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Quantum Lie algebras are generalizations of Lie algebras which have the quantum parameter h built into their structure. They have been defined concretely as certain submodules of the quantized enveloping algebras. On them the quantum Lie…

q-alg · Mathematics 2009-10-30 Gustav W. Delius , Mark D. Gould

Finding the ground-state energy of molecules is an important and challenging computational problem for which quantum computing can potentially find efficient solutions. The variational quantum eigensolver (VQE) is a quantum algorithm that…

Quantum Physics · Physics 2023-02-15 Daniel Yoffe , Amir Natan , Adi Makmal

The class of $\D$-locally nilpotent algebras (introduced in the paper) is a wide generalization of the algebras of differential operators on commutative algebras. Examples includes all the rings $\CD (A)$ of differential operators on…

Rings and Algebras · Mathematics 2024-06-13 V. V. Bavula

Accurate determination of ground-state energies for molecules remains a challenge in quantum chemistry and a cornerstone for progress in fields such as drug discovery and materials design. The Variational Quantum Eigensolver (VQE)…

Many combinatorial optimisation problems hide algebraic structures that, once exposed, shrink the search space and improve the chance of finding the global optimal solution. We present a general framework that (i) identifies algebraic…

Artificial Intelligence · Computer Science 2026-04-08 Min Sun , Federica Storti , Valentina Martino , Miguel Gonzalez-Andrades , Tony Kam-Thong

In this paper, we study the problem of optimizing a linear program whose variables are the answers to a conjunctive query. For this we propose the language LP(CQ) for specifying linear programs whose constraints and objective functions…

Databases · Computer Science 2024-08-07 Florent Capelli , Nicolas Crosetti , Joachim Niehren , Jan Ramon

Machine learning potentials (MLPs) are widely applied as an efficient alternative way to represent potential energy surfaces (PES) in many chemical simulations. The MLPs are often evaluated with the root-mean-square errors on the test set…

The Quantum Approximate Optimization Algorithm (QAOA) requires considered optimization problems to be translated into a compatible format. A popular transformation step in this pipeline involves the quadratization of higher-order binary…

Quantum Physics · Physics 2025-11-26 Damian Rovara , Lukas Burgholzer , Robert Wille

Variational quantum algorithms (VQAs) are a modern family of quantum algorithms designed to solve optimization problems using a quantum computer. Typically VQAs rely on a feedback loop between the quantum device and a classical optimization…

Quantum Physics · Physics 2022-08-26 Alexey Uvarov

Variational quantum eigensolver(VQE) typically minimizes energy with hybrid quantum-classical optimization, which aims to find the ground state. Here, we propose a VQE by minimizing energy variance, which is called as variance-VQE(VVQE).…

Quantum Physics · Physics 2020-06-30 Dan-Bo Zhang , Zhan-Hao Yuan , Tao Yin

We present a new linear scaling method for the energy minimization step of semiempirical and first-principles Hartree-Fock and Kohn-Sham calculations. It is based on the self-consistent calculation of the optimum localized orbitals of any…

Materials Science · Physics 2009-11-10 Luis Seijo , Zoila Barandiaran

We present two open-source implementations of the Locally Optimal Block Preconditioned Conjugate Gradient (LOBPCG) algorithm to find a few eigenvalues and eigenvectors of large, possibly sparse matrices. We then test LOBPCG for various…

Numerical Analysis · Mathematics 2023-05-12 Tommaso Nottoli , Ivan Giannì , Antoine Levitt , Filippo Lipparini

Variational quantum eigensolver (VQE) is an efficient computational method promising chemical accuracy in electronic structure calculations on a universal-gate quantum computer. However, such a simple task as computing the electronic energy…

Chemical Physics · Physics 2018-06-04 Ilya G. Ryabinkin , Scott N. Genin , Artur F. Izmaylov

The variational quantum eigensolver (VQE) is an algorithm to compute ground and excited state energy of quantum many-body systems. A key component of the algorithm and an active research area is the construction of a parametrized trial…

Variational quantum algorithms provide a direct, physics-based approach to protein structure prediction, but their accuracy is limited by the coarse resolution of the energy landscapes generated on current noisy devices. We propose a hybrid…

Emerging Technologies · Computer Science 2025-10-09 Yuqi Zhang , Yuxin Yang , Feixiong Chen , Cheng-Chang Lu , Nima Saeidi , Samuel L. Volchenboum , Junhan Zhao , Siwei Chen , Weiwen Jiang , Qiang Guan

Qubits are a great way to build a quantum computer, but a limited way to program one. We replace the usual "states and gates" formalism with a "props and ops" (propositions and operators) model in which (a) the C*-algebra of observables…

Quantum Physics · Physics 2025-09-08 David Wakeham

We propose SUN-VQC, a variational-circuit architecture whose elementary layers are single exponentials of a symmetry-restricted Lie subgroup, $\mathrm{SU}(2^{k}) \subset \mathrm{SU}(2^{n})$ with $k \ll n$. Confining the evolution to this…

Quantum Physics · Physics 2025-07-09 Kuan-Cheng Chen , Huan-Hsin Tseng , Samuel Yen-Chi Chen , Chen-Yu Liu , Kin K. Leung

By design, the variational quantum eigensolver (VQE) strives to recover the lowest-energy eigenvalue of a given Hamiltonian by preparing quantum states guided by the variational principle. In practice, the prepared quantum state is…

Quantum Physics · Physics 2021-06-29 Daniel Claudino , Jerimiah Wright , Alexander J. McCaskey , Travis S. Humble

Quantum simulation of molecular electronic structure is one of the most promising applications of quantum computing. However, achieving chemically accurate predictions for strongly correlated systems requires quantum phase estimation (QPE)…

Quantum Physics · Physics 2026-03-31 Shota Kanasugi , Riki Toshio , Kazunori Maruyama , Hirotaka Oshima

Generative quantum eigensolver (GQE) is a hybrid quantum-classical algorithm that iteratively trains a classical generative machine learning model such that the model can generate quantum circuits with desired properties such as…

Quantum Physics · Physics 2026-05-12 Junya Nakamura , Shinichiro Sanji
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