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On the basis of optimal control theory, we numerically study how to optimally manipulate molecular vibrational dynamics by using cycle-averaged polarizability interactions induced by mildly intense non-resonant laser (NR) pulses. As the…

Quantum Physics · Physics 2024-09-05 Reon Ishii , Tomotaro Namba , Hiroyuki Katsuki , Kenji Ohmori , Yukiyoshi Ohtsuki

Dissolution Dynamic Nuclear Polarisation (dDNP) increases the sensitivity of magnetic resonance experiments by $>10^4$-fold, permitting isotopically-labelled molecules to be transiently visible in MRI scans. dDNP requires a source of…

The efficiency of dipole-dipole coupling driven coherence transfer experiments in solid-state NMR spectroscopy of powder samples is limited by dispersion of the orientation of the internuclear vectors relative to the external magnetic…

Quantum Physics · Physics 2009-11-13 N. Khaneja , C. Kehlet , S. J. Glaser , N. C. Nielsen

Dynamic Nuclear Polarization (DNP) is a powerful suite of techniques that deliver multifold signal enhancements in NMR and MRI. The generated athermal spin states can also be exploited for quantum sensing and as probes for many-body…

We propose a nuclear-spin-polarization protocol in a general evolution-and-measurement framework. The protocol works in a spin-star configuration, where the central spin is coupled to the surrounding bath (nuclear) spins by flip-flop…

Quantum Physics · Physics 2022-12-07 Zhu-yao Jin , Jia-shun Yan , Jun Jing

We present a new class of control pulses designed to transfer co-located ensembles without relying on frequency selectivity, thereby allowing much faster state-transitions. A geometric approach allows us to construct sequences which are…

Atomic Physics · Physics 2026-04-23 K. L. Wood , W. A. Terrano

We study a mechanism by which nuclear hyperpolarization due to the polarization transfer from a microwave-pulse-controlled electron spin is suppressed. From analytical and numerical calculations of the unitary dynamics of multiple nuclear…

Quantum Physics · Physics 2024-03-12 Kento Sasaki , Eisuke Abe

Optical dynamic nuclear polarization (DNP) offers an attractive approach to enhancing the sensitivity of nuclear magnetic resonance (NMR) spectroscopy. Efficient, optically-generated electron polarization can be leveraged to operate across…

Dynamic nuclear polarization is widely used to enhance the sensitivity of nuclear magnetic resonance. It is presently the method of choice for enhancing the sensitivity of high-field solid state NMR experiments performed under cryogenic…

Chemical Physics · Physics 2022-02-02 Maria Grazia Concilio , Ilya Kuprov , Lucio Frydman

The ability to control spins in semiconductors is important in a variety of fields including spintronics and quantum information processing. Due to the potentially fast dephasing times of spins in the solid state [1-3], spin control…

We propose a new pulse sequence for dynamical averaging of the dipole-dipole interactions and inhomogeneities of the magnetic fields in the nuclear spin system. The sequence contains a short cycle of the periodic resonant pulse excitation…

Quantum Physics · Physics 2015-03-05 S. A. Moiseev , V. A. Skrebnev

Nuclear electric resonance (NER) is based on nuclear magnetic resonance mediated by spatial oscillations of electron spin domains excited by a radio frequency (RF) electric field, and it allows us to investigate the spatial distribution of…

Mesoscale and Nanoscale Physics · Physics 2012-10-25 S. Watanabe , G. Igarashi , N. Kumada , Y. Hirayama

Magnetic-field and microwave-frequency modulated DNP experiments have been shown to yield improved enhancements over conventional DNP techniques, and even to shorten polarization build-up times. The resulting increase in signal-to-noise…

Instrumentation and Detectors · Physics 2015-12-23 Mallory L. Guy , Lihuang Zhu , Chandrasekhar Ramanathan

Single crystal silicon is an excellent system in which to explore dynamic nuclear polarization (DNP), as it exhibits a continuum of properties from metallic to insulating as a function of doping concentration and temperature. At low doping…

Materials Science · Physics 2011-09-09 Anatoly E. Dementyev , David G. Cory , Chandrasekhar Ramanathan

We consider the problem of determining the spectrum of an electronic spin via polarization transfer to coupled nuclear spins and their subsequent readout. This suggests applications for employing dynamic nuclear polarization (DNP) for…

Quantum Physics · Physics 2021-10-19 Moniish Elanchezhian , Arjun Pillai , Teemu Virtanen , Ashok Ajoy

Diamond-based quantum sensors have enabled high-resolution NMR spectroscopy at the microscale in scenarios where fast molecular motion averages out dipolar interactions among target nuclei. However, in samples with low-diffusion, ubiquitous…

Quantum Physics · Physics 2025-08-26 Carlos Munuera-Javaloy , Ander Tobalina , Jorge Casanova

We review on the theoretical status of intense laser orientation and alignment. The evolution of the rotational wave packet and its dynamics leading to orientation and alignment is the topic of the present discussion. The major part of the…

Atomic Physics · Physics 2021-04-14 Vijit V. Nautiyal , Sumana Devi , Ashish Tyagi , Bhawna Vidhani , Anjali Maan , Vinod Prasad

The control of nuclear spins in quantum dots is essential to explore their many-body dynamics and exploit their prospects for quantum information processing. We present a unique combination of dynamic nuclear spin polarization and…

Mesoscale and Nanoscale Physics · Physics 2015-12-16 Florian Forster , Max Mühlbacher , Dieter Schuh , Werner Wegscheider , Geza Giedke , Stefan Ludwig

At the magnetic fields of common NMR instruments, electron Zeeman frequencies are too high for efficient electron-nuclear dipolar cross-relaxation to occur in solution. The rate of that process fades with the electron Zeeman frequency as…

Quantum Physics · Physics 2021-04-22 Maria Grazia Concilio , Murari Soundararajan , Lucio Frydman , Ilya Kuprov

$^1$H nuclear spin-lattice relaxation and Dynamic Nuclear Polarization (DNP) have been studied in amorphous samples of trehalose sugar doped with TEMPO radicals by means of mechanical milling, in the 1.6 K $\div$ 4.2 K temperature range.…