-12 Xiaoyuan Liu , Anthony Angone , Ruslan Shaydulin , Ilya Safro , Yuri Alexeev , Lukasz Cincio

The ADAPT-VQE algorithm is a promising method for generating a compact ansatz based on derivatives of the underlying cost function, and it yields accurate predictions of electronic energies for molecules. In this work we report the…

In this paper, we develop a new and efficient approach to the computation of envelope surfaces. We interpret one-parameter systems of surfaces as curves in the homogeneous spaces of suitable Lie groups. Using the formalism of Lie groups and…

Differential Geometry · Mathematics 2025-11-25 Michal Molnár , Zbyněk Šír , Jana Vráblíková

Classical mechanical systems are defined by their kinetic and potential energies. They generate a Lie algebra under the canonical Poisson bracket. This Lie algebra, which is usually infinite dimensional, is useful in analyzing the system,…

Mathematical Physics · Physics 2019-05-21 Robert I McLachlan , Ander Murua

The adaptive derivative-assembled pseudo-trotter variational quantum eigensolver (ADAPT-VQE) is a promising hybrid quantum-classical algorithm for molecular ground state energy calculation, yet its practical scalability is hampered by…

Quantum Physics · Physics 2026-02-05 Runhong He , Xin Hong , Qiaozhen Chai , Ji Guan , Junyuan Zhou , Arapat Ablimit , Guolong Cui , Shenggang Ying

L-QLES is an open source python code for generating 1D, 2D and 3D Laplacian operators and associated Poisson equations and their classical solutions. Its goal is to provide quantum algorithm developers with a flexible test case framework…

Quantum Physics · Physics 2024-02-20 Leigh Lapworth

Variational Quantum Eigensolver (VQE) faces significant challenges due to hardware noise and the presence of barren plateaus and local traps in the optimization landscape. To mitigate the detrimental effects of these issues, we introduce a…

Quantum Physics · Physics 2025-12-09 Chayan Patra , Rahul Maitra

We present high-precision quantum computing simulations of three-body atoms (He, H$^-$) and molecules (H$_2^+$, HD$^+$), the latter being studied beyond the Born-Oppenheimer approximation. The Non-Iterative Disentangled Unitary Coupled…

Quantum Physics · Physics 2025-10-22 Mohammad Haidar , Hugo D. Nogueira , J. -Ph. Karr

Quantum computational chemistry has emerged as an important application of quantum computing. Hybrid quantum-classical computing methods, such as variational quantum eigensolvers (VQE), have been designed as promising solutions to quantum…

We introduce the generative quantum eigensolver (GQE), a new quantum computational framework that operates outside the variational quantum algorithm paradigm by applying classical generative models to quantum simulation. The GQE algorithm…

Generalized eigenvalue problems (GEPs) play an important role in the variety of fields including engineering, machine learning and quantum chemistry. Especially, many problems in these fields can be reduced to finding the minimum or maximum…

We present a method for associating labeled directed graphs to finite-dimensional Lie algebras, thereby enabling rapid identification of key structural algebraic features. To formalize this approach, we introduce the concept of…

Mathematical Physics · Physics 2026-01-23 Tim Heib , David Edward Bruschi

Variational quantum eigensolver (VQE) emerged as a first practical algorithm for near-term quantum computers. Its success largely relies on the chosen variational ansatz, corresponding to a quantum circuit that prepares an approximate…

Quantum Physics · Physics 2020-07-10 D. Chivilikhin , A. Samarin , V. Ulyantsev , I. Iorsh , A. R. Oganov , O. Kyriienko

Variational quantum eigensolver ans\"atze hold considerable promise for ground-state energy calculations on near-term quantum hardware, yet most promising ansatz designs currently strongly depend on how well the molecular orbital basis…

Quantum computing can empower machine learning models by enabling kernel machines to leverage quantum kernels for representing similarity measures between data. Quantum kernels are able to capture relationships in the data that are not…

Designing compact and accurate circuits for the variational quantum eigensolver (VQE) is a central challenge in near-term quantum chemistry. Existing adaptive methods such as ADAPT-VQE design circuits by iteratively selecting operators from…

Quantum Physics · Physics 2026-05-28 Jianpeng Chen , Zirui Sheng , Cunxi Gong , Weitang Li

The adaptive derivative-assembled problem-tailored variational quantum eigensolver (ADAPT-VQE) is one of the most widely used algorithms for electronic structure calculations in quantum computers. It adaptively selects operators based on…

Chemical Physics · Physics 2025-08-29 Nonia Vaquero-Sabater , Abel Carreras , David Casanova