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Using a molecular dynamics computer simulation we determine the temperature dependence of the partial structure factors for a binary Lennard-Jones system. These structure factors are used as input data to solve numerically the wave-vector…

Condensed Matter · Physics 2016-08-31 Markus Nauroth , Walter Kob

The Classical Nucleation Theory (CNT) has played a key role in crystal nucleation studies since the 19th century and has significantly advanced the understanding of nucleation. However, certain key assumptions of CNT, such as a compact and…

Materials Science · Physics 2023-11-22 Fangzheng Chen , Kian Cole Dahlberg , Zohar Nussinov , K. F. Kelton

We test classical nucleation theory (CNT) in the case of simulations of deeply supercooled, high density liquid silica, as modelled by the BKS potential. We find that at density $\rho=4.38$~g/cm$^3$, spontaneous nucleation of crystalline…

Soft Condensed Matter · Physics 2009-11-11 Ivan Saika-Voivod , Peter H. Poole , Richard K. Bowles

A full understanding of polycrystalline materials requires studying the process of nucleation, a thermally activated phase transition that typically occurs at atomistic scales. The numerical modeling of this process is problematic for…

Materials Science · Physics 2018-05-09 Paul Jreidini , Gabriel Kocher , Nikolas Provatas

Nucleation at large metastability is still largely an unsolved problem, although is a problem of tremendous current interest, with wide practical value. It is well-accepted that the classical nucleation theory (CNT) fails to provide a…

Statistical Mechanics · Physics 2010-12-22 Mantu Santra , Rakesh S. Singh , Biman Bagchi

We present a simulation technique to evaluate the most important quantity for nucleation processes: the nucleation barrier, i.e. the free energy of formation of the critical cluster. The method is based on stabilizing a small cluster by…

Statistical Mechanics · Physics 2026-03-13 Adrian Llamas-Jaramillo , Ivan Latella , David Reguera

The freezing/melting transition is at the heart of many natural and industrial processes. In the classical picture, the transition proceeds via the nucleation of the new phase, which has to overcome a barrier associated to the free energy…

Soft Condensed Matter · Physics 2024-08-28 Patrice Porion , Joël Puibasset

Molecular simulations have provided valuable insight into the microscopic mechanisms underlying homogeneous ice nucleation. While empirical models have been used extensively to study this phenomenon, simulations based on first-principles…

We study by computer simulation the nucleation of a supersaturated Lennard-Jones vapor into the liquid phase. The large free energy barriers to transition make the time scale of this process impossible to study by ordinary molecular…

Statistical Mechanics · Physics 2018-08-15 Pablo M. Piaggi , Omar Valsson , Michele Parrinello

We calculate bubble nucleation rates in a Lennard-Jones fluid through explicit molecular dynamics simulations. Our approach -- based on a recent free energy method (dubbed reweighted Jarzynski sampling), transition state theory, and a…

Soft Condensed Matter · Physics 2022-11-16 Kristof M. Bal , Erik C. Neyts

We employ force-field molecular dynamics simulations to investigate the kinetics of nucleation to new liquid or solid phases in a dense gas of particles, seeded with ions. We use precise atomic pair interactions, with physically correct…

Chemical Physics · Physics 2020-08-11 O. C. F. Brown , D. Vrinceanu , V. Kharchenk , H. R. Sadeghpour

We present results from large-scale molecular dynamics (MD) simulations of homogeneous vapor-to-liquid nucleation. The simulations contain between one and eight billion Lennard-Jones (LJ) atoms, covering up to 1.2 {\mu}s (56 million…

Chemical Physics · Physics 2013-08-22 Jürg Diemand , Raymond Angélil , Kyoko K. Tanaka , Hidekazu Tanaka

We have performed large-scale Lennard-Jones molecular dynamics simulations of homogeneous vapor-to-liquid nucleation, with $10^9$ atoms. This large number allows us to resolve extremely low nucleation rates, and also provides excellent…

Chemical Physics · Physics 2014-04-07 Raymond Angélil , Jürg Diemand , Kyoko K. Tanaka , Hidekazu Tanaka

We have investigated by molecular dynamics method the influence of a finite number of particles used in computer simulations on fluctuations of thermodynamic properties. As a case study, we used the two-dimensional Lennard-Jones system. 2D…

Statistical Mechanics · Physics 2024-03-05 M. V. Kondrin , Y. B. Lebed

Recent developments in analog quantum simulators based on cold atoms and trapped ions call for cross-validating the accuracy of quantum-simulation experiments with use of quantitative numerical methods; however, it is particularly…

Quantum Gases · Physics 2022-03-23 Ryui Kaneko , Ippei Danshita

Nucleation is the onset of a first-order phase transition by which a metastable phase transforms into a more stable one. Such a phase transition occurs when an initial system initially in equilibrium is destabilized by the change of an…

Materials Science · Physics 2010-01-27 Emmanuel Clouet

In the study of crystal nucleation via computer simulations, hard spheres are arguably the most extensively explored model system. Nonetheless, even in this simple model system, the complex thermodynamics of crystal nuclei can sometimes…

Soft Condensed Matter · Physics 2025-02-19 Marjolein de Jager , Carlos Vega , Pablo Montero de Hijes , Frank Smallenburg , Laura Filion

The NEUT intranuclear cascade model is described and fit to a large body of \pipm--nucleus scattering data. Methods are developed to deal with deficiencies in the available historical data, and robust uncertainty estimates are produced. The…

Selected results of a classical simulation of N bodies in strong interaction are presented. The static properties of such classical systems are qualitatively similar to the known properties of atomic nuclei. The simulations of collisions…

Nuclear Theory · Physics 2009-11-07 D. Cussol

Understanding the equilibrium properties and out of equilibrium dynamics of quantum field theories are key aspects of fundamental problems in theoretical particle physics and cosmology. However, their classical simulation is highly…

Quantum Physics · Physics 2023-12-21 Philipp Schmoll , Jan Naumann , Alexander Nietner , Jens Eisert , Spyros Sotiriadis