Related papers: The Second Gibbs Paradox
Homogeneous nucleation, a textbook transition path for phase transitions, is typically understood on thermodynamic grounds through the prism of classical nucleation theory. However, recent studies have suggested the applicability of…
We explore the Higgs particle in the cosmic quark-gluon plasma (QGP) below the electroweak phase transition temperature $T_\mathrm{EW}\simeq 125\mathrm{\,GeV}$. We show that Higgs is neither in abundance (chemical) nor in momentum…
The analysis of the arguments within the limits of the classical thermodynamics that lead to the Gibbs paradox was made. Features of preconditions used in the derivation of the entropy of mixing of ideal gases that caused the appearance of…
The article reveals the error that in classical thermodynamics leads to the Gibbs paradox. The essence of the error lies in the fact that the entropy of an ideal gas is attributed to additive quantities, but it is not correct. The value of…
For different phases to coexist in equilibrium at constant temperature $T$ and pressure $P$, the condition of equal chemical potential $\mu$ must be satisfied. This condition dictates that, for a single-component system, the maximum number…
We report a numerical study of the rate of crystal nucleation in a binary suspension of oppositely charged colloids. Two different crystal structures compete in the thermodynamic conditions under study. We find that the crystal phase that…
Naturalness has for many years been a guiding principle in the search for physics beyond the Standard Model, particularly for understanding the physics of electroweak symmetry breaking. However, the discovery of the Higgs particle at 125…
As no heat effect and mechanical work are observed, we have a simple experimental resolution of the Gibbs paradox: both the thermodynamic entropy of mixing and the Gibbs free energy change are zero during the formation of any ideal…
The Higgs contribution to the effective potential appears to be complex. How do we interpret this, and how should we modify the calculation to calculate physical quantities such as the critical bubble free energy?
The existing constraints from particle colliders reveal a suspicious but nonlethal metastability for our current electroweak vacuum of Higgs potential in the standard model of particle physics, which is, however, disfavored in the early…
It is shown that the existence of single critical point of the fluid described by van der Waals equation of state is not the hypothesis and it is the consequence of the thermodynamic conditions of liquid-vapor phase equilibrium. It is also…
It is shown that the Gibbs paradox is actually paralogism, viz. an erroneous statement sounding credible due to the statistic-mechanical interpretation of entropy as a measure of "any and all" irreversibility. As an alternative, the…
The purpose of the study is to further investigate the classical Gibbs analysis of the heterogeneous system "stressed crystal - melt." It is demonstrated that each equilibrium configuration is stable with respect to a special class of…
The classical Gibbs paradox concerns the entropy change upon mixing two gases. Whether an observer assigns an entropy increase to the process depends on their ability to distinguish the gases. A resolution is that an "ignorant" observer,…
A unified theory of phase transitions and quantum effects in quantum anharmonic crystals is presented. In its framework, the relationship between these two phenomena is analyzed. The theory is based on the representation of the model Gibbs…
Besides the standard quantum version of the Coulomb/Kepler problem, an alternative quantum model with not too dissimilar phenomenological (i.e., spectral and scattering) as well as mathematical (i.e., exact-solvability) properties may be…
We consider the subtleties involved in the application of the Equivalence Theorem to the decay of an unstable Higgs particle. This is formally justified from consideration of unitarity and resonant elastic scattering of the stable decay…
Quantifying the configuration space and the Gibbs measure of thermally disordered condensed matter systems has been a long standing problem. The challenge is to avoid the Gibbs paradox, which forbids any ordering or labeling of the atoms.…
I present a concise review of the Higgs problem which plays a central role in particle physics today. The Higgs of the minimal Standard Model is so far just a conjecture that needs to be verified or discarded at the LHC. Probably the…
It is widely believed that heterogeneous nucleation occurs without an activation process when the surface is completely wettable. In this report, we review our previous work [J.Chem.Phys {\bf 134}, 234709 (2011)] to show that the critical…