Related papers: The Second Gibbs Paradox
Gibbs paradox in the context of statistical mechanics addresses the issue of additivity of entropy of mixing gases. The usual discussion attributes the paradoxical situation to classical distinguishability of identical particles and credits…
The Gibbs Paradox is essentially a set of open questions as to how sameness of gases or fluids (or masses, more generally) are to be treated in thermodynamics and statistical mechanics. They have a variety of answers, some restricted to…
The suggestion that particles of the same kind may be indistinguishable in a fundamental sense, even so that challenges to traditional notions of individuality and identity may arise, has first come up in the context of classical…
Phase diagrams of some globular proteins have a fluid-fluid transition as well as a fluid-crystal transition. Homogeneous nucleation of the crystal from the fluid phase near the critical point of the fluid-fluid transition is examined. As…
It is well known that the Gibbs inequality, which says that the Gibbs ratio is bounded above and below by positive constants, holds for the unique equilibrium states of H\"older continuous potentials on shift spaces, but it can fail for…
The Gibbs paradox has frequently been interpreted as a sign that particles of the same kind are fundamentally indistinguishable; and that quantum mechanics, with its identical fermions and bosons, is indispensable for making sense of this.…
This article presents the results of research into the causes of the Gibbs paradox in the formulation discussed by J. W. Gibbs himself. In this formulation, we are talking about an inexplicable (paradoxical) jump in the entropy of mixing of…
Non-hydrostatic stress has a peculiar effect on the phase equilibrium between solids and liquids. This was already pointed out by Gibbs. Gibbs derived his formulation of the condition for liquid-solid coexistence applying a surface…
We show in this note that Gibbs paradox arises not due to application of thermodynamic principles, whether classical or statistical or even quantum mechanical, but due to incorrect application of mathematics to the process of mixing of…
The Gibbs Mixing Paradox is a conceptual touchstone for understanding mixtures in statistical mechanics. While debates over the theoretical subtleties of particle distinguishability continue to this day, we seek to extend the discussion in…
Using a minimal algebraic model for the thermodynamics of binary rod--polymer mixtures, we provide evidence for a quintuple phase equilibrium; an observation that seems to be at odds with the Gibbs phase rule for two-component systems. Our…
The issue of the Gibbs paradox is that when considering mixing of two gases within classical thermodynamics, the entropy of mixing appears to be a discontinuous function of the difference between the gases: it is finite for whatever small…
Based on a reconsideration of the Gibbs paradox, we show that a residual, non-extensive term in entropy turns up upon mixing identical particles, whether they are indistinguishable or not. The positive contribution from this residual…
Identical classical particles are distinguishable. This distinguishability affects the number of ways W a macrostate can be realized on the micro-level, and from the relation S = k ln W leads to a non-extensive expression for the entropy.…
Homogeneous nucleation of a new phase near a second, continuous, transition, is considered. The continuous transition is in the metastable region associated with the first-order phase transition, one of whose coexisting phases is…
Physics associated with the Higgs field potential is rich and interesting and deserves a concise summary for a broader audience to appreciate the beauty and the challenges of this subject. We discuss the role of the Higgs potential in…
We first explore the liquid-gas mixed phase in a bulk calculation, where two phases coexist without the geometrical structures. In the case of symmetric nuclear matter, the system behaves congruently, and the Maxwell construction becomes…
For an ideal gas consisting N molecules within a volume V, the volume accessible to each molecule at an instantaneous time is V/N. The rest of the volume, (N-1)(V/N), is occupied by other (N-1) molecules. The textbook assumption that a…
During the spreading of a liquid over a solid substrate, the contact line can stay pinned at sharp edges until the contact angle exceeds a critical value. At (or sufficiently near) equilibrium, this is known as Gibbs' criterion. Here, we…
Traditionally, the difference in binding energy from the experimental value with respect to the theoretical liquid-drop model value, has been seen as indication of independent-particle character along with magicity for particular number of…